低GWP工质闪蒸补气式高温热泵性能对比

高温热泵作为一种有效的节能技术可以满足大多数的工业用热需求,遴选安全、环保、高效的制冷剂是当前高温热泵技术研究的重要工作之一。针对闪蒸补气式高温热泵,基于EES（Engineering Equation Solver）软件建立系统数学模型,以性能系数（COP）、制热量、单位容积制热量、冷凝压力、压缩比以及压缩机排气温度为性能指标,在冷凝温度 ≥ 100℃,温升分别为40℃、50℃和60℃工况下,对R1224yd(Z)、R1233zd(E)、R1336mzz(Z)和R1234ze(Z) 四种氢氟烯烃制冷剂在闪蒸补气式热泵系统中的应用潜力进行分析,并与R245fa比较。结果表明,R1336mzz(Z) 的COP最大、冷凝压力最低,但单位容积制热量最小,相对适用于小容量供热系统;R1234ze(Z)的单位容积制热量最大,且COP与R245fa相当,是R245fa的良好替代工质,尤其适用于大容量高温升供热系统;R1233zd(E) 虽然单位容积制热量偏低,但其COP、制热量和冷凝压力相对R245fa具有显著优势,亦可作为R245fa的替代工质;与R245fa相比,R1224yd(Z) 的热力性能无明显优势。     

Investigation of Vapor-liquid Ejector with Organic Working Fluids

The vapor-liquid ejector is a simply flow device and driven by thermal energy. In this paper, a modified mathematical model of the vapor-liquid ejector is proposed, and the validation shows good agreements with the experimental data. A study is carried out with six organic working fluids, namely R1233 zd(E), R1336 mzz(Z), R236 ea, R245 ca, R245 fa and R365 mfc. The influences of the entrainment ratio, the area ratio, the superheating at the vapor nozzle inlet, the subcooling at the liquid nozzle inlet, and the pressures at these inlets on the pressure lifting are parametrically investigated. An increase in the subcooling leads to the great increasing of pressure lifting and the superheating has slight effect on the pressure lifting, whereas others have the opposite tendency. The studies of the pressures and temperatures at the typical locations inside the vapor-liquid ejector are further conducted by using R1336 mzz(Z). The results show that the above parameters have great influence on these pressures and temperatures inside except that the pressures are insignificantly impacted by the superheating, and the temperatures are negligibly affected by the area ratio. R1336 mzz(Z) is recommended as a good working fluid for the vapor-liquid ejector.     

Optimum composition ratios of multicomponent mixtures of organic Rankine cycle for engine waste heat recovery

With the temperature glide in saturation states, the mixture working fluids have the advantages in thermal energy conversion. In this study, through the investigation in optimum mass fractions of multicomponent mixture working fluids, the economic performance enhancement of the organic Rankine cycle system is obtained for recovering waste heat from engine. The zero ozone-depletion-potential and dry working fluids of R236fa, R245fa, and R1336mzz(Z) are selected as the components of multicomponent mixtures in the system. The net power output, heat transfer calculation, and apparatus cost evaluation are employed to evaluate the power cost of the organic Rankine cycle system. Parameters of temperatures of waste heat sources and efficiencies of expanders are taken into account. The comparisons of economic performances for single-component working fluid and multicomponent mixtures with optimum mass fractions are proposed. The results show that R245fa, having a levelized cost of energy, LCOE, of 8.75 × 10⁻² $/kW-h, performs the best for single-component working fluids, better than R236fa by 1.6% and R1336mzz(Z) by 8.3%. All the two-component mixtures are superior to their single-component working fluids in economic performance. Among the three two-component mixture working fluids, R1336mzz(Z)/R236fa has the lowest LCOE_min, 8.57 × 10⁻² $/kW-h, followed by R236fa/R245fa and R245fa/R1336mzz(Z). In addition, R236fa/R245fa/R1336mzz(Z) mixture, which has a LCOE_min of 8.47 × 10⁻² $/kW-h, economically outperforms all other working fluids and has a lower LCOE_min than R236fa/R245fa by 1.7% and R245fa/R1336mzz(Z) by 2%.     

