Graphene oxide coated nanosheet-like γ-MnS@KB-S fabricated by spray drying for high energy density Li-S batteries

In order to prohibit the shuttle influence of lithium polysulfides in lithium sulfur battery, a kind of graphene oxide (GO) coated γ-MnS@KB-S (GO@MKB-S) composite cathode material was successfully fabricated. First of all, the γ-MnS@KB (MKB) composite powders were prepared via a solvothermal reaction, then a spray drying method was used to obtain GO@MKB-S composites, which displays core/shell nanostructure. SEM, TEM, XRD as well as Raman spectrum are implemented to look into the microstructures and the functions of the 2D nanosheet-like γ-MnS in setting in KB on the battery performance were carefully analyzed. It is demonstrated that electrochemical discharge capacity and rate performance are clearly improved by using GO@MKB-S composites compared to the cathode electrode of the GO coated KB-S (GO@KB-S). With a sulfur loading of 5 mg cm⁻², the cathode electrode of GO@MKB-S shows a considerable discharge capacity of 749.9 mAh g⁻¹ at 0.36 C. Additionally, the Li-S battery cycle retention of GO@MKB-S sample maintains 97.36% after 100 cycles and 78.69% after 200 cycles.     

鄂尔多斯盆地东部奥陶系风化壳古地貌特征嬗变及地质意义

鄂尔多斯盆地奥陶系风化壳气藏的发育与前石炭纪古地貌格局密切相关,目前主要认为发育西高东低的古地貌格局,自西向东依次发育岩溶高地、岩溶斜坡及岩溶盆地的古地貌单元。但随着勘探的深入,在盆地东部地区奥陶系早期认为的岩溶盆地区已经发现了大量代表了较强岩溶作用的岩溶角砾岩等地质现象,因此有必要从古地貌动态演化角度重新认识影响岩溶古地貌发育的内外因素,研究地质历史中奥陶系风化壳古地貌的性质嬗变,指导对区域储集空间发育规律的进一步研究与预测。以盆地东部奥陶系顶部风化壳古地貌恢复为目的,综合研究了古地理背景、残留地层厚度、古岩溶特征等因素。认为早期在盆地中东部存在一个大范围的岩溶古高地,形成了岩溶型储集空间,但后期盆地东部逐渐演变为古岩溶盆地,形成了现今的前石炭纪古地貌格局,并造成早期形成的溶蚀类储集空间被大量充填,整体储层较致密,但由于溶洞塌陷形成的裂缝网络沟通了白云岩晶间孔储集空间,局部仍然可以保留有较好的储层,是值得重视的勘探目标。     

2015—2019年江西省毒蕈中毒病例流行病学特征分析

目的 分析江西省毒蕈中毒病例的流行病学特征,为毒蕈中毒科学防控提供参考依据。方法 通过“食源性疾病监测报告系统”和“食源性疾病暴发监测系统”查询2015—2019年江西省毒蕈中毒病例,对其流行病学特征进行描述性分析。结果 2015—2019年江西省共报告毒蕈中毒病例1 354例,年均报告发病率为0.59/10万,病死率为1.6%(21/1 354),多数病例集中发生在5～10月份。中毒病例主要集中在上饶、宜春、九江地区的部分县(区)。40岁及以上人群为主要发病群体,占59.5%(806/1 354);6岁及以下儿童和60岁及以上人群病死率最高,分别为6.3%(5/80)和2.4%(8/327),且以农民为主。93.3%(1 263 /1 354)的中毒病例及95.2%(20/21)的死亡病例发生在家庭,86.6%(1 172/1 354)的毒蕈来源为自采,临床表现以胃肠道症状为主。结论 江西省毒蕈中毒具有季节性、区域性的特点,应针对重点区域、重点人群进行宣传教育,应加强基层医务人员培训,减少中毒病例的死亡。     

Dynamically Updating XML Data: Numbering Scheme Revisited

Almost all existing approaches use certain numbering scheme to encode XML elements to facilitate query processing when XML data is stored in databases. For example, under the most popular region-based numbering scheme, the starting and ending positions of an element in a document are used as the code to identify the element so that the ancestor/descendant relationship between two elements can be determined by merely examining their codes. While such numbering scheme can greatly improve query performance, renumbering large amount of elements caused by updates becomes a performance bottleneck if XML documents are frequently updated. Unfortunately, no satisfactory work has been reported for efficient update of XML data. In this paper, we first formalize the XML data update problem by defining the basic operators to support most XML update queries. We then present a new numbering scheme that not only requires minimal code-length in comparison with existing numbering schema but also improves update performance when XML data is frequently updated at arbitrary positions. The fundamental difference between our new scheme and existing ones is that, instead of maintaining the explicit codes for elements, we only store the necessary information and generate the codes when they are needed in query processing. In addition to present the basic scheme, we also discuss some optimization techniques to further reduce the update cost. Results of a comprehensive performance study are provided to show the advantages of the new scheme.     

