低温溶液缩聚法制备聚间苯二甲酰对苯二胺

采用低温溶液缩聚法制备了聚间苯二甲酰对苯二胺(PPIA),讨论了单体浓度、单体物质的量配比、反应温度等因素对聚合反应的影响,并用红外光谱(IR)、热重分析(TG)、X射线衍射(XRD)、扫描电镜(SEM)对实验产物进行了测定。红外检测出的特征峰符合PPIA的结构特征,热重测得热分解速率最大温度在520℃左右,X射线衍射表明聚合物有明显结晶现象,并且扫描电镜显示下的聚合物结构聚集状态良好。     

Analytical framework for ex-post evaluation of transport projects: Lessons learnt on retrospective CBA

This study deals with the ex-post evaluation of ten major transport projects which were co-financed by the European Regional Development Fund and the Cohesion Fund in the period 2000–2013 and located across nine EU Member States. The original contribution of this study is represented by the combination of the traditional ex-post Cost–Benefit approach with a qualitative analysis. Specifically, a retrospective Cost–Benefit analysis is used to quantify the benefits and costs of the projects, then interviews to relevant stakeholders were carried out. Ex-post CBA, when appropriately implemented and integrated with qualitative evidence, represents a powerful tool for supporting decision-making processes and for policy lessons.     

Multi-factor impact mechanism on combustion efficiency of a hydrogen-fueled micro-cylindrical combustor

As it is important to achieve higher combustion efficiency for applications of micro-cylindrical combustor, the multi-factor impact mechanism on the combustion efficiency of a hydrogen-fuelled micro-cylindrical combustor is investigated in this work. Firstly, six factors such as hydrogen/air equivalence ratio, inlet velocity, inlet temperature, wall thermal conductivity, wall emissivity and convective heat transfer coefficient of outer wall and five levels of each factor are determined. Orthogonal design table L₂₅(5⁶) is introduced to arrange cases. Secondly, grey relational analysis is adopted to investigate the effects of the six factors on combustion efficiency. Finally, the results of grey relational analysis are validated by analysis of variance. Based on grey relational analysis and analysis of variance, it is determined that the impact ranking from the largest to the smallest is hydrogen/air equivalence ratio, inlet velocity and inlet temperature, followed by the other three factors. The impact of wall thermal conductivity, convective heat transfer coefficient of outer wall and wall emissivity is considered to be equal due to their difference of impact on combustion efficiency is very small. This work provides us significant reference for optimizing combustion efficiency of a hydrogen-fuelled micro-cylindrical combustor.     

《电子显微分析》课程教学内容及方法研究

《电子显微分析》课程是目前高校材料类和生命科学类专业一门重要的专业选修课。根据《电子显微分析》课程特点，剖析了该课程的教学现状以及存在的问题。针对这些问题，在教学内容的设定、教学方式的调整及实践性教学的考核等方面做了一些思考。     

基于组合赋权-集对分析的煤矿煤尘爆炸危险性评价研究

针对目前煤尘爆炸危险性评价研究较少、各评价因素选择偏差较大的问题,通过分析煤尘爆炸特性,提出以煤尘可爆性危险、煤尘爆炸浓度危险、点火源危险3个必要条件为一级指标,煤质变异程度、挥发分、水分、灰分等14个二级指标,以层次分析法确定各指标的主观权重,以熵权法确定各指标的客观权重,利用乘法归一化方法对各指标的组合权重进行计算,构建集对分析-组合赋权煤尘爆炸危险性评价模型,并将该模型与已较成熟的改进FAHP模型、模糊事故树模型、灰色聚类评估体系、未确知测度评价模型一同应用于济宁某矿的煤尘爆炸危险性评价过程中,结果显示:集对分析-组合赋权评价模型、改进FAHP模型、灰色聚类评估体系评价结果为一般危险等级,模糊事故树模型的评价结果为较安全等级,集对分析-组合赋权煤尘爆炸危险性评价模型评价结果与改进FAHP模型、灰色聚类评估体系、未确知测度评价模型的评价结果一致,该模型对煤尘爆炸危险的评价具有较好的适用性。     

Turning a Digital Camera into an Absolute 2D Tele‐Colorimeter

We present a simple and effective technique for absolute colorimetric camera characterization, invariant to changes in exposure/aperture and scene irradiance, suitable in a wide range of applications including image‐based reflectance measurements, spectral pre‐filtering and spectral upsampling for rendering, to improve colour accuracy in high dynamic range imaging. Our method requires a limited number of acquisitions, an off‐the‐shelf target and a commonly available projector, used as a controllable light source, other than the reflected radiance to be known. The characterized camera can be effectively used as a 2D tele‐colorimeter, providing the user with an accurate estimate of the distribution of luminance and chromaticity in a scene, without requiring explicit knowledge of the incident lighting power spectra. We validate the approach by comparing our estimated absolute tristimulus values (XYZ data in ) with the measurements of a professional 2D tele‐colorimeter, for a set of scenes with complex geometry, spatially varying reflectance and light sources with very different spectral power distribution.     