分液冷凝有机朗肯循环系统R245fa/HFOs工质选择研究

有机朗肯循环是中低品位热能高效利用的有效技术之一,分液冷凝有机朗肯循环（LSCORC）是基于分液冷凝传热强化的新型热力循环。为寻找新型环保替代工质,建立LSCORC系统的热力学模型,以最大化净输出功为目标,重点考虑了雅各布数、冷热源换热匹配对系统性能的影响,对R245fa/HFOs工质进行了对比筛选。结果表明：工质的雅各布数越大,其净输出功越小;在基础工况下,R245fa/R1336mzz(Z)的热力性能及热经济性表现最佳;当热源参数变化时,雅各布数较小工质的性能表现普遍优于雅各布数较大的工质组合;当冷源参数变化时,在分液冷凝器两个流程中温度滑移和冷源温升匹配越好的工质组合,其系统净输出功越大。     

Thermal stability and decomposition mechanism of HFO‐1336mzz(Z) as an environmental friendly working fluid: Experimental and theoretical study

HFO‐1336mzz(Z) is a promising working fluid used in high‐temperature heat pump and organic Rankine cycle (ORC) system because of its environmental friendly features and good thermal performance. In this work, a test system is designed to assess the thermal stability of HFO‐1336mzz(Z). The fluoride ion concentration is used as an indicator of HFO‐1336mzz(Z) dissociation. The experimental results show that the pressure has a great effect on the dissociation of HFO‐1336mzz(Z) and the dissociation temperatures of HFO‐1336mzz(Z) at 2.1, 3.1, and 4.0 MPa for 24 hours are 310°C to 330°C, 290°C to 310°C, and 270°C to 290°C, respectively. The decomposition products of HFO‐1336mzz(Z) are measured by a Fourier transform infrared spectrometer (FTIR); the main decomposition products are HF, CF₄, CHF₃, C2F₄, C₂F₆, C₂HF₅, and C₃F₈. Finally, density functional theory (DFT) method is used to study the decomposition mechanism of HFO‐1336mzz(Z). The main initial decomposition reaction is the fracture of C?C bond into C–C bond, and then the CF₃ group is separated from HFO‐1336mzz(Z) molecule to produce CF₃ radical. H, F‐abstraction, and combination reactions are important in the consequent reactions to generate the main decomposition products.     

Results of an experimental study of an advanced jet-pump refrigerator operating with R245fa

An experimental jet-pump refrigeration system was designed and constructed to assess the performance of R245fa (1,1,1,3,3-pentafluoropropane) as a suitable refrigerant. The paper describes and evaluates the results of experimental tests over a range of operating conditions. In addition, the effects of primary nozzle geometry on jet-pump performance are reported. Performance maps, useful for practical design and control are also provided. Experimental values of coefficient of performance (COP) between 0.25 and 0.7 were obtained. These results demonstrate that low-grade heat can be used to drive efficient jet-pump refrigeration systems, using R245fa as their working fluid, for high temperature applications, such air conditioning.     

A combined power and ejector refrigeration cycle for low temperature heat sources

A combined power and ejector refrigeration cycle for low temperature heat sources is under investigation in this paper. The proposed cycle combines the organic Rankine cycle and the ejector refrigeration cycle. The ejector is driven by the exhausts from the turbine to produce power and refrigeration simultaneously. A simulation was carried out to analyze the cycle performance using R245fa as the working fluid. A thermal efficiency of 34.1%, an effective efficiency of 18.7% and an exergy efficiency of 56.8% can be obtained at a generating temperature of 395 K, a condensing temperature of 298 K and an evaporating temperature of 280 K. Simulation results show that the proposed cycle has a big potential to produce refrigeration and most exergy losses take place in the ejector.     

