三元体系PEG 4000-Cs2SO4-H2O在25,35和45 ℃时的相平衡研究

采用自制的相平衡研究装置，测定了PEG 4000-Cs2SO4-H2O三元体系在25，35和45℃时的等温平衡溶解度，同时给出了该体系的完整相图，在相图中观察到6个相区。结果表明，该体系双液相区随着温度的升高略有增加，结线的斜率也随温度的升高而增大。用四参数方程y=a bx^0.5 cχ dχ^2对该体系的双液线进行了拟合，拟合结果较好。用Othmer-Tobias方程和Bancroft方程对该体系结线的实验数据进行了关联，所有线性相关系数均大于0．98。热重分析确定平衡固相组成为无水硫酸铯。     

Enzymatic biosensor for nitrite detection based on direct electron transfer by CPO-ILEMB/Au@MoS2/GC

Journal of Applied Electrochemistry - A novel nitrite electrochemical biosensor is constructed by glassy carbon electrodes (GC) coated by chloroperoxidase (CPO) -Au nanoparticles-MoS2 nanoflowers...     

医用电刺激器的研制

本文着重介绍了如何应用可编程定时器，单稳电路、Ｄ／Ａ转换电路来实现计算机对医用电刺激器刺激频率，脉宽和电流强度的控制。     

Modal 11.8tex纱的生产实践

探讨Modal 11.8 tex纱的生产工艺。根据Modal纤维的性能特点,通过严格选用原料,采用多批号,按排队法进行配棉,防止色差;各工序合理配置工艺参数,并严格控制温湿度,保证粗纱在细纱处于放湿状态,络筒保持较高的相对湿度;正确调整细纱V型牵伸后区隔距以及缩短钢丝圈调换周期,较好地解决了后区牵伸力过大和短绒、棉结增多等问题,结果使Modal 11.8 tex纱顺利生产,质量较好地满足了使用需求,获得了良好的经济效益。     

水热法制硫氧镁晶须最优工艺条件研究

以工业七水硫酸镁和烧碱为原料,采用低温水热法新工艺进行中试制硫氧镁晶须,将制得的产物用X射线衍射和红外光谱进行表征,并讨论了温度、浓度、搅拌强度和后处理等对产物的影响,获得了最优的工艺条件.结果表明该绿色循环工艺制备硫氧镁晶须,流程简单、获得的晶须性能好、物料利用率高、成本低,且对环境友好.     

基于灰关联矢量投影法的黑启动方案优选

制定科学合理的黑启动方案对于实现电力系统大面积停电后的快速恢复具有重要的现实意义。提出了基于灰关联矢量投影法的黑启动方案评估模型,通过层次分析法确定指标的主观权重,采用熵权法确定指标的客观权重,基于加法原理融合主客观权重信息得到各指标的综合权重值。结合灰色系统理论和矢量投影原理,计算评价对象的优属度,实现黑启动方案优选。实际电网的应用实例证明了该方法可以为黑启动恢复提供科学合理的决策参考。     

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为提高整体开发效率，降低开发成本，长庆苏里格气田应用了小井眼钻井技术。针对苏里格气田的具体情况，在小井眼钻井工艺方面，进行了包括井身结构优化、套管优选、井壁稳定性控制、地层出水预测等多方面的技术研究。2003年共进行了4口小井眼井的施工,其中包括2口天然气欠平衡钻井,通过小井眼天然气欠平衡钻井实践表明，应用该项技术，与常规钻井相比较，机械钻速可以得到大幅度提高，是提高钻井速度、缩短钻井时间的有效途径。     

MEASUREMENT AND CORRELATION OF LIQUID-LIQUID EQUILIBRIA FOR TERNARY SYSTEMS OF WATER+RUBIDIUM CHLORIDE+PROPANOL

Liquid-liquid equilibria for ternary systems of water + rubidium chloride + 1-propanol and water + rubidium chloride + 2-propanol were measured at T = 298.15, 308.15, and 318.15 K. The experimental data were correlated using Othmer-Tobias and Bancroft correlations. The salting-out effect of 1-propanol in the two-liquid region was greater than that for 2-propanol, but the effect of temperature on the equilibrium was not significant.     

Quaternized magnetic microspheres for the efficient removal of reactive dyes

In this paper, a novel quaternized magnetic resin, NDMP, was prepared and characterized. Two reactive dyes (RDs), Orange G (OG) and red RWO, were used as a small-molecular RD and large-molecular RD, respectively, to investigate their adsorption on NDMP. A common quaternized magnetic resin, MIEX, was selected for comparison. The adsorption kinetics of OG onto both resins and the adsorption kinetics of RWO onto NDMP followed pseudo-second-order kinetics, whereas the adsorption of RWO onto MIEX was better fitted by pseudo-first-order kinetics. The experimental data illustrated that the equilibrium adsorption amount of both RDs onto NDMP (1.9 mmol OG/g, 0.70 mmol RWO/g) was twice as large as that on MIEX (1.0 mmol OG/g, 0.35 mmol RWO/g). The Langmuir equation and the Freundlich model fit the isotherm data for OG and RWO adsorption, respectively. The adsorption of OG on the NDMP and MIEX resins declined in the presence of NaCl or Na₂SO₄. The effects of the salts on the adsorption of RWO were different. The recyclability of NDMP and MIEX were also evaluated. This work provides a reusable efficient adsorbent for the removal of RDs.     

CsCl-PEG400-H2O三元体系在15,25和35℃时的等温溶解度、密度及折光率研究

采用半微量相平衡测定装置和高精度密度-折光率测定仪,精确测定了CsCl-PEG 400-H2O三元体系在15,25和35℃3个温度下不同组分百分比溶液的折光率和密度数据,通过关联密度和折光率数据获得了CsCl在上述温度下的等温溶解度.对饱和体系的溶解度研究表明:在同一温度下CsCl的溶解度随聚乙二醇质量分数的增加而减小;在不同温度下CsCl的溶解度随温度的升高而增大.采用经验方程lnS=A1+A2ω2+A3ω2(2)+A4ω2(3)对饱和体系的溶解度进行了关联,效果较好.对不饱和体系的研究表明:当盐含量一定时,随着醇水比例的增加,体系的密度不断增大,折光率也随盐含量增加而增大;当醇水质量比一定时,体系的密度和折光率随盐含量的增加而增大,对不饱和体系的密度和折光率用经验方程Y=(A0+A1ω2+A2ω1+A3ω1ω2+A4ω2ω1(2))×exp[A5(ω1/ω3)+A6(ω1/ω3)2]进行拟合,拟合效果较好,同时给出了体系的盐析率曲线.本研究不仅为溶液化学提供了基础数据,也为混合溶液中盐和醇的分离纯化提供一种新的方法和思路,对CsCl进一步的应用、开发和研究具有一定的参考价值.