全文获取类型
收费全文 | 135537篇 |
免费 | 13196篇 |
国内免费 | 7580篇 |
学科分类
工业技术 | 156313篇 |
出版年
2024年 | 478篇 |
2023年 | 2312篇 |
2022年 | 4336篇 |
2021年 | 6022篇 |
2020年 | 4659篇 |
2019年 | 3627篇 |
2018年 | 4017篇 |
2017年 | 4502篇 |
2016年 | 3943篇 |
2015年 | 5808篇 |
2014年 | 7452篇 |
2013年 | 8633篇 |
2012年 | 10123篇 |
2011年 | 10943篇 |
2010年 | 9613篇 |
2009年 | 9022篇 |
2008年 | 8953篇 |
2007年 | 8320篇 |
2006年 | 7939篇 |
2005年 | 6327篇 |
2004年 | 4429篇 |
2003年 | 3753篇 |
2002年 | 3723篇 |
2001年 | 3181篇 |
2000年 | 2810篇 |
1999年 | 2448篇 |
1998年 | 1812篇 |
1997年 | 1423篇 |
1996年 | 1309篇 |
1995年 | 985篇 |
1994年 | 830篇 |
1993年 | 581篇 |
1992年 | 496篇 |
1991年 | 375篇 |
1990年 | 267篇 |
1989年 | 237篇 |
1988年 | 141篇 |
1987年 | 111篇 |
1986年 | 89篇 |
1985年 | 50篇 |
1984年 | 32篇 |
1983年 | 32篇 |
1982年 | 41篇 |
1981年 | 31篇 |
1980年 | 45篇 |
1979年 | 12篇 |
1965年 | 2篇 |
1960年 | 2篇 |
1959年 | 17篇 |
1951年 | 10篇 |
排序方式: 共有10000条查询结果,搜索用时 17 毫秒
11.
Shilin Du Yichen Dong Feiqiang Guo Beile Tian Songbo Mao Lin Qian Chengyun Xin 《International Journal of Hydrogen Energy》2021,46(27):14138-14147
The potential of using high metals containing coal gangue and lignite to prepare high-activity coal char-based catalysts is investigated for effective biomass tar decomposition. Loose structure and rough surface are formed for these char-based catalysts with heterogeneous distribution of a large number of inorganic particles. In the biomass tar decomposition, the performance of the coal char-based catalysts is significantly influenced by the content of the metals in the raw materials and coal gangue char (GC) with the ash content as high as 50.80% exhibits the highest activity in this work. A high biomass tar conversion efficiency of 93.5% is achieved at 800 °C along with a significant increase in the fuel gas product. During the five-time consecutive tests, the catalytic performance of GC increases a little at the second or third times reuse and remains relatively stable, showing the remarkable stability of the catalyst in biomass tar decomposition applications. 相似文献
12.
Xinming Ren Beiyue Ma Gaofeng Fu Fan Qian Guoqi Liu Jingkun Yu Yawei Li 《Ceramics International》2021,47(14):19959-19969
The recycling of solid waste is a win-win solution for humans and nature. For this purpose, magnesite tailings and silicon kerf waste were employed to prepare MgO–Mg2SiO4 composite ceramics by solid-state reaction synthesis in the present work. Then, effects of sintering temperature and raw material ratio on as-prepared ceramics were systematically studied. As-prepared ceramics showed improvement in their relative density (from 47.55%–68.12% to 90.96%–95.25%) and cold compressive strength (from 7.34–118.66 MPa to 303.39–546.65 MPa) with the increase in sintering temperature from 1300 to 1600 °C. In addition, it was found that Si promoted synthesis process of Mg2SiO4 phase through transient liquid phase sintering and Fe2O3 accelerated sintering process through activation sintering. Consequently, the presence of Mg2SiO4 phase effectively improved the density and strength of MgO–Mg2SiO4 composite ceramic, while reducing its thermal conductivity. This work provides a potential reutilization strategy for magnesite tailings, and as-prepared products are expected to be applied in fields of construction, metallurgy, and chemical industry. 相似文献
14.
