原位固氮剂在污泥堆肥过程中保氮机制

高温好氧堆肥技术虽然可有效处理有机固体废物，但常常会释放大量的氨气和造成氮素损失。本文以硫酸镁、磷酸二氢钾、硫酸镁+磷酸二氢钾（分别记为MgSO₄、KP和KPM处理组）为原位固氮剂，污泥和木屑为原料，进行高温好氧堆肥试验，研究以上原位固氮剂对污泥堆肥过程中的氨气挥发和氮素损失的影响。结果表明，硫酸镁（MgSO₄）对物料pH有显著的降低效应，添加硫酸镁使堆体高温期pH降低至8.17，低于硫酸镁+磷酸二氢钾（KPM）组（8.55）和对照（CK）组（8.90）。与CK相比，MgSO₄和KPM的NH₃累积释放量分别降低了34%和28%，反而KP组增加了35%。对比不同条件下XRD图谱可知，MgSO₄的固氮效应并不是由于MgNH₄PO₄·6H₂O的生成，而是由于其对pH的降低效应造成的。堆肥结束后，除了KP组，各处理条件下的种子发芽率值（germination index，GI）均不会对后续使用带来不利影响。     

城市低有机质污泥的好氧堆肥研究

针对低有机质含量污泥和难降解调理剂混合堆肥时因发热量不足而易导致堆肥失败的问题,利用草坪碎屑作为污泥堆肥的调理剂,考察了添加草屑发酵物后低有机质污泥的好氧堆肥效果.结果表明,草屑发酵后可转化为易被微生物利用的外加碳源,有利于低有机质污泥的堆肥;将发酵青草按1：5的质量比加到低有机质污泥中,混合后在强制通风条件下进行好氧堆肥,能使污泥堆肥温度升至55℃,并维持3 d以上,使污泥达到无害化和稳定化;对腐熟后的污泥进行植物栽培试验,证明了其可作为有机肥使用,并具有良好的效果.     

污泥堆肥化对重金属生物可利用性的影响

通过重金属形态分析及在模拟雨水、酸雨淋溶条件下重金属迁移实验和理论分析，研究了堆肥化处理对污泥中重金属生物可利用性的影响。结果表明：堆肥化处理使重金属的不稳定形态含量降低，原污泥在酸雨淋溶下重金属已经迁移到约16厘米深的土柱中，而经过处理后的污泥淋出液中的重金属含量很低，仅有少量污泥中含量较高的元素向土柱深层迁移。迁移量及深度明显低于未处理的原污泥。实验及理论分析均证明了堆肥化处理可以降低污泥中重金属在土壤中的迁移性，使重金属的生物可利用性降低。     

沈阳市污水处理厂1000t/d污泥处理工程设计

沈阳市污水处理厂污泥处理工程是目前世界上已投入运行的处理规模最大的机械化槽式污泥堆肥项目,介绍了项目工艺流程及设计情况(物料衡算、单体工艺参数、主要设备等),总结了项目设计特点,并分析了项目运行效果,最后得到结论:对于超大型污泥处理项目,堆肥仍可视为有效处理方法之一;规模的扩大不应以牺牲环境质量为代价,除臭仍应受到充分重视;机械化程度的提高对于规模化堆肥技术的推广具有现实意义;该项目堆肥成品含水率为35％,严于国家标准,但并未引起运行成本升高,对于采用返混为主的堆肥系统是一个有益的借鉴;在本土化基础上的国际合作是探索适合中国国情污泥处理处置道路的理想选择.     

堆肥过程中挥发性有机物的产生与释放

总结了堆肥过程中挥发性有机物(VOCs)的产生及其影响因素.堆肥产生的VOCs中,氮化物、硫化物及挥发性脂肪酸属于臭味物质,但大部分VOCs不产生臭味,其中甲胺、二甲胺、甲硫醇、乙硫醇、2-甲基呋喃和甲醛应作为堆肥厂职业健康安全评价时的参考指标.温度、通气状况是影响堆肥过程中VOCs释放的重要因素,温度升高可促使VOCs产生,适当通风可减少VOCs释放.     

Coastal environment: EC‐cost 48 bioconversion projects and economic aspects

Seaweed has proved to be both a potential resource and a problem for coastal areas. In the framework of the European Communities, a scientific commission was created some 8 years ago, in order to address the matter of seaweed bioconversion in Europe. A book, recently published, represents a fair review and survey of seaweed as a resource in Europe. The matter of seaweed problems and expanded use is now under study in a new programme.

This paper traces back the development and growth of this inter‐European effort and also provides an overview of achievements.     

一种家用小型太阳能堆肥箱的设计

针对目前市场上常见的厨余垃圾堆肥箱不易保温、堆肥时间长、沥水效果差、臭味重等问题,设计一种家用小型堆肥箱,该装置包括太阳能集热板、太阳能电池板、通风管路、投料口、沥水筛网、尾气处理等多个模块。通过对堆肥箱空间结构进行设计和优化,使其更好地满足高温好氧堆肥工艺的需求,同时由于引入了太阳能为整个系统的保温和通风供能,大大降低了能耗。该装置与自然堆肥相比缩短了堆肥时间,且整个系统移动搬运方便,不受放置地点限制,十分适合庭院内使用。     

Corn and rice waste: a comparative and critical presentation of methods and current and potential uses of treated waste

Although corn and rice waste can be hardly classified among the most hazardous waste, their treatment is very important in view of the great volume of waste materials involved. In this review article, an update is provided for most of the waste treatment techniques (composting, pyrolysis, gasification, combustion) used to alter the physical, chemical or biological character of the waste, to reduce its volume and/or toxicity and to make the waste safer for disposal. Furthermore, all current and potential uses of treated corn and rice waste such as fertilisers, biomass and biogas/biofuel are summarised. Four comprehensive tables and six figures provide a thorough presentation of both waste treatment methods (characteristics, advantages and disadvantages) and uses of treated corn and rice waste.     

Performance of an industrial biofilter from a composting plant in the removal of ammonia and VOCs after material replacement

BACKGROUND: Biofiltration is a suitable odor reduction technique for the treatment of gaseous emissions from composting processes, but little is known about the start‐up of full‐scale biofilters after material replacement and their performance after several years of operation. RESULTS: Biofilter material (wood chips used previously as bulking agent in a composting process) can effectively remove ammonia and most of the volatile organic compounds (VOCs) content, achieving removal efficiencies greater than 70% for VOCs and near 90% for ammonia immediately after material replacement. These removal efficiencies were maintained for several months after material replacement. In the studied full‐scale biofilter no lag phase was observed in the removal of ammonia whereas in the case of VOCs different patterns were detected during biofilter start‐up. For the old biofilter material, after 4 years of operation, a statistically significant decrease of removal efficiency for ammonia in comparison with the new material was detected. No statistically significant differences were found in the case of VOCs. CONCLUSIONS: Data on the emissions of several pollutants from biofilters treating composting exhaust gases have been systematically obtained. The tested filtering media presented adequate properties for biofiltration of gases emitted during the composting process. Copyright © 2009 Society of Chemical Industry