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产品名称单位2006年累计2006年10月同比增长(累计)/%同比增长(本月)/%合成橡胶万t153·4415·0313·004·30顺丁橡胶万t37·663·2815·80-16·80合成纤维万t1500·38156·7211·8011·30锦纶纤维万t68·507·0315·2013·90轮胎外胎万条35784·813730·9617·8014·10子午线轮胎外胎万条14629·881656·2029·0037·10胶鞋万双126930·4814881·5226·1021·30大中型拖拉机台182525·0014495·0029·20-0·70小型拖拉机万台167·5216·39-0·60-8·70汽车万辆620·6161·7925·1035·60载货汽车万辆171·2717·2110·0038·10公路客车万辆1… 相似文献
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Solubilities and properties (density, conductivity and pH value) of solutions in the quaternary system Li+,K+//CO2-3,B4O2-7-H2O at 288 K were experimentally studied with the isothermal equilibrium method. The phase diagram of the system consisted of two invariant points E and F, five univariant curves, and four crystallization fields that belonged to K2CO3·3/2H2O,Li2B4O7·3H2O,K2B4O7·4H2O and Li2CO3. The composition of the solution corresponding to E was w(CO2-3)=2.27 %,w(B4O2-7)=6.05 %,w(K+ )=4.30%,w(Li+)=0.30 % and the equilibrium solids were Li2B4O7· 3H2O+K 2B4O7·4H2O+Li2CO3;The composition of the solution for F was w(CO2-3)=22.45%,w(B4O2-7)=1.88%,w(K+ )=29.96%,w(Li+ )=0.03% and the equilibrium solids were K2CO3·3/2H2O+K 2B4O7·4H2O+Li2CO3. K2CO3 possesses strong salting-out effect on K2B4O7,Li2CO3 and Li2B4O7. 相似文献
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研究在硫黄硫化体系下炭黑N774、环烷油和增粘树脂用量对丁基橡胶(IIR)胶料动态力学性能的影响。结果表明:随着炭黑N774用量的增大,IIR混炼胶的剪切储能模量(G′)和损耗因子(tanδ)增大,硫化胶的损耗峰值[tanδ最大值(tanδmax)]减小,损耗峰值温度[tanδmax温度(Tp)]向高温方向移动;随着环烷油用量的增大,IIR混炼胶的G减小,tanδ增大,硫化胶的tanδmax增大,Tp向低温方向移动;随着增粘树脂用量的增大,IIR混炼胶的G′减小,tanδ增大,硫化胶的tanδ-温度曲线呈双峰形态,Tp向高温方向移动。 相似文献
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负载型K2CO3/Al2O3二氧化碳吸收剂的碳酸化反应特性 总被引:2,自引:0,他引:2
The carbonation characteristics of K2CO3/Al2O3 supported sorbent for CO2 capture was investigated with thermogravimetric apparatus(TGA),X-ray diffraction(XRD),scanning electron microscopy analysis(SEM)and N2 adsorption.The results showed that the carbonation rate of K2CO3 before being loaded on Al2O3 was slow.However,the K2CO3/Al2O3 upported sorbent showed excellent carbonation performance.The difference in carbonation behavior between K2CO3 nd K2CO3/Al2O3 supported sorbent was analyzed from the microscopic view.The analytical reagent K2CO3 sample was of monoclinic crystal structure and could react quickly with H2O in the experimental carbonation environment to produce K2CO38226;1.5H2O,which was unfavorable to carbonation reaction.When K2CO3was loaded on Al2O3,the surface area and porosity of the sorbent was improved greatly.So the carbonation properties of the K2CO3/Al2O3 supported sorbent was also improved. 相似文献
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微生物燃料电池(MFC)在处理含硝酸盐(NO3--N)废水时具有同时产电和脱氮的潜力,寻找成本低且改善其产电脱氮性能的阴极修饰材料是MFC在含氮废水处理领域应用的关键。氧化亚铜/还原氧化石墨烯(Cu2O/rGO)复合材料具有良好的电化学性能,在替代铂基材料提高MFC性能方面具有一定的应用前景。本研究通过还原法制备了Cu2O/rGO复合材料,并对材料的结构和氧还原性能进行表征;同时,将其负载于阴极碳布后分析其电化学性能,并通过MFC的输出电压、功率密度和NO3--N的去除率探究Cu2O/rGO阴极对MFC产电和脱氮性能的强化作用;通过对反硝化相关酶活性和胞外聚合物的测定,探究Cu2O/rGO阴极强化MFC性能的机理。结果表明:Cu2O/rGO复合材料具有大量的介孔结构,能够为电子传递提供更多的通道,并且Cu2O/rGO复合材料具有良好的氧化还原可逆性;与Pt/C阴极相比,Cu2O/rGO阴极的交换电流密度升高33.53%,电子转移阻力降低65.53%;Cu2O/rGO-MFC在处理NO3-N废水时获得的最大平均输出电压(662.54 mV)、最大功率密度(26.27 mW/cm2)、平均库伦效率(32.02%)和NO3--N去除速率(83.33 mg NO3--N L/h)均高于Pt/C-MFC(485.33 mV,16.98 mW/cm2,7.38%,41.67 mg NO3--N L/h);Cu2O/rGO复合材料通过提高MFC阴极反硝化关键酶活性和类蛋白组分含量,改善了MFC的产电和脱氮性能。 相似文献
