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31.
Junzhe Li Shao-hua Luo Yang Sun Jiayu Li Jun Zhang Ting-Feng Yi 《Ceramics International》2019,45(4):4849-4856
Sodium-substituted LiMnPO4/C/reduced graphene oxide (LNMP@rGO) was synthesized in this study via freeze drying and carbon thermal reduction method with graphene oxide as carbon source. Sodium ion doping is optimized and rGO effects are evaluated by XRD, SEM, TEM, BET, Raman, and electrochemical performance measurements. Well-distributed nanoparticles with average size of ~50?nm are evenly distributed on the surface or intercalation between rGO layers, resulting in a porous ion/electronic conductive network. Compared to 122.3?mA?h?g?1 in unmodified LNMP, the best LNMP@rGO (20?mg rGO) exhibits an excellent initial discharge capacity of 150.4?mA?h?g?1 at 0.05?C at 122.9% of the initial capacity. The capacity retention rate is 95.8% of the initial capacity after 100 cycles at 1?C. Capacity of 101.2?mA?h?g?1 is preserved even at rates as high as 10?C. 相似文献
32.
Yajing Zhao Xin Min Minghao Fang Xiaowen Wu Yan’gai Liu Zhaohui Huang 《International Journal of Applied Ceramic Technology》2019,16(4):1596-1605
Lanthanum hexaaluminate is a promising candidate to establish yttria partially stabilized zirconia as a thermal barrier coating material for super alloy due to their remarkable stability and thermophysical performance. In order to understand the relationship between the structure and properties and gain new low thermal conducting materials, the LnMgAl11O19 (LnMA, Ln: La, Pr, Nd, Sm, Eu, Gd) materials were synthesized firstly and further used to produce the LnMA ceramics. With the increasing relative atomic mass of the replaced Ln3+ ions from La to Gd, the lattice parameters and grain sizes of the LnMA platelets decrease, while the mechanical properties increase, and the thermal physic properties decrease. The GdMgAl11O19 ceramics obtain the lowest thermal conductivity with the value of 1.91-1.78 W/m K in the range from room temperature to 800°C, which could be considered as a promising candidate for application in thermal barrier coating materials. These results could further provide reference for developing novel materials lower thermal conductivity. 相似文献
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为了改善工业硝酸铵的吸湿结块性能,通常会加入添加剂(有机包覆剂或无机改性剂),而工业硝酸铵作为乳化炸药的主要原料,其添加剂对乳化炸药的制备和性能会产生影响。因此,分别对采用有机包覆剂蜡的泰国产工业硝酸铵和采用无机改性剂的俄罗斯产工业硝酸铵,开展了制备现场散装乳胶基质的工业试验。结果表明:两类工业硝酸铵均可作为乳化炸药原材料使用,但有机包覆剂会沉入水相罐底部或粘附在输送管道内壁,对水相和乳胶基质制备造成不利影响,因此需要在水相制备环节分离去除包覆剂蜡;硝酸镁、硝酸钙等无机改性剂对乳胶基质制备无影响,但生产的乳胶基质稳定性较差,通过调整乳化剂的种类和配比以及乳化器的转速可得到一定改进。 相似文献
38.
采用UDP650型闭合场非平衡磁控溅射系统在硅片及316不锈钢基底表面制备了不同掺杂设计的类金刚石涂层(DLC、Cr/DLC和WC/DLC),通过SEM、Raman、硬度仪和划痕仪研究了涂层的结构及力学性能,利用多功能摩擦试验机考察了涂层在大气及海水环境下的摩擦学性能。结果表明,Cr或WC掺杂能显著促进DLC涂层的石墨化,同时提高涂层的结合力及韧性。在摩擦磨损试验中,由于海水的润滑作用,3种涂层在海水环境下的摩擦因数及磨损率均低于大气环境。同时,WC/DLC在3种涂层中表现出最佳的摩擦学性能,这取决于其高的石墨化程度,良好的结合力及优异的韧性。 相似文献
39.
ABSTRACTA comprehensive literature review of the existing techniques for removing and repairing of damaged thermal barrier coatings is presented, with the focus on top ceramic coats. The advantages and disadvantages of each technique are compared and assessed. The review shows that there is not a universal method applicable to all coating systems. The selection of the coating removal and repair process must be specific to damaged coating systems, based on their composition, type of damages, and available resources. This review will provide some inside look at various approaches in an effort to meet the different coating repair needs. 相似文献
40.
Jian Wang Shuai Huang Mingyang He Peihua Wangyang Yangfan Lu Hongjian Huang Lei Xu 《Ceramics International》2018,44(7):7656-7662
The ceramic coatings on the surface of aluminum alloy substrates with micro-grooves have been successfully fabricated in the silicate solution via micro-arc oxidation (MAO) approach. Microstructure characterization showed that the larger main discharge channels were located in the center of micro-groove, the smaller secondary discharge channels were located on both sides of main discharge channel; and a few irregular micro-pores existed in the vicinity of all discharge channels, which were mainly cause by the rapid cooling and solidification of discharge channels hindering the removal of gases produced via reaction. Moreover, the growing direction of coating in the initial stage was mainly outward-growth and resulted in the formation of inverted triangle coating structure, which was due to the sharp-angled effect. But in the final growing stage, the inward-growth behavior played a key role owing to the spark transfer. According to above results and discussion, the formation of smooth, uniform and homogeneous ceramic coating on the surface of whole trapezoidal micro-groove substrate contained four stages: anodic oxidation growth, sharp corner rapid growth, coating homogenization and groove self-filling. 相似文献