Influence of nanoadditives on ignition characteristics of Kusum (Schleichera oleosa) biodiesel

Biodiesel obtained from inedible sources emerged as a productive approach in Indian energy scenario due to the scarcity of food resources come up with extensive usage of edible crops. Kusum (Schleichera oleosa) oil is abundantly available in India and can be used as feedstock to produce biodiesel. However, issues such as higher viscosity, poor stability, and lower calorific value result in poor ignition characteristics, hence limiting its use in combustion applications. An improvement in performance and emission characteristics can be achieved by doping nanoparticles in Kusum biodiesel (KBD). The present work examines the impact of a metal compound and carbon‐primarily based nanoparticles on the evaporation time and ignition probability of the KBD. During the experimental process, different fuel samples of KBD were prepared by amalgamating nanoparticles; then, a sequence of hot plate (stainless steel) ignition test was conducted on these test fuels. The comparative assessment of neat biodiesel and the biodiesel fuel doped with 30 ppm each of alumina (Al2O3), and multiwalled carbon nanotubes (MWCNTs) nanoparticles were carried out. The Kusum oil was converted to biodiesel using two‐stage transesterification process. In the initial stage, refined oil was gone through the acid catalyst esterification process followed by the transesterification reaction. The prepared methyl ester was confirmed and characterized using GC‐MS technique. The thermophysical and spray properties of the test fuels including density, viscosity, calorific value, cloud/pour point, Sauter mean diameter (SMD), and specific surface area (SSA) were also calculated. The experimental result showed a significant increase in ignition probability and heat conduction properties due to improved surface area/volume ratio. Also, lower evaporation time was noted for metal/carbon‐based nanoparticles doped biodiesel as compared with neat biodiesel.     

Energy Efficient Multitier Random DEC Routing Protocols for WSN: In Agricultural

Wireless Personal Communications - Fog computing is an emerging paradigm that provides confluence facilities between Internet of Things (IoT) devices and cloud. The fog nodes process the...     

In vivo evaluation of a mucoadhesive polymeric caplet for intravaginal anti-HIV-1 delivery and development of a molecular mechanistic model for thermochemical characterization

Context and objective: The aim of this study was to develop, characterize and evaluate a mucoadhesive caplet resulting from a polymeric blend (polymeric caplet) for intravaginal anti-HIV-1 delivery.

Materials and methods: Poly(lactic-co-glycolic) acid, ethylcellulose, poly(vinylalcohol), polyacrylic acid and modified polyamide 6, 10 polymers were blended and compressed to a caplet-shaped device, with and without two model drugs 3′-azido-3′-deoxythymidine (AZT) and polystyrene sulfonate (PSS). Thermal analysis, infrared spectroscopy and microscopic analysis were carried out on the caplets employing temperature-modulated DSC (TMDSC), Fourier transform infra-red (FTIR) spectrometer and scanning electron microscope, respectively. In vitro and in vivo drug release analyses as well as the histopathological toxicity studies were carried out on the drug-loaded caplets. Furthermore, molecular mechanics (MM) simulations were carried out on the drug-loaded caplets to corroborate the experimental findings.

Results and discussion: There was a big deviation between the T_g of the polymeric caplet from the T_g's of the constituent polymers indicating a strong interaction between constituent polymers. FTIR spectroscopy confirmed the presence of specific ionic and non-ionic interactions within the caplet. A controlled near zero-order drug release was obtained for AZT (20 d) and PSS (28 d). In vivo results, i.e. the drug concentration in plasma ranged between 0.012–0.332?mg/mL and 0.009–0.256?mg/mL for AZT and PSS over 1–28 d.

Conclusion: The obtained results, which were corroborated by MM simulations, attested that the developed system has the potential for effective delivery of anti-HIV-agents.     

