Synthesis and Crystal Structure of N-phenylthiocyano-phenylthioformamide-bis （ η5-methylcyclopentadienyl） （tetrahydrofuran） Samarium （Ⅲ）

The insertion reaction of phenyl isothiocyanate into the Ln-S bond was studied. Phenyl isothiocyanate reacted with [(CH3C5H4)2Sm(SPh)(THF)]2 to give the title complex, (CH3C5H4)2Sm[SC(SPh) NPh](THF),in good yield, which was characterized by elemental analyses, IR, ^1H NMR and X-ray structural determination. The crystal structure analysis of complex shows that samarium atom is coordinated by two CH3C5H4 groups, one O atom of THF, and N and S atoms from the SC(SPh)NPh ligand to form a distorted trigonal-bipyramidal geometry.     

Synthesis, Characterization and Crystal Structure of Neutral Homoleptic Lanthanide Amide Yb(NPh_2)_3(THF)

Ｌａｎｔｈａｎｉｄｅａｍｉｄｅｃｏｍｐｌｅｘｅｓａｒｅａｎｉｍ ｐｏｒｔａｎｔｃｌａｓｓｏｆｐｒｅｃｕｒｓｏｒｓｆｏｒｌａｎｔｈａｎｉｄｅｄｅｒｉｖａｔｉｖｅｓ .Ｉｔｃａｎｂｅｅａｓｉｌｙｔｒａｎｓｆｏｒｍｅｄｔｏｃｏｒ ｒｅｓｐｏｎｄｉｎｇｌａｎｔｈａｎｉｄｅｃｏｍｐｌｅｘｂｙｒｅａｃｔｉｎｇｗｉｔｈｉｎｖｏｌｖｉｎｇｐｒｏｔｉｃｒｅａｇｅｎｔｓ[1,2 ] .Ｔｈｅｌａｎｔｈａｎｉｄｅａｍｉｄｅｕｓｅｄａｓｓｙｎｔｈｅｔｉｃｐｒｅｃｕｒｓｏｒｉｓｎｅｕｔｒａｌｈｏｍｏｌｅｐｔｉｃｃｏｍｐｌｅｘ ,ｏｔｈ…     

Synthesis and Characterization of the First Dinuclear Europium （Ⅱ） Complex Supported by Carbon-Bridged Biphenolate Ligand

Amongpossiblealternativestothetraditionalan cillaryligandbis(cyclopentadienyl)setinrareearth metalchemistry,alkoxides(aryloxides)havereceived muchattentionandbecomeincreasinglypopularsince theyareeasilyavailable,tunableandevenpotentially recyclableancillarysetsformediatingthereactivityof theseelectropositivecations[1,2].Thechelatebiphenol andbinaphtholhavebeenfoundtobeabletoactasa dianionicligandintherareearthchemistry,whichhas theadvantagesofavoidingligandredistributionreac tions,andallowingth…     

二胍基钛配合物对苯乙烯聚合反应的催化性能研究

初步研究了所合成的五个二胍基钛配合物与改性的甲基铝氧烷(MMAO)组成的摧化体系对苯乙烯聚合的催化性能。结果表明:二胍基钛二氯化物和MMAO组成的催化体系可以催化苯乙烯的立体规整聚合,得到高间同含量的聚苯乙烯。     

Reaction of Bis （Methylcyclopentadienyl） Lanthanide Amido Complex with n-Hexyl isocyanate-Synthesis and Characterization of {（MeC5H4 ）2 Yb[ OC（NPh2 ）N（n-hexyl） ]}2

In recent years,the synthesis of polyisocyanatesand their chemical structures have received consider-able attention,because polyisocyanates have somespecial properties,such as chiral spiral structure[1]and liquid crystal[2]etc.We previously reported thatcyclopentadienyl lanthanide amido complexes[3]anddivalent lanthanide complexes[4]both can catalyze theoligomerization or polymerization of phenyl isocyanate.Furthermore,the active intermediates of these reac-tions were obtained by the stoichiom…     

Synthesis, Crystal Structure of [ （MeC5H4）2Ln（μ-OCH2 CH2NMe2 ） ]2 （Ln = Sm, Y, Nd） and Their Catalytic Activity for Ring-Opening Polymerization of ε-Caprolactone

Reaction of (MeC5H4)3Ln with HOCH2CH2NMe2 in tetrahydrofuran (THF) gives the new complexes [ (MeC5H4)2Ln(μ-OCH2CH2NMe2)]2(Ln = Sm, Y, Nd) with nitrogen functionalized μ-alkoxide ligand. The complexes were characterized by elemental analysis and IR, and [ (MeC5H4)2Sm(μ-OCH2CH2NMe2)]2 was structurally characterized by the X-ray diffraction to be a dimer formed by two unsymmetric oxygen bridges. The complex has a tricyclic skeleton with the additional two Sm- N bonds via intmmoleeular coordination of OCH2CH2NMe2. The coordination number of the central metal Sm is nine. The tide complexes show good catalytic activity for ring-opening polymerization of ε-capmlactone.     

