Co-precipitation synthesis of ZnAl2O4: Cr3+ phosphor for better light penetration in pc-LED

Cr doped ZnAl₂O₄ spinel samples were prepared by the traditional solid state reaction and co-precipitation synthetic route, and the results suggest that the co-precipitation method has some superiority in contrast to the solid state reaction method. XRD, FT-IR, and XPS spectra confirmed that the well-crystallized spinel cubic phase of ZnAl₂O₄: Cr³⁺ samples were successfully formed. The morphology of the samples was investigated by FE-SEM and FE-TEM, and the results show that the samples by the co-precipitation route can generate a smaller size of particles compared to the solid state reaction. Photoluminescence excitation spectra monitored at 686 nm are comprised of two broad excitation bands near 530 nm and 395 nm, and the emission spectra show emissions ranging from 640 to 780 nm, due to the ²E?→?⁴A₂ spin-forbidden transition of Cr³⁺ ions in spinel lattices. The optimized concentration monitored at 686 nm is 1%, while at 693 nm is 3.5%. Compared with the samples by solid state reaction method, the samples by co-precipitation method show preferable luminescent properties, such as the higher photoluminescence intensity and higher quantum efficiency. Several phosphor-converted LEDs were to investigate the applicability of the prepared samples. The results confirm that the phosphor has potential applications in plant growth and supplementing the red region in white-LEDs and the phosphors prepared by co-precipitation are more suitable to be used in phosphor-converted LED devices due to their preferable luminescent properties.

     

Co?N graphene encapsulated cobalt catalyst for H2O2 decomposition under acidic conditions

Hydrogen peroxide (H₂O₂) has been listed as one of the 100 most important chemicals in the world. However, huge amount of residual H₂O₂ is hard to timely decomposed into O₂ and H₂O under acidic condition, easily resulting in explosion hazard. Here, we reported a core–shell structure catalyst, that is graphene with Co N structure encapsulated Co nanoparticles. Co N graphene shell serves as the active site for the H₂O₂ decomposition, and Co core further enhance this decomposition. Benefiting from it, the H₂O₂ decomposition were close to 100% after 6 cycles without pH adjustment, which increased 6 orders of magnitude compared with no catalyst. At the same time, the O₂ generation reached 99.67% in 2 h with little metal leaching, and ·OH has been greatly inhibited to only 0.08%. This work can cleanly remove H₂O₂ with little deep oxidation and protect the process of H₂O₂ utilization to achieve a safer world.     

Study on the removal of olefins from naphtha by clay loaded with trifluoromethanesulfonic acid

Journal of Porous Materials - In this work, a trifluoromethanesulfonic acid (TFOH) modified clay (TFOH-Clay) was developed for the removal of trace olefins in heavy naphtha. 5%TFOH-Clay can...     

纯净美妆产品的设计理念

以消费者、行业专家、各品牌商以及全球各个美妆相关行业对纯净美妆的认识为依据,从配方设计、关键的原料筛选、生产过程、包材选择以及测试评估等方面,对如何实现纯净美妆产品进行了较为详细的阐述,无疑为纯净美妆的标准建立和定义提供很好的参考.     

Spatial–Temporal Fusion Based Path Planning for Source Seeking in Wireless Sensor Network

International Journal of Wireless Information Networks - Source seeking problem has been faced in many fields, especially in search and rescue applications. We proposed a virtual structure-based...     

基于SSD的眨眼与打哈欠检测

提出了一种新的基于SSD网络的眨眼与打哈欠检测。首先,对原SSD架构进行四个方面的修改。第一,主干网用MobileNetV3替换了VGG,使得架构尺寸缩减三分之一。第二,重新设计了输出检测器,实现了目标检测与分类、目标定位与高宽比回归多任务的融合。第三,网络直接回归高宽比,比传统的从关键点离线计算高宽比的方法鲁棒性要高。第四,省去了非最大抑制层(NMS)中的重叠度(IOU)计算和阈值设定,使得单目标检测速度提高了40%。另外,在数据集YawDD上验证了所提出方法的有效性,眨眼与打哈欠的测全率为95.1%与100.0%,在单卡2080Ti上实现了41fps的高检测速度。     

Self-healing,elastic and deformable novel composite phase change polymer based on thermoplastic elastomer SEBS for wearable devices

Journal of Materials Science - Form-stable composite phase change materials (C-PCMs) prepared by microencapsulation method and porous matrix adsorption method need for compression molding after...