聚羧酸减水剂对不同晶型C3S早期水化放热的影响

采用水化微量热仪研究了不同类型聚羧酸减水剂对不同晶型C3S水化放热特性的影响。结果表明:单斜晶系(M)C3S、三方晶系(R)C3S的水化放热速率峰值相比三斜晶系(T)C3S显著降低,且水化放热峰出现延迟,MC3S的水化放热峰延迟最明显。三种晶型C3S的3d水化放热总量由大到小为:TC3S、MC3S、RC3S。不同分子结构的甲氧基聚乙二醇甲基丙烯酸酯系聚羧酸减水剂,主链越短,支链越长,对TC3S的水化延迟作用越大。乙烯基聚乙二醇醚系聚羧酸减水剂对三种晶型C3S的水化放热过程延迟作用由大到小为:RC3S、MC3S、TC3S。对水化放热曲线进行的Krstulovic-Dabic模型研究表明,C3S的水化过程为NG-D类型水化历程。     

Effects of molecular structure of polycarboxylate-type superplasticizer on the hydration properties of C3S

Effects of polycarboxylate-type superplasticizer(PC) molecular structure on the hydration heat of tricalcium silicate(C3S) paste and polymerization degree of hydration products(C-S-H gel) were researched by using TAM AIR isothermal microcalorimetry(TA) and 29Si nuclear magnetic resonance(NMR).Methoxy polyethylene glycol-methacrylates-based polycarboxylate superplasticizers with different side chain lengths and main chain lengths were employed.PC molecules with shorter main chain or longer side chains caused stronger retardation of C3S early hydration and lesser increase of C3S 3 d hydration degree.NMR measurement indicated that the incorporation of PC increased the hydration degree of C3S paste and the polymerization degree of silicon-oxygen tetrahedron of C-S-H gel.The tendency for C3S 7 d hydration degree to improve was more pronounced while PC molecules with longer main chain or shorter side chain were added.Whereas,PC molecules with longer main chains or longer side chains increased the 7 d polymerization degree of C-S-H gel.     

Effect of curing regime on the distribution of Al3+ coordination in hardened cement pastes

The effect of curing regime on the distribution of Al³⁺ coordination in hardened cement pastes within 28 d were investigated by ²⁹Si and ²⁷Al magic angle spinning (MAS) nuclear magnetic resonance(NMR) with deconvolution technique. The results indicate that the tetrahedral coordination Al³⁺ incorporated in C-S-H structure mainly originate from the Al³⁺ incorporated in the alite and belite phases in the Portland cement. The curing regime of constant temperature of 20 °C is beneficial to the octahedral coordination Al³⁺ transforming to tetrahedral coordination Al³⁺ incorporated in C-S-H structure. However, at curing regime of variable temperature, the temperature rising process is more advantageous to the transformation from ettringite to monosulphate, substitution of Al³⁺ for Si⁴⁺ in the C-S-H structure and the formation of the third aluminate hydrate (TAH) than that at constant temperature of 20 °C. The high temperature of 60 °C in the holding temperature process promotes the decomposition of ettringite, and enhances the consumption of the Al³⁺ incorporated in C-S-H phases and the Al³⁺ in TAH for the monosulphate forming. The temperature decreasing promotes the transformation from monosulphate to ettringite, and increases the consumption of the Al³⁺ incorporated in C-S-H phases, and then increases the quantity of the TAH.     

钢管膨胀混凝土力学性能及其膨胀模式的研究

配制出了强度性能和工作性能良好的膨胀混凝土,研究了该种钢管膨胀混凝土的力学性能,分析了钢管限制条件下核心混凝土的膨胀模式。研究结果表明,掺加适量膨胀剂的钢管膨胀混凝土具有较优良的力学性能,其极限承载力比普通钢管混凝土可提高8％左右。     

钢管膨胀混凝土力学性能及膨胀模式的研究

配制出了强度性能和工作性能良好的膨胀混凝土,研究了该种钢管膨胀混凝土的力学性能,分析了钢管限制条件下核心混凝土的膨胀模式。研究结果表明,掺加适量膨胀剂的钢管膨胀混凝土具有较优良的力学性能,其极限承载力比普通钢管混凝土可提高8％左右。     

集料组成对次轻混凝土宏观性能影响的研究

研究了集料组成对次轻混凝土宏观性能的影响规律，通过调整集料组成配制出了密度在2200kg／m^3左右，强度大于60MPa的次轻混凝土。结果表明，集料组成能明显地影响次轻混凝土的表观密度、抗压强度、抗拉强度和弹性模量。     

大流动性高强轻集料混凝土的研究

为设计出具有大流动性性能的高强或超高强轻集料混凝土，分别研究了水胶比、砂率、轻集料最大粒径3个关键技术参数和矿物掺合料组成设计对混凝土工作性能和抗压强度的影响规律，确定了配制LC50～LC60自密实高强轻集料混凝土的主要技术方法，制备出坍落度为240mm以上、扩展度达到680～700mm、28d抗压强度超过60MPa的大流动性高强轻集料混凝土。     

细集料对超高性能混凝土的性能影响

为探寻出一种低成本、可替代石英砂的细集料来制备超高性能混凝土(UHPC),研究了不同种类、级配的细集料对超高性能混凝土的工作性能、力学性能和收缩性能影响规律,通过XRD、SEM等测试方法对其微结构进行分析.研究结果表明:在相同胶凝材料体系、水胶比、钢纤维掺量、标准养护条件下,河砂制备的UHPC的流动性略低于石英砂制备的UHPC;河砂制备的UHPC与石英砂制备的UHPC的抗压/抗折强度均可达140 MPa/20 MPa以上;粒径小于1.18 mm河砂制备的UHPC的收缩率最低,可至600×10-6.分析XRD、SEM等表征结果发现石英砂和河砂制备的UHPC中砂与胶凝浆体连接更紧密,而机制砂制备的UHPC中界面较为明显.粒径小于1.18 mm河砂制备的UHPC的流动性、力学性能和收缩率综合最佳,并且河砂的价格较低,可降低UHPC的成本,良好的替代传统UHPC中的石英砂.     

工业废渣注浆材料的抗溶蚀性能

针对水玻璃-水泥(soluble glass-cement,SC)注浆材料在地层加固过程中抗水溶蚀性能差和工业废渣得不到有效利用等问题,用工业废渣完全取代SC注浆材料中的水泥制备出水玻璃-工业废渣(矿渣、钢渣、粉煤灰)(soluble glass-activated industrial residue slag,SAS)注浆材料.模拟淡水侵蚀环境,对SAS和SC两体系注浆材料进行了水溶蚀试验研究,结果表明SAS系列抗水溶蚀性能优于SC系列的.在水溶蚀作用180d条件下,SAS注浆材料的强度无损失,而SC系列结石体强度损失率达50%;SAS系列的Si溶出量、溶出物质总量和电导率等都低于SC系列的.压汞法、X射线衍射、扫描电镜测试结果也表明:SAS具有致密的微观结构和低溶解度的水化产物,从微观层次证明了SAS系列注浆材料的高抗水溶蚀性能.     

水泥替代矿粉对沥青混凝土性能的影响

掺加适量水泥替代矿粉提高沥青凝土性能,在国内研究很少。文中通过水泥替代石灰石质矿粉对沥青胶浆软化点、针入度和抗老化性能影响的研究,发现掺加适量的水泥可显著提高沥青混凝土的温度稳定性和水稳性。