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排序方式: 共有245条查询结果,搜索用时 15 毫秒
1.
Nils von Preetzmann Philipp Eckmann Adriaan M. H. van der Veen Jianrong Li Markus Richter 《American Institute of Chemical Engineers》2021,67(4):e17128
Exact knowledge of natural gas composition is essential in custody transfer to determine the energy content of the delivery. However, for liquefied natural gas (LNG), a reliable composition determination is difficult. Here, we describe the design of a laboratory-scale reference liquefier that enables the validation and calibration of optical spectroscopy sensors by providing them with a sample of metrologically traceable composition. Hence, it is crucial to avoid fractionation of the sample during liquefaction. This is realized by supercritical liquefaction of a reference gas mixture in conjunction with a special vapor–liquid-equilibrium (VLE) cell. As this is a demanding high-pressure application, low-pressure condensation as liquefaction method was also assessed. Through experimental investigations and VLE calculations, preservation of the composition of the produced liquid sample during condensation was studied. We conclude that under optimized conditions, validation, and calibration measurements of optical sensors can be performed on condensed liquids, which, however, needs further confirmation. 相似文献
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The effects of dicumyl peroxide/vinyltriethoxysilane treatment and nanoclay content were investigated for low-density polyethylene (LDPE)/clay nanocomposites. LDPE was treated with 0.1 phr of DCP with, respectively, 1 phr and 3 phr VTES (System A), and with 0.2 phr of DCP with the same amounts of VTES (System B), and then mixed with different contents (1, 3, and 5 wt%) of modified clay (Cloisite 15A). The morphology and extent of crosslinking, as well as the thermal, mechanical, and thermomechanical properties were studied. X-ray diffraction results of all the VTES-treated LDPE/clay nanocomposites showed an increase in interlayer spacing, which indicates that the polymer chains were intercalated between the clay layers. Transmission electron microscopy micrographs of System B showed some evidence of exfoliated clay layers, indicating that the system exhibited a mixed morphology. The clay-containing samples had better thermal stability than LDPE, but the thermal stability did not differ much for the two systems. VTES observably decreased the melting enthalpy of LDPE, while the presence of clay had little influence on this value. This is somewhat contrary to the gel content results that showed a decrease in the extent of crosslinking in the presence of and with increasing clay content. VTES/DCP treatment and the presence of clay observably changed the dynamic mechanical and tensile behaviour of the LDPE. 相似文献
3.
Chongxin Yuan N.Bert Roozen Otto Bergsma Adriaan Beukers 《Engineering Analysis with Boundary Elements》2013,37(2):250-259
The aircraft fuselage is idealized as a composite cylinder, its vibroacoustic properties are studied both experimentally and numerically, and a minimization of the inner pressure of a composite cylinder is conducted with the genetic algorithm (GA). In the optimization, the Acoustic Transfer Vector (ATV), which comes from the boundary element method, builds the relationship between the structural surface velocity and the sound pressure at the specific filed points. Results show that the noise reduction obtained by the experimental and numerical methods have a good agreement; the optimization method which combines GA and ATV show high efficiency and robustness; increase of the bending stiffness of the cylinder can improve the noise reduction at low frequencies; both the reduction of weight and the increase of noise insulation can be achieved by the optimization of the layup at different regions of the cylinder individually. 相似文献
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The performance of PCD tools in high-speed milling of Ti6Al4V 总被引:1,自引:1,他引:0
Gert Adriaan Oosthuizen Guven Akdogan Nico Treurnicht 《The International Journal of Advanced Manufacturing Technology》2011,52(9-12):929-935
Tool performance of conventional tools is poor and a major constraint when used in milling titanium alloys at elevated cutting speeds. At these high cutting speeds, the chemical and mechanical properties of Ti6Al4V cause complex wear mechanisms. In this paper, a fine-grain polycrystalline diamond (PCD) end mill tool was tested, and its wear behavior was studied. The performance of the PCD tool has been investigated in terms of tool life, cutting forces, and surface roughness. The PCD tool yielded longer tool life than a coated carbide tool at cutting speeds above 100?m/min. A slower wear progression was found with an increase in cutting speeds, whereas the norm is an exponential increase in tool wear at elevated speeds. Observations based on scanning electron microscope (SEM) and energy dispersive spectroscopy (EDAX) analysis suggest that adhesion of the workpiece is the wear main type, after which degradation of the tools accelerates probable due to the combined effect of high temperature degradation coupled with abrasion. 相似文献