(Semi-)blind channel estimation for space time block coded system with transmit diversity

This paper deals with a blind channel estimation method for space-time coded block transmission system. By concatenating the real part and imaginary part of the received signal to form an elongated vector, we derive an equivalent input–output system model. Then channel state information (CSI) is blindly estimated using subspace method, utilizing only the redundancy inherent in space-time block coding (STBC) and cyclic prefix (CP). The estimation ambiguity, which is common to all blind methods, is analyzed in detail and we prove that there only exist four scalar indeterminacies. Three effective methods to eliminate the ambiguities are also proposed. Compared with other blind channel estimation methods for space time systems, this method needs neither redundant precoding nor oversampling, and thus has higher data rate. Besides, this method is robust to channel order overestimation, which is effectively demonstrated by numerical simulations. This work was supported by NSFC (60496310, 60672093), NSFJS(BK2005061) and BK2005061.     

以回收聚酯为主要原料的PET/PE合金片材的研制及应用

以自制接枝共聚相容剂,将回收聚对苯二甲酸乙二醇酯（rPET）分别与全新线性低密度聚乙烯（PE?LLD）和回收聚乙烯（rPE?HD）共混改性,采用具备免干燥和侧面强制喂料系统的同向双螺杆挤出机熔融挤出rPET/PE合金片材（rPET与PE质量比为80∶20）,研究了不同厚度合金片材的性能。结果表明,使用rPET制备的合金片材产品外观品质保持较好; rPET/PE合金片材具有良好的力学性能,其中拉伸强度大于39 MPa,断裂伸长率随片材厚度增加而递减,厚度为2.5 mm的rPET/rPE合金片材拉伸强度为39.7 MPa,断裂伸长率为21 %,冲击强度为12 kJ/m²,适合应用于吸塑箱包、土工格室等;免干燥和侧面强制喂料系统,可以减少合金片材加工流程,节约能源,设备产量提了117 %。     

相转移催化合成对氯苄叉丙酮

以对氯苯甲醛和丙酮为原料，以PSTEA作相转移催化剂合成对氯苄叉丙酮。讨论了影响综合的反应主要因素，获得了最佳反应条件，在此条件下，产品收率可达97．7％。该合成方法工艺简单，收率较高，催化剂催化活性高。     

Activatable Protein Nanoparticles for Targeted Delivery of Therapeutic Peptides

Clinical translation of therapeutic peptides, particularly those that require penetration of the cell membrane or are cytolytic, is a major challenge. A novel approach based on a complementary mechanism, which has been widely used for guided synthesis of DNA or RNA nanoparticles, for de novo design of activatable protein nanoparticles (APNPs) for targeted delivery of therapeutic peptides is described. APNPs are formed through self‐assembly of three independent polypeptides based on pairwise coiled‐coil dimerization. They are capable of long circulation in the blood and can be engineered to target diseases. Peptides to be delivered are incorporated into APNPs and released into the disease microenvironment by locally enriched proteases. It is demonstrated that APNPs mediate efficient delivery of NR2B9c, a neuroprotective peptide that functions after cell penetration, and melittin, a cytolytic peptide that perturbs the lipid bilayer, for effective treatment of stroke and cancer, respectively. Due to their robust properties, simple design, and economic costs, APNPs have great potential to serve as a versatile platform for controlled delivery of therapeutic peptides.     

基于PU2RC的下行多用户MIMO系统多模发送方案

针对有限反馈下行多用户多输入多输出（multiple-input multiple-output, MIMO）系统,提出了一种基于每用户正交码率控制（per user unitary rate control, PU2RC）的多模发送方案。该方案通过最大化系统的遍历和速率来自适应地选取发送模式,即系统同时传输的并行数据流数目。由于直接计算系统的遍历和速率比较困难,论文推导出它的一个上界,并以最大化该上界来简化发送模式的选取。仿真结果表明,所提方案的遍历和速率性能优于传统PU2RC方案,特别当系统中用户数不大或者信噪比较高时,性能有明显的改善。