Synthesis, Characterization and Crystal Structure of Neutral Homoleptic Lanthanide Amide Yb（NPh2）3（THF）2

A neutral homoleptic lanthanide amide Yb(NPh2)3(THF)2 was obtained by reaction of anhydrous YbCl3 with LiNPh2 in THF. The product was characterized by elemental analysis, infrared spectrum and X-ray crystallographic analysis. The crystal data are monoclinic, P21/n space group, a=1.2052(2) nm, b=1.9369(3) nm, c=1.6523(2) nm, β=92.79(1)°, V=3.8524(9) nm3, Z=4, Dc=1.417 g*cm-3, μ=24.67 cm-1 (Mo Kα), F(000)=1668, R=0.036, Rw=0.039. The central metal ytterbium is coordinated by three terminal NPh2 groups and two THF molecules to form a five-coordinate distorted trigonal bipyramid. The mean Yb-N bond length is 0.2219(6) nm.     

Synthesis and characterization of lanthanide complexes containing a bulky tridentate [N,N,O] Schiff base ligand

The lanthanide complexes containing a bulky tridentate [N,N,O] Schiff base ligand 3,5-But2-2-(OH)C6H2CH=N-8-C9H6N (HL) were synthesized and characterized. The reaction of anhydrous LnCl3 with NaL formed in situ in a 1:1 molar ratio in THF at room temperature afforded the lanthanide Schiff base dichloride complexes LnLCl2(DME) (Ln=Eu (1);Sm (2)). Complexes 1 and 2 can be used as precursors for the synthesis of the lanthanide cyclopentadienyl Schiff base derivatives. The reactions of complexes 1 and 2 with one equiv of NaCH3C5H4 in THF provided the desired products LnL(CH3C5H4)Cl(THF)·THF (Ln=Eu (3);Sm (4)) in good isolated yields. These complexes were characterized by elemental analysis, IR spectra, and X-ray structural determination, in the case of complexes 3 and 4. The crystal data of complex 3 are monoclinic, P21/c space group, a=1.3370(2) nm, b=1.5190(2) nm, c=1.8910(3) nm, β=109.846(4)°, V=3.6125(8) nm3, Z=4, Dc=1.416 mg/m3, μ=1.847 mm-1, F(000)=1584, R=0.0707, wR=0.1350. The crystal data of complex 4 are monoclinic, P21/c space group, a=1.3383(1) nm, b=1.5210(2) nm, c=1.8960(2) nm, β =109.878(3)°, V=3.6293(7) nm3, Z=4, Dc=1.407 mg/m3, μ=1.728 mm-1, F(000)=1580, R=0.0670, wR=0.1385.     

Synthesis and Crystal Structure of Bis （tert-butyl-cyclopentadienyl） Erbium Ethoxide, （t-BuCp）2ErOEt

Ｍｏｓｔｏｆｏｒｇａｎｏｌａｎｔｈｏｃｅｎｅｃｏｍｐｌｅｘｅｓｃｏｎ ｔａｉｎｉｎｇＬｎ Ｃσ ｂｏｎｄｈａｖｅｐｒｏｖｅｎｔｏｂｅｈｉｇｈｌｙｅｆｆｉｃｉｅｎｔｃａｔａｌｙｓｔｓｏｒｐｒｅｃａｔａｌｙｓｔｓ ,ｓｕｃｈａｓｆｏｒＣ-Ｈｂｏｎｄａｃｔｉｖａｔｉｏｎｒｅａｃｔｉｏｎ[1] ,ｈｙｄｒｏｇｅｎａｔｉｏｎｒｅａｃｔｉｏｎ[2 ] ,ａｎｄｈｏｍｏｇｅｎｏｕｓｐｏｌｙｍｅｒｉｚａ ｔｉｏｎ[3] .Ｈｏｗｅｖｅｒ ,ａｍｏｎｇｔｈｉｓｆａｍｉｌｙｏｆｃｏｍ ｐｌｅｘｅｓ ,σ ｂｏｎｄｅｄｏｒｇａｎｏｌａｎｔｈｏｃ…     

Synthesis, Characterization, and Reactivity of Amine Bis（phenolato） Cyclopentadienyl Lanthanide Complexes

（C5H5）3Ln（THF）reacted with amine bis（phenol） LH2 [ L = Me2NCH2CH2N {CH2-（2-O-C6H2-But^1-3-Me- 5）}2 ] in a 1：1 molar ratio in THF to generate the amine bis（phenolato） cyclopentadienyl lanthanide complexes LLn（C5H5） （THF）·（THF）,（Ln = La （1）, n =0; Ln = Sm（2）, n = 1） in high yields. Complexes 1 and 2 were fully characterized by elemental analysis, NMR （for 1） and IR spectra, and X-ray structural determination. The crystal data of complex 1 are monoclinic, P21/c space goup, a= 1.1595（1） nm, b = 1.8588（2） nm, c = 1.6647（1） nm, β = 98.490（2）°, V =3.5486（5） nm^3, Z =4, Dc = 1.338 mg· m^3,μ = 1240 mm^-1, F（000）= 1488, R =0.0249, wR = 0.0568. The crystal data of complex 2 are monoclinic, P21/c sp ace goup, a = 0.9692 （1） nm, b = 1.4583 （2） nm, c = 2.8192 （3） nm, = 96.805 （2）°, V = 3.9584 （7） nm^3, Z=4, Dc =1.340 mg · ma, μ = 1.524 mm^-1, F（000）= 1668, R =0.0346, wR =0.0756. The attempts failed to synthesize the amine bis（phenolate） lanthanide alkoxides by the reactions of complexes 1 and 2 with alcohols. The preliminary results revealed that complex 1 can initiate ε-caprolactone polymerization.