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Affective priming studies have shown that participants are faster to pronounce affectively polarized target words that are preceded by affectively congruent prime words than affectively polarized target words that are preceded by affectively incongruent prime words. We examined whether affective priming of naming responses depends on the valence proportion (i.e., the proportion of stimuli that are affectively polarized). In one group of participants, experimental trials were embedded in a context of filler trials that consisted of affectively polarized stimulus materials (i.e., high valence proportion condition). In a second group, the same set of experimental trials was embedded in a context of filler trials consisting of neutral stimuli (i.e., low valence proportion condition). Results showed that affective priming of naming responses was significantly stronger in the high valence proportion condition than in the low valence proportion condition. We conclude that (a) subtle aspects of the procedure can influence affective priming of naming responses, (b) finding affective priming of naming responses does not allow for the conclusion that affective stimulus processing is unconditional, and (c) affective stimulus processing depends on selective attention for affective stimulus information. (PsycINFO Database Record (c) 2011 APA, all rights reserved) 相似文献
8.
Reduced percolation concentration in polypropylene/expanded graphite composites: Effect of viscosity and polypyrrole 下载免费PDF全文
Jürgen Pionteck Elixana Maria Melchor Valdez Francesco Piana Mária Omastová Adriaan Stephanus Luyt Brigitte Voit 《应用聚合物科学杂志》2015,132(20)
With the goal to obtain material combining electrical and thermal conductivity at low filler loadings, composites based on polypropylenes (PP) and expanded graphite (EG) have been prepared. The effects of matrix viscosity and of coating the EG particles with polypyrrole (PPy, EG/PPy = 37.5/62.5 by weight) on the EG dispersibility and formation of percolation structures have been analyzed. When increasing the EG amount from 6 to 8 wt %, the electrical conductivity of PP/EG composites increased by 7–9 orders of magnitude, independent of matrix viscosity. When EG‐PPy is added, percolation was observed between 8 and 12 wt % EG‐PPy (3 and 4.5 wt % EG) in case of PP with higher viscosity and 6 wt % EG (2.25 wt % EG) in case of PP with lower viscosity, exhibiting a strong synergistic effect of EG and PPy in the latter case. In contrast, PPy does not contribute to reduction of thermal percolation concentration. Thermal percolation is observed at 8 wt % EG in PP/EG composites, but no percolation was found in PP/EG‐PPy composites with EG‐PPy contents of up to 20 wt %, corresponding to 7.5 wt % EG. Analyzing the melt rheology it becomes clear that the contribution of PPy to the formation of a filler network is strongly dependent on the matrix viscosity. The comparison of thermal, electrical and rheological percolation reveals that PPy participates in electron transport reducing the electrical percolation but not to heat transport. Overall, we found a good correlation between electrical, thermal, and melt rheological percolation concentrations. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 41994. 相似文献
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Micro gear pump with internal electromagnetic drive 总被引:1,自引:0,他引:1
This paper presents the concept, design and fabrication of a gear pump based on recently introduced synchronous micro motors as an integrated driving system. The micro motor is fully integrated in the fluidic system consisting of the inlet, outlet and pump chamber. A preliminary test on the gear pump flow rate is successfully reported. The whole system is mainly realized by means of micro fabrication technologies like UV-depth lithography and copper electroplating. Polymer magnets with alternating axial magnetization were applied in the toothed rotors. The use of polymer magnets affords a miniaturization with maximum space filling and without limitation in shape. In first tests the temperature behavior and the functional capability were investigated. 相似文献