Effect of Co,Pd and Pt ultra-thin films on the Ni-silicide formation: investigating the sandwich configuration

The effect of Co, Pd and Pt ultrathin films on the kinetics of the formation of Ni-silicide by reactive diffusion is investigated. 50 nm Ni/1 nm X/ 50 nm Ni (X?=?Co, Pd, Pt) deposited on Si(100) substrates are studied using in-situ and ex-situ measurements by X-ray diffraction (XRD). The presence of Co, Pd or Pt thin films in between the Ni layers delays the formation of the metal rich phase compared to the pure Ni/Si system and thus these films act as diffusion barriers. A simultaneous silicide formation (δ-Ni₂Si and NiSi phases) different from the classic sequential formation is found during the consumption of the top Ni layer for which Ni has to diffuse through the barrier. A model for the simultaneous growth in the presence of a barrier is developed, and simulation of the kinetics measured by XRD is used to determine the permeability of the different barriers. Atom probe tomography (APT) of the Ni/Pd/Ni system shows that the Pd layer is located between the Ni top layer and δ-Ni₂Si during the silicide growth, in accordance with a silicide formation controlled by Ni diffusion through the Pd layer. The effect of the barrier on the silicide formation and properties is discussed.

     

Creative clusters in the regeneration of Valletta and the cultural politics of Strait Street

The paper aims to unfold the narrative of development in a creative cluster project for the regeneration of Strait Street in Valletta, Malta. This is approached by first examining the distinctive, historically contentious background of the neighbourhood and, thereafter, unpacking the development narrative of policy documents and the discursive and material constructs about the creative city approach to regeneration strategies in the city. Using a ‘system-wide’ analytical framework, this material is then scrutinized to gain an understanding of the specificities involved and, finally, discuss the crucial features of the key dimensions elucidating the potential strengths and weaknesses of the case     

Flexible,Mechanically Stable,Porous Self-Standing Microfiber Network Membranes of Covalent Organic Frameworks: Preparation Method and Characterization

Covalent organic frameworks (COFs) show advantageous characteristics, such as an ordered pore structure and a large surface area for gas storage and separation, energy storage, catalysis, and molecular separation. However, COFs usually exist as difficult-to-process powders, and preparing continuous, robust, flexible, foldable, and rollable COF membranes is still a challenge. Herein, such COF membranes with fiber morphology for the first time prepared via a newly introduced template-assisted framework process are reported. This method uses electrospun porous polymer membranes as a sacrificial large dimension template for making self-standing COF membranes. The porous COF fiber membranes, besides having high crystallinity, also show a large surface area (1153 m² g⁻¹), good mechanical stability, excellent thermal stability, and flexibility. This study opens up the possibility of preparation of large dimension COF membranes and their derivatives in a simple way and hence shows promise in technical applications in separation, catalysis, and energy in the future.     

Quality of information and communication technology introduction

Software Quality Journal -     

Optimal packing of material flow on conveyor belts

We are interested in an optimal packing density problem for material flows on conveyor belts in two spatial dimensions. The control problem is concerned with the initial configuration of parts on the belt to ensure a high overall flow rate and to further reduce congestion. An adjoint approach is used to compare the optimization results from the microscopic model based on a system of ordinary differential equations with the corresponding macroscopic model relying on a hyperbolic conservation law. Computational results highlight similarities and differences of both optimization models and emphasize the benefits of the macroscopic approach.     

NaWuReT-Workshop: Forschung in der Reaktionstechnik für und mit der Gesellschaft

In this article, the results of the NaWuReT (Early Career Reaction Engineers) workshop on the topic “Are we doing relevant science?” are presented. The topics “(In)surmountable hurdles for Citizen Scientists in reaction engineering?” and “Circular Economy in reaction engineering with/for society?” were discussed. Therefrom, a variety of ideas and suggestions were extracted.     

Mercury levels in lichens from different host trees around a chlor-alkali plant in New Brunswick,Canada

Mercury concentrations were determined in the epiphytic lichen Hypogymnia physodes along five transects starting from a chlor-alkali plant located at Dalhousie, New Brunswick, a landfill site and a nearby electricity generating station. Lichen samples were collected from white birch (Betula papyrifera) and spruce (Picea sp.) or balsam fir (Abies balsamea). Average lichen background mercury values were 0.088+/-0.005 microg/g from white birch and 0.148+/-0.046 microg/g from spruce trees, with a detection limit of 0.05 microg/g. The chlor-alkali plant and a power plant were identified, respectively, as a major source and a minor source of elevated mercury levels in lichens. At 125 m north-west of the New Brunswick Power plant, 0.28 microg/g Hg were found in Hypogymnia physodes from spruce trees, while at 250 m west (downwind) of the chlor-alkali plant, 3.66 microg/g of mercury were determined. High values, 0.98 microg/g in lichens from spruce trees and 0.79 microg/g in lichen samples from white birch were also measured at 125 m south of the chlor-alkali plant and decreased exponentially with distance. The sphere of influence of the chlor-alkali plant with respect to mercury deposition was estimated to extend 2.4-3.4 km from the plant. The mercury concentrations in Hypogymnia physodes collected from white birch were significantly lower than the concentrations in the same lichen from spruce trees in areas with elevated levels of mercury, but not in areas with low mercury levels. The magnitude of this difference dropped with distance from the source.     

Complexation of organic compounds in the presence of Al3+ during micellar flocculation

Complexes of Al and model pollutants phenol, benzoic acid, 2,4-D (2,4-dichlorophenoxyacetic acid) and 2,4-DB (2,4-dichlorophenoxybutiric acid) play a key role in the removal of organic pollutants by co-adsorption on micelles of anionic surfactants flocculated by means of Al(3+). This technique, known as adsorptive micellar flocculation (AMF), is related to removal of organic compounds by coagulation-precipitation with Al and Fe salts. Some of the stoichiometries found (6Al:1L and higher, with "L" the organic compound) indicate that complexes of a cationic nature form in the presence of high excesses of Al, possibly polyaluminium complexes related to the species [Al(13)O(4)(OH)(24)](7+). In the case of phenol it has been established by spectroscopic measures that in the range of [Al(2)(SO(4))(3)](tot) between 5 x 10(-5) and 3 x 10(-4)M and [phenol](tot) between 10(-3) and 6 x 10(-3)M complexes exist at pH as low as 2.4. The results show that AMF may be explained by the chemisorption of molecules of organic compounds able to incorporate into the polyaluminic complexes occurring within the Stern layer of flocculating micelles.     

Characterization of activated sludge flocs by confocal laser scanning microscopy and image analysis

In this study we present a new approach to determine volumes, heterogeneity factors, and compositions of the bacterial population of activated sludge flocs by 3D confocal imaging. After staining the fresh flocs with fluorescein-isothiocyanate, 75 stacks of images (containing approx. 3000 flocs) were acquired with a confocal laser scanning microscope. The self-developed macro 3D volume and surface determination for the KS 400 software package combined the images of one stack to a 3D image and calculated the real floc volume and surface. We determined heterogeneity factors like the ratio of real floc surface to the surface of a sphere with the respective volume and the fractal dimension (D(f)). According to their significant influence on floc integrity and quality, we also investigated the chemical composition of flocs and quantified their bacterial population structure by using group-specific rRNA-targeted probes for fluorescence in situ hybridization. By a settling experiment we enriched flocs with poor settling properties and determined the above-mentioned parameters. This approach revealed shifts in floc volume, heterogeneity, and bacterial and chemical composition according to the settling quality of the flocs.