Influence of microwave heating and time on functional,pasting and thermal properties of cassava starch

The effect microwaving power and time on the functional, pasting and thermal properties of cassava starch was investigated. Cassava starch at a moisture content of 30% was microwaved at 600 and 700 W for 0, 5, 15, 30 and 60 s following a preliminary study. Microwaving power and time did not alter the crystalline pattern of the starch, but there were obvious changes in the starch morphology. Starch colour was significantly (P ≤ 0.05) altered by microwave heating, with the total colour difference increasing from 4.85 to 43.01. Microwave treatment increased starch gelatinisation temperatures but decreased the swelling power, water absorption capacity and the relative crystallinity. These changes were influenced by microwave heating power and time. The results further revealed that the peak viscosity (3714.00–1947.00 cP) and setback ratio (1.70–1.49) decreased with increasing microwave heating time. However, breakdown viscosity (322.67–897.63 cP) and pasting temperature (1947.00–3714.00 °C) increased.     

Enhanced dielectric properties of three phase dielectric MWCNTs/BaTiO3/PVDF nanocomposites for energy storage using fused deposition modeling 3D printing

This research studied the effect of fused deposition modeling (FDM) 3D printing on three phase dielectric nanocomposites using poly(vinylidene) fluoride (PVDF), BaTiO₃ (BT), and multiwall carbon nanotubes (CNTs). PVDF polymer and BT ceramics are piezo-, pyro- and di-electric materials extensively used for sensor and energy storage/harvesting applications due to their unique characteristic of dipole polarization. To increase dielectric property, CNTs have been recently utilized for uniform dispersion of BT nanoparticles, ultrahigh polarization density, and local micro-capacitor among matrix. It was proved that 3D printing process provides homogeneous dispersion of nanoparticles, alleviating agglomeration of nanoparticles and reducing micro-crack/voids in matrix which can potentially enhance their dielectric property than traditional methods. In this research, these three-phase nanocomposites are fabricated through FDM 3D printing process and characterized for dielectric property. Increasing both BT and CNT nanoparticles improves dielectric properties, while CNTs have a percolation threshold near 1.7?wt%. The most desirable combination of dielectric constant and loss properties (118 and 0.11 at 1?kHz) is achieved with nanocomposites containing 1.7?wt%-CNT/45?wt%-BT/PVDF. These results provide not only a technique to 3D print dielectric nanocomposites with improved dielectric property but also large-scale electronic device manufacturing possibility with freedom of design, low cost, and faster process.     

A local and global tour on MOMoT

Software and Systems Modeling - Many model transformation scenarios require flexible execution strategies as they should produce models with the highest possible quality. At the same time,...     

Feeding high amounts of almond hulls to lactating cows

California is the leading state for the production of almonds, with more than 400,000 bearing hectares of orchards that produced approximately 1 billion kilograms of shelled nuts in 2017. Almond hulls (AH) are a regional by-product feedstuff fed predominantly to dairy cattle in California. A 2012 study surveyed 40 dairy farms in California and found that 39 out of 104 total mixed rations contained AH, with a mean daily feeding rate of 1.45 kg/cow. In 2017, approximately 2 billion kilograms of AH was produced. At a feeding rate of 1.45 kg/cow daily, even if all 1.7 million lactating cows in California are consuming AH, there will be a surplus of AH on the market as the approximately 130,000 nonbearing hectares come into nut production. Therefore, the potential of feeding varying amounts of AH to lactating dairy cows was investigated using 12 Holstein cows with 4 primiparous and 8 multiparous cows. The dietary treatments were 4 total mixed rations containing 0, 7, 13, or 20% AH. The AH used contained 12.8% crude fiber (as-is basis), which was below the 15% legal limit set by state feed regulations. Diets were formulated so that as the inclusion rate of AH increased, the amount of steam-flaked corn and soyhull pellets decreased and soybean meal inclusion increased. Experimental design was a replicated 4 × 4 Latin square. Diet had a cubic effect on actual milk yield, energy-corrected milk yield, and dry matter intake, with the 7% AH diet having the highest values and the 13% AH diet having the lowest. The percent and yield of total solids and the yields of lactose and fat did not differ with diet, but percent and yield of protein declined linearly with increased AH inclusion, and fat percent increased linearly. Apparent total-tract digestibilities of dry matter and organic matter were higher with the inclusion of AH in the diet. Total percentage of the day spent ruminating increased linearly with higher amounts of AH. Overall, this work demonstrated that AH can be fed at varying amounts, up to 20% of the diet, to lactating dairy cows to support high levels of milk production and that increasing amounts of AH (up to 20%) in the diet could lead to improved digestibility and milk fat percentage but decreased milk protein production.     