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The CuO/γ-Al2O3/cordierite catalyst, after being sulfated by sulfur dioxide (SO2) at 673 K, exhibits high activities for selective catalytic reduction (SCR) of nitrogen oxide (NO) with ammonia (NH3) at 573-723 K. The intrinsic kinetics of SCR of NO with NH3 over CuO/γ-Al2O3/cordierite catalyst has been measured in a fixed-bed reactor in the absence of internal and external diffusions. The experimental results show that the reaction rate can be quantified by a first-order expression with activation energy of 94.01 kJ•mol1 and the corresponding pre-exponential factor of 3.39×108 cm3•g1•s1 when NH3 is excessive. However, when NH3 is not enough, an Eley-Rideal kinetic model based on experimental data is derived with Ea of 105.79 kJ•mol1, the corresponding A of 2.94×109 cm3•g1•s1, heat of adsorption ΔHads of 87.90 kJ•mol1 and the corresponding Aads of 9.24 cm3•mol1. The intrinsic kinetic model obtained was incorporated in a 3D mathematical model of monolithic reactor, and the agreement of the prediction with experimental data indicates that the present kinetic model is adequate for the reactor design and engineering scale-up. 相似文献
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This paper reports on ¬¬¬a new microporous composite silica membrane prepared via acid-catalyzed polymeric route of sol-gel method with tetraethylorthosilicate (TEOS) and a bridged silsesquioxane [1, 2-bis(triethoxysilyl)ethane, BTESE] as precursors. A stable nano-sized composite silica sol with a mean volume size of ~5 nm was synthesized. A 150 nm-thick defect-free composite silica membrane was deposited on disk support consisting of macroporous α-Al2O3 and mesoporous γ-Al2O3 intermediate layer by using dip-coating ap-proach, followed by calcination under pure nitrogen atmosphere. The composite silica membranes exhibit molecular sieve properties for small gases like H2, CO2, O2, N2, CH4 and SF6 with hydrogen permeances in the range of (1-4)107 mol•m2•s1•Pa1 (measured at 200 C, 3.0×105 Pa). With respect to the membrane calcined at 500 C, it is found that the permselectivities of H2 (0.289 nm) with respect to N2 (0.365 nm), CH4 (0.384 nm) and SF6 (0.55 nm) are 22.9, 42 and >1000, respectively, which are all much higher than the corresponding Knudsen values (H2/N2 3.7, H2/CH4 2.8, and H2/SF6 8.5). 相似文献
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A new method called structural catastrophe analysis was applied to the analysis of pressure fluctuation time series with chaotic and fractal characteristics in gas-solids fluidized bed.In every type of fixed bed,bubbling bed,turbulent bed,fast fluidized bed and pneumatic conveying stage,pressure fluctuation signals were sampled and dynamic exponents were solved.The changes of Tmean and Tmax in different types of fluidized bed were analyzed and summarized.It was concluded that Tmean and Tmax can indicate different types of fluidized,and Tmax can also be recognized as a new characteristic parameter in addition to correlation parameters,LE exponent and K entropy. 相似文献