Porous ceramics with tailored pore size and morphology as substrates for coral larval settlement

The growing demand for stony corals as ornamental aquarium animals requires defined aquacultural breeding strategies. For the sexual propagation of corals, material substrates are needed, that attract larvae and support their settlement and development. In this study, five types of highly porous ceramic materials were developed following the example of coral skeleton. The applicability of these settlement substrates was tested using larvae of the stony coral Pocillopora damicornis. Partial sintering of pressed clay pellets, freeze casting of clay and alumina-mullite based slurries and direct foaming of high alkane phase emulsified suspensions (HAPES) using alumina were employed. By the addition of mm-sized spherical polystyrene beads as sacrificial templates during freeze casting (alumina-mullite), superficial pores in the size of the larvae were created. The inorganic substrates featured open porosities between 35% (pressed clay) and 83% (foamed alumina), pore sizes ranging from nm to mm-scale and pore morphologies dominated by interparticle porosity (pressed), lamellar pores (freeze casting) and cellular pore types (direct foaming). The ceramic substrates were incubated in artificial sea water for 3 months to induce necessary biofilm formation and algae growth. Afterwards, individual substrates were exposed to 5 coral larvae, and their settlement behavior was monitored over 14 days. At the end of this period, all ceramic materials were successfully accepted as settlement substrates, with a mean settlement rate of 46.2%, and no significant differences between the substrate types. On samples with large surface superficial pores, a significantly reduced survival of settled larvae (79%) compared to the other porous materials (93–98%) was determined, suggesting a non-ideal surface topography. While alumina foam samples (HAPES) exhibit the most promising results in terms of settlement and survival of larvae, clay-based substrates provide a more economic solution for the sexual propagation of corals in aquaculture.     

Possible origin of ferromagnetism in antiferromagnetic orthorhombic-YFeO3: A first-principles study

Rare-earth orthoferrites (RFeO₃) are well-known for the antiferromagnetic ground state. However, some of the recent experimental results suggest that the few members of RFeO₃ family possess ferromagnetism. In the present investigation we report the possible origin of ferromagnetism in antiferromagnetic YFeO₃ using density functional theory. For this purpose, we have considered pure as well as self-doping in YFeO₃ i.e. by considering the point defect at Y, Fe and O sites. Our finding suggests that the point defects in YFeO₃ results in the mixed-valence state of Fe, which may result in ferromagnetism through Zener double exchange mechanism.     

基于GRA-GRNN模型的露天金属矿爆破后矿岩界线位移分析

为了避免露天金属矿爆破后导致爆堆边缘矿石品位贫化损失,需要根据最低品位阈值重新计算矿岩边界,而影响矿岩边界发生改变因素众多,需要确定主要影响因素。因此,利用爆堆爆破前地形方向和爆堆地质数据,构建灰色关联-广义回归神经网络模型(GRA-GRNN)分析爆堆矿岩边界变化主要影响因素。首先对爆堆钻孔品位数据使用析取克里金法进行空间插值,并根据矿山工艺最低品位阈值提取爆破前的矿岩边界;其次,将爆破前后的数字DEM模型进行求差,求得爆破后的爆堆数字DEM模型,并构建爆破前后爆堆数字DEM模型空间分布椭圆,从而确定爆堆爆破后的水平形变方向;对影响爆堆爆破后形变的可能因素进行提取,并应用GRA-GRNN模型选取主要影响因素及对其强度进行分析,并将其结果与BP神经网络模型预测结果进行了对比。从实验结果可知,影响爆堆爆破后形变强度排前三的因素为:爆破前地形方向、爆孔排距和列距,强度分别为0.880、0.760和0.755,预测结果优于BP模型。     

基于熵权-灰色关联分析的电动汽车充电基础设施PPP项目风险评价研究

电动汽车充电基础设施PPP项目的建设和实施,不仅可以有效缓解政府财政和管理压力,还可以借助社会资本先进的管理运营经验,提高充电服务供给效率,实现双赢。但是,电动汽车充电基础设施PPP项目具有投资大、特许运营期长等特点,同时还涉及多个项目参与者,关系复杂,潜在的风险因素较多。文章通过文献梳理,首先识别出了电动汽车充电基础设施PPP项目潜在的风险因素,从宏观、中观、微观三个层次建立了基于项目全生命周期的风险评价指标体系,然后建立了基于熵权-灰色关联分析的项目风险评价模型。最后,以T市电动汽车充电基础设施PPP项目为例进行了实证分析,并根据风险评价的结果,从不同项目参与方的角度提出了风险应对的策略。