Advanced Postirradiation Characterization of Nuclear Fuels Using Pulsed Neutrons

Methods for postirradiation characterization of bulk (cm³) irradiated materials or even spent nuclear fuels are sparse due to their extremely radioactive nature. While several methods exist to characterize smaller volumes (<?1 mm³) of such samples, selecting these volumes from larger samples is challenging. X-ray-based methods are prohibitive due to the strong γ-radiation from the sample flooding the detectors. Neutron-based methods available in the proximity of irradiation reactors allow for thermal neutron radiography or computed tomography using a small reactor source, but one cannot assess isotope distributions or microstructural features such as phases, texture, or strain from diffraction measurements due to flux limitations. We present herein a pathway to provide pulsed neutron characterization of bulk irradiated samples using time-of-flight neutron diffraction for microstructural characterization and energy-resolved neutron imaging for assessment of isotopic densities and distributions. Ultimately, laser-driven pulsed neutron sources may allow deployment of these techniques pool-side at irradiation reactors.

     

Optical properties and quantum efficiency of thin-film alkali halides in the far ultraviolet

The optical constants of thin films of CsI, KI, and KBr and the quantum efficiency (QE) of planar photocathodes made with these alkali halides in the 53.6-174.4-nm spectral range are presented. The optical constants were obtained from measurements of the reflectance as a function of incidence angle. The effect of film heating and exposure to UV irradiation on the optical properties and on the QE of the three alkali halides was investigated. KBr was found to be the most stable material for both heating and UV irradiation. KI appeared to be close to temperature stable, whereas UV exposure affected its optical constants. CsI optical constants changed after 420 K heating and after UV exposure. The changes in the optical constants were related to the QE changes, and a certain correlation between both variations was determined. However, it was also demonstrated that the QE changes cannot be explained solely by the changes in optical constants.     

High-resolution neutron microtomography with noiseless neutron counting detector

The improved collimation and intensity of thermal and cold neutron beamlines combined with recent advances in neutron imaging devices enable high-resolution neutron radiography and microtomography, which can provide information on the internal structure of objects not achievable with conventional X-ray imaging techniques. Neutron detection efficiency, spatial and temporal resolution (important for the studies of dynamic processes) and low background count rate are among the crucial parameters defining the quality of radiographic images and tomographic reconstructions. The unique capabilities of neutron counting detectors with neutron-sensitive microchannel plates (MCPs) and with Timepix CMOS readouts providing high neutron detection efficiency (∼70% for cold neutrons), spatial resolutions ranging from 15 to 55 μm and a temporal resolution of ∼1 μs—combined with the virtual absence of readout noise—make these devices very attractive for high-resolution microtomography. In this paper we demonstrate the capabilities of an MCP-Timepix detection system applied to microtomographic imaging, performed at the ICON cold neutron facility of the Paul Scherrer Institute. The high resolution and the absence of readout noise enable accurate reconstruction of texture in a relatively opaque wood sample, differentiation of internal tissues of a fly and imaging of individual ∼400 μm grains in an organic powder encapsulated in a ∼700 μm thick metal casing.     

Scatter rejection in quantitative thermal and cold neutron imaging

The accuracy of quantitative neutron transmission radiography can be substantially decreased if highly scattering materials, such as water or plastics, exist in the sample. There are currently two main solutions to this problem: either performing experiments at a large distance between the detector and the sample or employ some numerical correction techniques. In the former case, the spatial resolution is substantially reduced by the limited beam divergence, while the latter correction requires a priori information about the sample and is limited to distances of above ∼2 cm. We demonstrate the feasibility of another technique, namely the possibility to remove the scattered neutron component from the transmitted neutron beam by a very compact polycapillary collimator. These ∼1 mm thick devices can be placed between the sample and the detector and remove most of the neutrons scattered at angles larger than the acceptance angle of the collimator (typically 1°). No image distortions above ∼10 μm scales are introduced by these collimators. The neutron transmission of highly scattering samples (water and plexiglass) is measured in our experiments with and without scatter rejection. In the latter case, the accuracy of measured transmission coefficient was substantially improved by our collimators.     

Centroiding algorithms for high speed crossed strip readout of microchannel plate detectors

Imaging microchannel plate (MCP) detectors with cross strip (XS) readout anodes require centroiding algorithms to determine the location of the amplified charge cloud from the incident radiation, be it photon or particle. We have developed a massively parallel XS readout electronic system that employs an amplifier and ADC for each strip and uses this digital data to calculate the centroid of each event in real time using a field programmable gate array (FPGA). Doing the calculations in real time in the front end electronics using an FPGA enables a much higher input event rate, nearly two orders of magnitude faster, by avoiding the bandwidth limitations of the raw data transfer to a computer. We report on our detailed efforts to optimize the algorithms used on both an 18 mm and 40 mm diameter XS MCP detector with strip pitch of 640 microns and read out with multiple 32 channel "Preshape32" ASIC amplifiers (developed at Rutherford Appleton Laboratory). Each strip electrode is continuously digitized to 12 bits at 50 MHz with all 64 digital channels (128 for the 40 mm detector) transferred to a Xilinx Virtex 5 FPGA. We describe how events are detected in the continuous data stream and then multiplexed into firmware modules that spatially and temporally filter and weight the input after applying offset and gain corrections. We will contrast a windowed "center of gravity" algorithm to a convolution with a special centroiding kernel in terms of resolution and distortion and show results with < 20 microns FWHM resolution at input rates > 1 MHz.     

