| Synthesis and Crystal Structure of N-phenylthiocyano-phenylthioformamide-bis （ η5-methylcyclopentadienyl） （tetrahydrofuran） Samarium （Ⅲ） |
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| 引用本文： | 李焕荣,姚英明,沈琪,王璐,郁开北.Synthesis and Crystal Structure of N-phenylthiocyano-phenylthioformamide-bis （ η5-methylcyclopentadienyl） （tetrahydrofuran） Samarium （Ⅲ）[J].中国稀土学报(英文版),2002,20(5):370-373. |
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| 作者姓名： | 李焕荣 姚英明 沈琪 王璐 郁开北 |
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| 作者单位： | [1]DepartmentofChemistryandChemicalEngineering,SuzhouUniversity,Suzhou215006,China [2]DepartmentofChemistryandChemicalEngineering,SuzhouUniversity,Suzhou215006,China／／StateKeyLaboratoryofOrganometallicChemistry,ShanghaiInstituteofOrganicChemistry,ChineseAcademyofSciences,Shanghai200032.Chinn [3]ChengduInstituteofOrganicChemistry,AcademiaSinica,Chengdu610041,China |
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| 基金项目： | ProjectsupportedbytheNationalNatureScienceFoundationofChina ( 2 0 0 72 0 2 7 |
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| 摘 要： | The insertion reaction of phenyl isothiocyanate into the Ln-S bond was studied. Phenyl isothiocyanate reacted with (CH3C5H4)2Sm(SPh)(THF)]2 to give the title complex, (CH3C5H4)2SmSC(SPh) NPh](THF),in good yield, which was characterized by elemental analyses, IR, ^1H NMR and X-ray structural determination. The crystal structure analysis of complex shows that samarium atom is coordinated by two CH3C5H4 groups, one O atom of THF, and N and S atoms from the SC(SPh)NPh ligand to form a distorted trigonal-bipyramidal geometry.
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| 关 键 词： | 钐 稀土 合成 晶体结构 核磁共振 XRD 硫醇盐 插入反应 |
Synthesis and Crystal Structure of N-phenylthiocyano-phenyl-thioformamide-bis(η5-methylcyclopentadienyl)(tetrahydrofuran) Samarium(Ⅲ) |
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| Li Huanrong,Yao Yingming.Synthesis and Crystal Structure of N-phenylthiocyano-phenyl-thioformamide-bis(η5-methylcyclopentadienyl)(tetrahydrofuran) Samarium(Ⅲ)[J].Journal of Rare Earths,2002,20(5):370-373. |
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| Authors: | Li Huanrong Yao Yingming |
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| Abstract: | The insertion reaction of phenyl isothiocyanate into the Ln S bond was studied. Phenyl isothiocyanate reacted with (CH 3C 5H 4) 2Sm(SPh)(THF)] 2 to give the title complex, (CH 3C 5H 4) 2SmSC(SPh)NPh](THF), in good yield, which was characterized by elemental analyses, IR, 1H NMR and X ray structural determination. The crystal structure analysis of complex shows that samarium atom is coordinated by two CH 3C 5H 4 groups, one O atom of THF, and N and S atoms from the SC(SPh)NPh ligand to form a distorted trigonal bipyramidal geometry. |
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| Keywords: | rare earths samarium thiolate complex insertion reaction phenyl isothiocyanate |
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