Theoretical study of a transcritical ejector refrigeration cycle with refrigerant R143a

In this paper, a transcritical ejector refrigeration cycle (TERC) using refrigerant R143a as working fluid is proposed to improve the performance of the ejector refrigeration systems driven by low-grade thermal energy. This method adopts an adequate combination of thermal and mechanical energy through the operation of the transcritical process for generator to enhance the performance of the conventional ejector refrigeration cycle (ERC) at the cost of additional driving mechanical energy. The performance characteristics of the TERC are investigated based on theoretical simulations. The TERC is also compared with the conventional ERC using refrigerant R134a. The study shows that when utilizing the low-grade thermal energy, the TERC yields significant increase in COP by adding auxiliary mechanical energy of the cycle pump and has a higher potential in making effective use of the low-grade thermal energy with gradient temperature, such as solar energy gained by a flat plate or evacuated tube solar collector. This also indicates that the TERC is an attractive alternative to the ejector refrigeration systems driven by low-grade thermal energy. Further experimental work for the TERC may be launched in the near future to verify practical applications.     

基于热源耦合ORC ANN模型的循环性能预测及工质优选

基于已建立的有机朗肯循环(ORC) 人工神经网络(ANN)模型,将其与热源进行耦合,从而在不同烟气工况下对ORC进行循环性能预测及工质优选。为了分析与热源耦合的ORC ANN模型精度,基于初选的10种工质,比较了该模型与REFPROP软件对基本ORC和回热ORC的计算结果,比较结果表明：该ORC ANN模型对大部分循环参数的平均相对偏差都小于5%。在此基础上,针对不同烟气热源温度（523.15,488.15和453.15 K）,以最大净输出功为目标,分别优化循环的蒸发温度,优化结果显示：3种热源温度对应的最佳工质分别为R1336mzz(Z),R600a和R236fa。     

Experimental comparison of R245fa and R245fa/R601a for organic Rankine cycle using scroll expander

An experimental test was conducted to compare R245fa with R245fa/R601a on the organic Rankine cycle performance. The major objective of this paper is to ascertain the highest thermal efficiency and the optimal dimensionless volume ratio using the two working fluids. The experimental system consists of an electrically heated boiler, a vapor generator, a scroll expander, a condenser, a working fluid pump, and so on. For the typical weather conditions of May in Tianjin, the experiment results show that the working fluid charge has an important influence on the organic Rankine cycle performances. The optimal isentropic efficiency of the scroll expander corresponds to the design expansion ratio. Underexpanded and overexpanded processes result in the decline of the isentropic efficiency of the scroll expander, with the former playing a major role. R245fa/R601a improves the heat transfer performance in the vapor generator because of the nonisothermal phase change. The highest thermal efficiency for R245fa and R245fa/R601a is 4.38% and 4.45%, thereby illustrating that R245fa/R601a precedes R245fa. The optimal dimensionless volume ratios for R245fa and R245fa/R601a are 0.38 and 0.41, respectively. The experimental test lays foundation of the 500‐kW geothermal plant for demonstration in the next step. Copyright © 2014 John Wiley & Sons, Ltd.     

Particular characteristics of transcritical CO2 refrigeration cycle with an ejector

The present study describes a theoretical analysis of a transcritical CO₂ ejector expansion refrigeration cycle (EERC) which uses an ejector as the main expansion device instead of an expansion valve. The system performance is strongly coupled to the ejector entrainment ratio which must produce the proper CO₂ quality at the ejector exit. If the exit quality is not correct, either the liquid will enter the compressor or the evaporator will be filled with vapor. Thus, the ejector entrainment ratio significantly influences the refrigeration effect with an optimum ratio giving the ideal system performance. For the working conditions studied in this paper, the ejector expansion system maximum cooling COP is up to 18.6% better than the internal heat exchanger cycle (IHEC) cooling COP and 22.0% better than the conventional vapor compression refrigeration cycle (VCRC) cooling COP. At the conditions for the maximum cooling COP, the ejector expansion cycle refrigeration output is 8.2% better than the internal heat exchanger cycle refrigeration output and 11.5% better than the conventional cycle refrigeration output. An exergy analysis showed that the ejector expansion cycle greatly reduces the throttling losses. The analysis was also used to study the variations of the ejector expansion cycle cooling COP for various heat rejection pressures, refrigerant temperatures at the gas cooler exit, nozzle efficiencies and diffuser efficiencies.     