Neutron Collimation With Microchannel Plates: Calibration of Existing Technology and Near Future Possibilities

A new type of high performance and compact neutron collimator can be manufactured from Gd- or B-doped microchannel plates (MCPs). Structures only a few mm thick have very narrow rocking curves and high out-of-angle rejection ratios, as observed previously with a cold neutron beam. We present the results of measurements with a collimated (L/D ratio ~280:1) thermal neutron beam. MCP collimators doped with 3 mole % of ^natGd₂O₃ as well as doped with 10 mole % of ¹⁰B₂O₃ were calibrated for transmission versus tilt angle. The MCPs used in this study were only 0.6 and 0.8 mm thick with ~8.5 mum circular pores on 11.5 mum centers. All the measured rocking curves agree well with the theoretically predicted performance. Both experimental and modeling results indicate that very efficient MCP collimators (with <0.1deg wide rocking curves and a rejection ratio exceeding 10³) can be built with the existing technology. The possibility to manufacture collimators with very large L/D ratios exceeding 1000:1 is also discussed for the case of unetched MCPs. The peak transmission of such devices with very sharp rocking curves will be limited to ~40% by the transmission of the undoped glass. Application of MCP collimators for scatter rejection in neutron radiography is also considered in terms of possible image distortions, which are shown to occur only for the systems with detector spatial resolution better than 20 mum FWHM     

High‐Resolution Strain Mapping Through Time‐of‐Flight Neutron Transmission Diffraction with a Microchannel Plate Neutron Counting Detector

Abstract: Conventional neutron radiography can be strongly enhanced by obtaining Bragg‐edge information spatially correlated with the attenuation coefficient. This can now be achieved through time‐of‐flight techniques at pulsed neutron sources, utilising a neutron counting detector with high‐spatial and high‐temporal resolution. In these measurements, the positions of Bragg edges can in principle be obtained for each 55 × 55 μm² pixel of the radiographic image. The combination of both Bragg‐edge and attenuation information enables high spatial resolution studies to be carried out on material composition, phase transitions, texture variations, as well as residual strain mapping. In this article, we present the results of high‐resolution strain maps of a ferritic steel cantilever sample measured at different loads by both transmission and conventional diffraction modes, as well as strains in an austenitic steel compact‐tension (CT) crack sample. The proof of principle experiments performed on the ENGIN‐X beamline on a bent cantilever arrangement resulting in a uni‐axial stress field verified that the strain values measured in diffraction and transmission mode are in good agreement. The characteristics of the transmission mode detector as well as the measured strain maps and future possibilities of this technology are discussed.     

Microchannel plate cross-strip detectors with high spatial and temporal resolution

The cross-strip imaging readout employs charge division, and centroiding, of microchannel plate charge signals detected on two orthogonal layers of sense strips to encode event X-Y positions and times. We have developed cross-strip detectors and fully parallel channel position encoding electronics. The front-end amplifiers utilize two 32-channel pre-amplifier ASICs that send signals to a full 64-channel 60 MHz ADC circuit followed by a FPGA event-processing board. Tests with a software Finite Impulse Response filter and centroiding algorithm demonstrate <10mm resolution with a 32mm cross-strip anode detector using low microchannel plate gain (～10(6)). The self-triggered event timing accuracy is 750 ps, and the system is capable of encoding photons at >1 MHz in combination with firmware-based FPGA centroiding algorithms.     

Electronic and optical moi? Interference with microchannel plates: artifacts and benefits

The spatial resolution of position-sensitive detectors that use stacks of microchannel plates (MCP's) with high-resolution anodes can be better than 20-mum FWHM [Proc. SPIE 3114, 283-294 (1997)]. At this level of accuracy, channel misalignments of the MCP's in the stack can cause observable moiré interference patterns. We show that the flat-field detector response can have moiré beat pattern modulations of as great as ~27% with periods from as small as a few channel diameters to as great as the size of a MCP multifiber. These modulations, however, may be essentially eliminated by rotation of the MCP's or by a mismatch of the channel sizes. We also discuss how the modulation phenomena can be a useful tool for mapping the metric nonlinearities of MCP detector readout systems. Employing the optical moiré effect, we demonstrate a simple, but effective, technique for evaluation of geometrical deformations simultaneously over a large MCP area. For a typical MCP, with a 60-channel-wide multifiber, we can obtain accuracies of 1.2 mrad for multifiber rotations and twists and 35/(L/p) mrad for channel-long axis distortions (where L/p is MCP thickness to interchannel distance ratio). This technique may be used for the development of MCP x-ray optics, which impose tight limitations on geometrical distortions, which in turn are not otherwise easily measurable with high accuracy.     

Investigation of microstructure in additive manufactured Inconel 625 by spatially resolved neutron transmission spectroscopy

Non-destructive testing techniques based on neutron imaging and diffraction can provide information on the internal structure of relatively thick metal samples (up to several cm), which are opaque to other conventional non-destructive methods. Spatially resolved neutron transmission spectroscopy is an extension of traditional neutron radiography, where multiple images are acquired simultaneously, each corresponding to a narrow range of energy. The analysis of transmission spectra enables studies of bulk microstructures at the spatial resolution comparable to the detector pixel. In this study we demonstrate the possibility of imaging (with ~100 μm resolution) distribution of some microstructure properties, such as residual strain, texture, voids and impurities in Inconel 625 samples manufactured with an additive manufacturing method called direct metal laser melting (DMLM). Although this imaging technique can be implemented only in a few large-scale facilities, it can be a valuable tool for optimization of additive manufacturing techniques and materials and for correlating bulk microstructure properties to manufacturing process parameters. In addition, the experimental strain distribution can help validate finite element models which many industries use to predict the residual stress distributions in additive manufactured components.