In-situ synthesis of zirconium oxycarbide by electroreduction of ZrO2/C in molten salt

Homogenous ZrC_xO_y powders have been successfully synthesized by in-situ electro-reduction of solid ZrO₂–C composite precursors in molten CaCl₂. The effect of applied cell voltage and molar ratio of ZrO₂ to C on preparation of ZrC_xO_y were investigated. The reduction pathway of the composite electrode was studied based on the analysis of intermediate products using X-ray diffraction (XRD) and scanning electron microscopy (SEM). The results show that ZrO₂ is firstly converted to CaZrO₃. The resulting CaZrO₃ is then reduced to ZrC_xO_y. The ZrC_xO_y formation is dramatically influenced by electrolysis voltage and molar ratio of ZrO₂ to C: a higher cell voltage and lower molar ratio of the ZrO₂ to C are more preferable for the formation of ZrC_xO_y powder. Homogenous ZrC_xO_y powders with particle size of ~100 nm are synthesized by ZrO₂/C starting elemental powders in CaCl₂ molten salt at 1123 K for more than 3 h, when the cell voltage is 3.0 V and the molar ratio of the ZrO₂ to carbon starting materials is 1:1.0.     

Synthesis and photoluminescent properties of high-efficient color-tunable Ba3Y2B6O15: Ce3+, Tb3+ phosphors

High-efficient Ce³⁺/Tb³⁺ co-doped Ba₃Y₂B₆O₁₅ phosphors with multi color-emitting were firstly prepared, and their structural and luminescent properties were studied by XRD Rietveld refinement, emission/excitation spectra, fluorescence lifetimes as well as temperature-variable emission spectra. Upon 365?nm excitation, the characteristic blue Ce³⁺ band along with green Tb³⁺ peaks were simultaneously found in the emission spectra. Moreover, by increasing concentration of Tb³⁺, a blue-to-green tunable emitting color could be realized by effective Ce³⁺→Tb³⁺ energy transfer. Furthermore, all Ba₃Y₂B₆O₁₅: Ce³⁺, Tb³⁺ phosphors exhibit high internal quantum efficiency of ~?90%, while the temperature-variable emission spectra reveal that the phosphors possess impressive color stability as well as good thermal stability (T₅₀ =?~?120?°C). The results indicate that these efficient color-tuning Ba₃Y₂B₆O₁₅: Ce³⁺, Tb³⁺ might be candidate as converted phosphor for UV-excited light-emitting diodes.     

WIRELESS BODY-AREA NETWORKS

The last decade has witnessed the convergence of three giant worlds:electronics,computer science and telecommunications.The next decade should follow this convergence in most of our activities with the generalization of sensor networks.In particular with the progress in medicine,people live longer and the aging of population will push the development of wireless person-     

老井复查评价技术在浅层油藏中的研究与应用

本文以靖安地区浅层老井为例,利用钻井、录井、测井、取心等资料,结合现代测井解释评价技术,对受当时技术条件限制被误判的储层进行再分析研究。制定可行的复查评价标准与流程,确定出油下限,优选补孔潜力井,并结合精细地质研究成果筛选建产目标区,达到挖潜增效和滚动增储的双重目的。对老区日后寻找新储量进行勘探开发具有十分重要的意义。     

中美欧建筑结构荷载规范对比研究

随着"一带一路"国际工程项目的持续推进,关于国内外建筑结构荷载规范的对比研究变得十分迫切.本文针对中国、美国和欧洲建筑结构荷载规范,从承载力极限状态和正常使用状态两个方面,对荷载组合的设计表达式与分项系数取值进行了系统研究.结合实际工程算例详细分析了中美欧荷载组合计算方法的异同,研究表明:中美规范计算结果接近,欧洲规范计算结果偏于保守,产生差异的主要原因在于不同规范的分项系数取值不同,部分规范引入调整系数以增大或减小某项荷载组合值.     

Fabrication and use of artificial superhydrophilic surfaces

Superhydrophilic surfaces have recently received some attention due, in large part to the intense interest on the antonymous field of superhydrophobicity. Imparting superhydrophilicity onto surfaces through coatings, texturing, or choice of materials appears to hold significant commercial promise for the protection for optical devices (e.g. anti-fogging), self-cleaning, and stain resistant paints and flooring and use in the area of ‘intelligent’ coatings. In this review, the fabrication and application of artificial superhydrophilic surfaces are discussed. The focus is on results reported over the past decade for these materials. The contents of this review are written to provide an introductory yet comprehensive overview of this emerging field.     

颗粒在椭圆形回转干馏炉内运动分析

通过实验研究颗粒在不同椭圆滚筒内的运动情况,分析了不同填充率、不同转速和不同颗粒粒径对其的影响。由实验得出:颗粒在椭圆不同位置的运动情况并不一致,随着长短轴之比变大,运动趋于平缓;填充率降低会引起颗粒运动模式过渡区间变大,进入小瀑布模式所需转速增加;颗粒粒径增大,颗粒在筒内受重力、摩擦力的影响变得更加明显,在长轴垂直水平位置,所受惯性影响更加显著,并出现明显的多种模式相结合的运动形式。     

Multicolor Emission in a Single‐Phase Phosphor Ca3Al2O6:Ce3+,Li+: Luminescence and Site Occupancy

A single‐phase multicolor emitting phosphor, Ca₃Al₂O₆:Ce³⁺,Li⁺, was prepared by a solid‐state reaction. When the Ce³⁺ concentration is lower than 0.030 (molar ratio in Ca₃Al₂O₆), yellow and greenish blue emissions can be observed under the excitation by a blue and a near UV light, respectively. The yellow‐emitting phosphor possesses an internal quantum efficiency of 89%. Additional purplish blue emission turns up when Ce³⁺ concentrations are higher than 0.040. Tunable emission bands are originated from Ce³⁺ ions on different Ca sites in Ca₃Al₂O₆. Although the emission band of purplish blue or greenish blue overlaps the excitation band of yellow emission, and the distances between the unlike Ce³⁺ ions are in the range of electric dipole–dipole interaction, no energy transfer is observed. Furthermore, emission wavelengths for the yellow, greenish blue, and purplish blue emission show little change upon increasing Ce³⁺ concentrations.     

校企合作化学与材料专业工程创新训练平台的规划与建设

强化工程训练教学环节,是地方本科学校应用技术人才培养模式创新的核心内容。本文从指导思想、原则和目标、具体措施等方面进行阐述和探讨,论述了化学与材料专业工程创新训练平台规划与建设的内容和保证其正常运行的措施。     

发动机缸盖螺栓疲劳断裂失效分析

通过断口(宏观)形貌分析、微观组织分析、化学成分检测以及硬度测试等手段对SCM435钢发动机缸盖螺栓的疲劳断裂进行失效分析。结果表明,失效SCM435钢缸盖螺栓的化学成分和显微组织合格,硬度符合技术要求。失效样件1的断裂原因为表面脱碳引起的脆性断裂,螺栓断裂部位的表面脱碳层宽为120μm;失效样件2主要是非金属夹杂物所引起的疲劳断裂,近球状的CaS-CaO-Al₂O₃-MgO复合型冶金夹杂物造成了沿晶裂纹。对材料的塑韧性、表面脱碳及非金属夹杂物等指标,提出了改善建议。