Sumeng Wei Yining Xu Baohua Kong Meijuan Wang Jingming Zhang Qian Liu Yuling Yang 《International Journal of Food Science & Technology》2022,57(8):5024-5035
The present work was conducted to illustrate the mechanism of gel formation of myofibrillar proteins (MPs) under different microwave heating times. The results showed that the denaturation enthalpy (ΔH) of the MPs significantly decreased when the heating time increased from 3 to 9 s and then completely disappeared as the heating time progressed, indicating that the MPs gradually denatured and subsequently aggregated with increasing heating time, which was further verified by the changes in the secondary structure, electrophoretic bands, and gel properties (e.g., water holding capacity and textural profiles) of the MPs. Microstructural images indicated that the MP gel formed under 12 s had the most compact network, indicating that extended microwave heating time could induce quality deterioration of MP gels. Moreover, the hydrophobic forces, electrostatic forces, and disulphide bonds of the MPs gradually intensified with increasing microwave heating time, suggesting that both non-covalent and covalent bonds could promote molecular denaturation and subsequent aggregation of MPs. In addition, correlation analysis revealed that the changes in the molecular conformation of MPs induced by different microwave heating times could effectively regulate the formation of MP gels and their related properties. 相似文献
15.
目的:研究抗坏血酸(ascorbic acid,AsA)-还原型谷胱甘肽(reduced glutathione,GSH)循环代谢在水杨酸处理采后甜瓜诱导的过量H2O2清除过程中的作用。方法:用4 mmol/L水杨酸浸泡‘玉金香’厚皮甜瓜10 min,测定处理后果实常温贮藏过程中丙二醛(malondialdehyde,MDA)含量,分析活性氧的积累水平、超氧化物歧化酶(superoxide dismutase,SOD)和过氧化氢酶(catalase,CAT)活力,以及AsA-GSH循环过程相关酶活力及产物和底物含量。结果:水杨酸处理降低了果实MDA含量,第10天处理组MDA含量较对照组降低14.6%;显著提高了果实O2-·的产生速率和H2O2含量(P<0.05),其中处理后第2天O2-·的产生速率高出同期对照组的1.9 倍,第6天H2O2含量高出对照组果实29.7%;提高了果实SOD活力,但抑制了CAT活力,说明H2O2的清除可能是依赖于除酶促系统外的其他系统。此外,水杨酸处理提高了果实抗坏血酸过氧化物酶、单脱氢抗坏血酸过氧化物酶、脱氢抗坏血酸还原酶和谷胱甘肽还原酶的活力,增加了AsA和氧化型谷胱甘肽的含量,降低了脱氢抗坏血酸和GSH的含量。结论:水杨酸处理诱导了厚皮甜瓜果实的氧爆,抑制了MDA产生,由水杨酸诱导产生的过量H2O2主要依靠AsA-GSH循环系统清除。 相似文献
16.
我公司1#生产线的窑头使用布袋收尘器,型号:HMMC391-4×4,处理风量:1 350 000 m3/h,过滤风速<0.9 m/min,收尘器风室4 排×4 列。投入使用3个月后停机检查,发现第一排4 个风室的滤袋较多底部被磨穿,主要集中在灰斗四周的前3 环区域,前两排风室其他位置的滤袋也较多出现异常磨损,但后
两排风室的滤袋却完好无损。 相似文献
17.
Fangjun Zhu You Shi Guorong Hu Zhongdong Peng Yanbing Cao Qian Sun Zhichen Xue Yinjia Zhang Ke Du 《Ceramics International》2021,47(3):3070-3078
Titanium and boron are simultaneously introduced into LiNi0.8Co0.1Mn0.1O2 to improve the structural stability and electrochemical performance of the material. X-ray diffraction studies reveal that Ti4+ ion replaces Li+ ion and reduces the cation mixing; B3+ ion enters the tetrahedron of the transition metal layers and enlarges the distance of the [LiO6] layers. The co-doped sample has spherical secondary particles with elongated and enlarged primary particles, in which Ti and B elements distribute uniformly. Electrochemical studies reveal the co-doped sample has improved rate performance (183.1 mAh·g-1 at 1 C and 155.5 mAh·g-1 at 10 C) and cycle stability (capacity retention of 94.7% after 100 cycles at 1 C). EIS and CV disclose that Ti and B co-doping reduces charge transfer impedance and suppresses phase change of LiNi0.8Co0.1Mn0.1O2. 相似文献
18.
19.
A new aqueous slurry-based laminated object manufacturing process for porous ceramics is proposed: firstly, an organic mesh sheet is pre-paved as a pore-forming template before slurry layer scraping; secondly, the 2D pattern is built with laser outline cutting of the dried mesh–ceramic composite layer; finally, the pore structure is formed after degreasing and sintering. Alumina parts with porosities of 51.5 %, round hole diameters of 80 ± 5 μm were fabricated using 70 wt. % solid content slurry and 100 mesh nylon net. Using an organic mesh as the framework and template not only reduces the risk of damage of the green body but also ensures the regularity, uniformity and connectivity of the micron scaled pore network. The layer-by-layer drying method avoids the delamination phenomenon and improves the paving density. The new method can realize the flexible design of the pore structure by using various organic mesh templates. 相似文献
20.