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Recombinant Escherichia coli BL21 is used to produce human-like collagen. The key constituents of media are optimized using response surface methodology (RSM). Before thermal induction, the highest biomass production and the lowest production of some hazardous by-products, especially acetic acid, were obtained in the media containing 0.085 mol∙L1 glucose and 0.019 mol∙L1 nitrogen (carbon-nitrogen ratio, 4.47︰1). After thermal induction, when the concentrations of glucose and nitrogen in the media were 0.065 mol∙L1 and 0.017 mol∙L1, respectively (carbon-nitrogen ratio, 3.82︰1), the productivity of human-like collagen per cell was the highest while that of acetic acid was the lowest. The extended analysis showed that the production of lactic acid and propionic acid increased while that of some intermediate acids of the tricarboxylic acid cycle decreased if the dose of glucose in-creased. 相似文献
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Considering limited success in target-hitting discharge from alcohol industry, our attention was directed toward a recycling use of distillery spentwash (DS) in cassava bioethanol production by using a two-stage up-flow anaerobic sludge blanket bioremediation (TS-UASBB). With the TS-UASBB, , COD, N and P in the effluent from the DS degraded significantly and their concentrations were kept at 0.2 g•L1, 2.0 g•L1, 1.0 g•L1 and 15 mg•L1, respectively, in 13 batch processes for water-recycled ethanol fermentation. With the effluent used directly as dilution water, no heat-resistant bacteria were found alive. The thirteen-batch ethanol production individually achieved 10% after 48 h fermentation. The starch utilization ratio and total sugar consumption were 90% and 99.5%, respectively. The novel water-recycled bioethanol production process with ethanol fermentation and TS-UASBB has a considerable potential in other starchy and cellulosic ethanol production. 相似文献
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张博;任冬云;董维煜;吴大鸣 《中国塑料》2009,23(3):95-97
采用布管法连续扩胀装置加工了聚氯乙烯(PVC)环向扩胀管和双向自增强管。实验结果表明,直径从40 mm扩胀到50 mm的环向扩胀管的环向拉伸强度提高了23 %~25 %,环向弹性模量提高了12 %。双向自增强PVC管的环向拉伸强度提高了26 %~33 %,弹性模量提高了30 %~33 %。通过对不同轴向拉伸比的双向自增强管的拉伸强度比较发现,随着轴向拉伸比的增加,环向拉伸强度逐渐提高。,环向弹性模量提高12%。双向自增强PVC管的拉伸强度提高了26%-33%,弹性模量提高了30%-33%。通过对不同轴向拉伸比双向自增强管的拉伸强度比较发现,随着轴向拉伸比的增加,环向拉伸强度逐渐提高。 相似文献
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构筑Z型异质结复合物是光催化领域解决电子-空穴对复合较快的常用方法,其独特的双光子体系能高效的提升光催化速率而备受关注。本文通过水热法原位构筑二维/二维(2D/2D)WO3/Ag:ZnIn2S4 Z型异质结复合物,并且利用透射电子显微镜(TEM)、X射线衍射(XRD)、X射线光电子能谱(XPS)、紫外-可见漫反射光谱(UV-Vis DRS)、光电化学(PEC)和荧光光谱(PL)对其微观形貌、物相结构、元素化学态和光电性能等进行表征分析,以及采用可见光(加λ>420 nm的滤光片)照射来评价2D/2D WO3/Ag:ZnIn2S4 Z型异质结复合物光解水制氢气和光降解甲基橙(MO)的催化性能。结果表明,在2D/2D WO3/Ag:ZnIn2S4 Z型异质结复合物中,随着Ag:ZnIn2S4的含量增加,光催化性能也显著增强。当Ag:ZnIn2S4的质量分数为35.0%时,复合物表现出最佳的制氢速率(158.93 μmol.g-1.h-1)与降解速率(0.18 min-1),这为基于WO3纳米片设计和构筑2D/2D Z型异质结复合物用于可见光催化制氢和污染物降解提供了新的见解。 相似文献
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The adsorption and mechanism of Re(VII) on resin D318 were studied using chemical methods and IR spectrometry. At pH 5.2, the static and dynamic saturation adsorption capacities were 351.4 and 366.5 mg&;#8226;g&;#61485;1, respectively. The adsorption behavior obeyed the Freundlich empirical equation and the adsorption rate constant k298 was 6.37×10&;#61485;4 s&;#61485;1. The desorption percentage was up to 99.7% when 2.0 mol&;#8226;L&;#61485;1 KSCN was used for dynamic desorption. 相似文献
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研究在溶聚丁苯橡胶(SSBR)和白炭黑配方体系中,橡胶操作油(简称操作油)用量对胶料性能的影响。结果表明:随着操作油用量的增大,胶料的门尼粘度、FL和Fmax减小,t5和t90延长;硫化胶的邵尔A型硬度、定伸应力和拉伸强度减小,拉断伸长率、撕裂强度和回弹值增大,耐磨性能和抗切割性能下降,弹性模量和粘性模量减小,0和70 ℃时的损耗因子变化不大,玻璃化温度(Tg)降低。SSBR胶料的门尼粘度、焦烧时间和转矩以及硫化胶的邵尔A型硬度、定伸应力、拉断伸长率、回弹值和Tg均与操作油用量之间具有高度线性相关性。 相似文献