Ejector enhanced vapor compression refrigeration and heat pump systems—A review

The present paper provides a literature review on two-phase ejectors and their applications in vapor compression refrigeration and heat pump systems. Geometry, operation and modeling of ejector, and effects of various operating and geometric parameters, and refrigerant varieties on the ejector performances as well as performance characteristics of both subcritical and transcritical vapor compression systems with various cycle configurations are well-summarized. Moreover, system optimal operation and control to get maximum performance by using ejector as an expansion device are also discussed. However, a lot of research work still needs to be done for large-scale applications in industry and for the replacement/modification of conventional refrigeration and heat pump machines. Favorable performance improvement along with several advantages in installation, operation and control with ejector stimulates the commercialization of ejector enhanced refrigeration and heat pump systems and hoping this contribution will be useful for any newcomer in this field of technology.     

采用不同工质的高温复合热泵开水器特性研究

热泵开水器具有较高的能源利用效率,是公共场所电加热开水装置的理想替代品。从提高能源效率和一机两用的角度,构建了一种高温复合热泵开水器系统。建立了系统热力学模型,选R236fa、R245fa、R365mfc、R245ca、RC318和R236ea等6种较高临界温度的制冷工质,通过能量分析和[火用]分析的方法,探讨了不同制冷工质对高温复合热泵开水器系统性能的影响。研究结果表明:R245fa作为工质的高温复合热泵开水器系统具有最佳的性能,而以RC318作为工质的系统性能最差。在给定工况下,R245fa作为工质系统制热性能系数(COP_h)为2.47,而其制冷性能系数(COP_c)为3.37,[火用]损失和[火用]效率分别为9.47 kW和49.07%;与R245fa相比,RC318作为工质系统的总能耗增加了39.53%。     

Experimental study on a small‐scale pumpless organic Rankine cycle with R1233zd(E) as working fluid at low temperature heat source

This paper focuses on the novelty pumpless organic Rankine cycle (ORC) and its choice of working fluids. Based on the selection criteria, the refrigerant of R1233zd(E) is firstly chosen and investigated in the pumpless ORC system. In the system, the feed pump is removed, and the refrigerant flows back and forth between two heat exchangers, which act as the evaporator or condenser, respectively. The impacts of the heating water temperature and loads on the system performance are studied to find out the best operating conditions. The low‐grade heat source is simulated by an electric boiler. The temperature of the heat resource ranges from 80°C to 100°C with the interval of 5°C. The temperature of the cooling water inlet is 10°C and is kept constant. The largest average power output is 127 W under the condition of 100°C heating water with nine loads. Because the cycle efficiency with heating steam temperature of 100°C cannot be determined, the highest energy and exergy efficiencies are 3.5% and 17.1%, respectively, for heating water of 95°C with seven loads. The experimental results show that the energy and exergy efficiencies increase with the increase of the heating temperature. The power and current outputs increase when the loads increase under the condition of the constant heating water temperature, whereas the voltage output decreases meanwhile. The generating time increases when the loads increase. This phenomenon is mainly caused by the increasing evaporating pressure and decreasing condensing pressure when the loads increases.     

Experimental studies on an ammonia ejector refrigeration system

An ejector refrigeration system has been designed and developed to operate with a simulated (electric) heat source, which can be realized in practical applications by renewable energy sources like solar energy, geothermal energy, etc., or waste heat. In this paper, an experimental study on an ejector refrigeration system working with ammonia is presented. The influence of the generator, condenser, and evaporator temperatures on the ejector refrigeration system performance is presented. The entrainment ratio and COP of the system increase with increasing generator and evaporator temperatures and decrease with increasing condenser temperature.     