Hybrid composite friction materials reinforced with combination of potassium titanate whiskers and aramid fibre: Assessment of fade and recovery performance

Composite friction materials based on synergistic ternary combination of potassium titanate whiskers, aramid fibre and graphite have been characterized for friction braking performance on Krauss friction tester. The dynamics of friction build-up and friction-decay as a function of number of braking instances and modes of braking cycles have been found to be more consistent in the composites with ≥7.5 wt% of aramid fibres whereas the absolute friction effectiveness remained higher in the composites with ≥25 wt% of potassium titanate whiskers. Wear surface morphology has revealed topographical variations and their underlying role in controlling the friction and wear performance.     

An ab initio study of ZrB2–SiC interface strength as a function of temperature: Correlating phononic and electronic thermal contributions

This work focuses on understanding correlations between thermal conduction and mechanical strength in a model high temperature material interface. Analyses examine single crystal ZrB₂, single crystal SiC, and a 〈0 0 0 1〉–〈1 1 1〉 ZrB₂–SiC interface using a framework based on Car Parrinello molecular dynamics (CPMD) ab initio simulation method from 500 K to 2500 K. Analyses indicate that the strength reduction with increase in temperature is strongly correlated to phonon and electron thermal diffusivity change. With increase in temperature, phonon thermal diffusivity increases in the case of ZrB₂ and reduces in the cases of SiC as well as the interface. Electron contribution to thermal diffusivity increases with temperature increase in the case of interface. Examination of change in thermal properties at different mechanical strain levels reveals that the mechanisms of strength and thermal property change with increase in temperature may be similar to the mechanisms responsible for property change with change in applied strain.     

Atomistic analyses of the effect of temperature and morphology on mechanical strength of Si–C–N and Si–C–O nanocomposites

3-D molecular dynamics (MD) analyses of SiC–Si₃N₄ nanocomposite deformation and SiCO nanocomposite deformation are performed at 300 K, 900 K, and 1500 K. In SiC–Si₃N₄ nanocomposites, distribution of second phase SiC particles, volume fraction of atoms in GBs, and GB thickness play an important role in temperature dependent mechanical behavior. The deformation mechanism is a trade-off between the stress concentration caused by SiC particles and Si₃N₄–Si₃N₄ GB sliding. The temperature increase tends to work in favor of GB sliding leading to softening of structures. However, microstructural strength increases with increase in temperature when GBs are absent. In the case of SiCO nanocomposites, findings indicate that temperature change dependent amorphization of nanodomains, the nanodomain wall placement, the nanodomain wall thickness, and nanodomain size are important factors that directly affect the extent of crystallinity and the strength against mechanical deformation.     

Performance assessment of hybrid composite friction materials based on flyash–rock fibre combination

Friction composites based on several combinations of flyash and inorganic mineral rock fibres such as lapinus™ fibre were fabricated, characterised and tribo-evaluated. The tribo-performance in terms of their friction-fade and friction-recovery behaviour has been rigorously evaluated while synchronously taking into account of the in situ braking induced temperature rise in the disc at the braking interface on a Krauss friction testing machine following pulse velocity wave (PVW) 3212 norms as per the Economic Commission for Europe (ECE) regulations. The fade behaviour has been observed to be highly dependent on the combination of flyash–lapinus fibre e.g. fade remained maximum (45%) in the composite with the highest amount of lapinus fibre content and lowest amount of flyash whereas the frictional fluctuations in terms of μ_max − μ_min has been observed to be higher in case of low flyash–high lapinus fibre combination. The recovery response seemed unaffected by the disparity of ingredients and remained consistently stable within the range of 112 ± 2%. The analysis of friction and wear performance has revealed that flyash along with lapinus fibre provide thermo-mechanical stability and overall mechanical integrity to the system causing reduction in friction-fade whereas wear was found to be more recovery-controlled and less fade controlled. Worn surface morphology investigation using SEM has been carried out which has revealed that the interplay of flyash–lapinus combination and topographical attributes vis-a-vis dynamics of contact patches (formation–destruction) largely influence the friction and wear performance of such composites.