Energetics and Structure of Polymer‐Derived Si–(B–)O–C Glasses: Effect of the Boron Content and Pyrolysis Temperature

The structure and properties of polymer‐derived Si–(B–)O–C glasses have been shown to be significantly influenced by the boron content and pyrolysis temperature. This work determined the impact of these two parameters on the thermodynamic stability of these glasses. High‐temperature oxide melt solution calorimetry was performed on a series of amorphous samples, with varying boron contents (0–7.7 at.%), obtained by pyrolysis of precursors made by a sol–gel technique. Thermodynamic analysis of the calorimetric results demonstrated that at a constant pyrolysis temperature, adding boron makes the materials energetically less stable. While the B‐containing glasses pyrolyzed at 1000°C were energetically less stable than the competitive crystalline components, increasing the pyrolysis temperature to 1200°C led to their enthalpic stability. ²⁹Si and ¹¹B MAS nuclear magnetic resonance (NMR) spectroscopy measurements on selected samples confirmed a decrease in the concentrations of mixed Si‐centered SO_iC_4?i and B‐centered BO_jC_3?j bonds at the expense of formation of SiO₄ and B(OSi)₃ species (indicating a tendency toward phase separation) when the boron content and pyrolysis temperature increased. In light of the findings from calorimetry and NMR spectroscopy, we propose a structure–energetic relationship in Si–(B–)O–C glasses.     

A New Test to Evaluate the Fire Performance of Residential Sprinklers

Fire tests were conducted using the Underwriters Laboratories (UL) UL 1626 Fire Test for residential sprinklers. The results indicated that sprinkler performance in UL 1626 could not be reproduced due to differences in material flammability properties. This conclusion was reached in a cooperative effort with UL. Factory Mutual Research's Approval fire test that had been redesigned based on UL 1626 was thus subject to the same variability. A new fire test was developed using fuel with controlled material flammability parameters based upon the use of the ASTM E2058 Fire Propagation Apparatus. The new fuel package consists of a wood crib (one half the height of the one which was used in UL 1626) supported over a pan with heptane, two polyether foam cushions (about 60% greater in density than the foam previously used in UL 1626) measuring 34 in by 30 in by 3 in (864 mm by 762 mm by 76 mm) and in (6 mm) Douglas Fir plywood paneling. The new fire test was shown in a series of sprinklered fire tests to provide a reproducible challenge to residential sprinklers comparable to that observed in the Factory Mutual Research and the Los Angeles Residential Test Programs.     

Claiming participation – a comparative analysis of DIY urbanism in Denmark

The article discuss the conflicts, potentials and possible alliances of do-it-yourself (DIY) urbanism when it takes the form of spontaneous place appropriations, when it is performed as participatory urban design and when it is integrated strategically in planning. DIY urbanism and experimentation with participation are currently strong influential factors in Danish planning. The article explores the use of participatory DIY urban design in two cases: the relocation of beer drinkers in Enghave Square and the Carlsberg City development in Copenhagen, Denmark. Carlsberg City is the most thorough Danish example of how DIY urban design is employed as an investment and planning tool. It discusses the implications of DIY urbanism in terms of how it can be understood in the context of the struggles over ‘the right to the city’, how it applies different activist tactics for the appropriation of space, and how it is integrated in planning and the development logic.     

Fine-spray (water mist) protection of shipboard engine rooms

Twenty-three fire tests were conducted to determine the ability of current fine-spray (water mist) technologies to extinguish fires specified in the International Maritime Organization (IMO) fire test procedure for engine rooms greater than 3000 m³. The tests were conducted using nozzle installed at a 5 m height and 1·5 m spacing in a large test facility (2800 m² area and 18 m height). Two types of nozzles were tested: a low pressure nozzle operating between 1·2 and 1·5 MPa with flow per nozzle between 12·0 and 13·41/m and a multi-nozzle high-pressure prototype consisting of seven nozzles operating at 6·9 MPa flowing at 5·3 1/m per prototype. These nozzles were selected because they had been shown to extinguish IMO fire tests in enclosures with a protected area of 83 m² and a ceiling height of 4·5 m. The fire tests selected from the IMO procedure included 6 MW diesel spray fires on top of the IMO engine mock-up, a shielded 6 MW diesel spray fire adjacent to the mock-up, a 1 MW shielded diesel spray fire adjacent to the mock-up, and a wood crib within a 2 m² pan filled with heptane. In tests in which no additional enclosure surrounded the nozzles other than the test facility, fires were not significantly affected by the water mist using either nozzle. To further investigate mist-system capabilities, a ceiling was then placed directly over the nozzles at a 5 m height covering an area of 188 m². Using 90 high-pressure prototype nozzles, the test fires were not extinguished. A 940 m³ enclosure was then formed by dropping tarpaulins to the floor from the ceiling. A 4 m² vent was placed in the wall. With the 90 high-pressure prototype nozzles, the 6 MW spray fire on top of the mock-up was extinguished. When the 6 MW fire was shielded beside the mock-up, the fire was not extinguished. With the vent closed, the 6 MW shielded spray fire was extinguished. Under the same test conditions, a 1 MW shielded diesel spray fire and a 0·1 m² heptane pool fire were not extinguished. The fire test results indicated that protection of engine rooms with volumes of about 1000 m³ is possible by optimizing current fine-spray technology while significantly larger volumes will require improved discharge characteristics.