Performance evaluation of a low-temperature solar Rankine cycle system utilizing R245fa

A low-temperature solar Rankine system utilizing R245fa as the working fluid is proposed and an experimental system is designed, constructed and tested. Both the evacuated solar collectors and the flat plate solar collectors are used in the experimental system, meanwhile, a rolling-piston R245fa expander is also mounted in the system. The new designed R245fa expander works stably in the experiment, with an average expansion power output of 1.73 kW and an average isentropic efficiency of 45.2%. The overall power generation efficiency estimated is 4.2%, when the evacuated solar collector is utilized in the system, and with the condition of flat plate solar collector, it is about 3.2%. The experimental results show that using R245fa as working fluid in the low-temperature solar power Rankine cycle system is feasible and the performance is acceptable.     

Experimental investigation of moderately high temperature water source heat pump with non-azeotropic refrigerant mixtures

Experimental investigations were carried out on non-azeotropic refrigerant mixtures, named M1A (mass fraction of 20%R152a and 80%R245fa), M1B (mass fraction of 37% R152a and 63%R245fa) and M1C (mass fraction of 50%R152a and 50%R245fa), based on a water-to-water heat pump system in the condensing temperature range of 70–90 °C with a cycle temperature lift of 45 °C. Performance of R245fa was tested for comparison. Unfair factors in experimental comparative evaluation research with the same apparatus were identified and corrected. Experimental cycle performance of the mixtures were tested and compared with improved experimental assessment methodology. The results show that all of the mixtures deliver higher discharge temperature, higher heating capacity, higher COP and higher ε_h,c than R245fa. M1B presents the most excellent cycle performance and is recommended as working fluid for moderate/high temperature heat pump.     

R245fa作为有机朗肯循环工质的材料相容性研究

对于可再生能源和工业余热资源,有机朗肯循环技术(organic Rankine cycle,ORC)被认为是一种高效的能源回收利用技术。其中R245fa因为其自身良好的环保性以及热力性能,被认为是一种具有良好应用前景的ORC工质。对于ORC系统来说,工质的材料相容性是保证系统稳定运行的基础。针对ORC系统实际工况,确定部件、温度、材料等因素的对应关系,提出一套适用于ORC工质材料相容性研究的实验方法,并以R245fa为例开展了实验研究。实验结果表明,在高温条件下,304不锈钢与R245fa的相容性要优于铜材料;同时在橡胶密封材料的选择上,不建议使用氟橡胶,且三元乙丙橡胶的相容性要优于聚四氟乙烯。     

喷射器性能及太阳能喷射制冷系统工质的优化

考虑实际流体热力学性质、混合效率和激波等因素,建立了喷射器热力学模型,计算结果与文献中实验数据吻合很好。文中计算了采用环境友好工质R134a、R152a、R717、R290、R600a时喷射系数及喷射制冷系统性能系数。结果表明,对于确定几何参数的喷射器,喷射系数和喷射制冷系统性能系数主要取决于膨胀比与压缩比,两者分别随膨胀比的增加而增大,压缩比的增加而减小。太阳能驱动喷射制冷系统时(发生温度在80℃左右),采用R134a可以使喷射系数和喷射制冷系统能效比最大,明显优于其他工质。     

有机朗肯循环与再热式循环低温热源发电系统热力性能研究

针对120℃以下的低温余热热源,探讨了基本有机郎肯循环发电系统和再热式有机朗肯循环发电系统模型的基本原理.从热力学第一定律角度出发,研究了纯工质R245fa和非共沸混合工质R21/R245fa在基本有机郎肯循环系统中,以及纯工质R245fa在再热式有机郎肯循环系统中,三种形式的有机郎肯循环系统热力性能随蒸发温度的变化情况.与纯工质基本有机郎肯循环系统相比,再热式有机郎肯循环最大可提高系统净输出功7.08％,而混合工质对提高整个系统热力性能具有较大的优势,净输出功和热效率最大可提高4.67％和2.91％.