排序方式: 共有63条查询结果,搜索用时 15 毫秒
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水热法合成了Bi2WO6粉体,并采用XRD、FESEM及UV-Vis分光光度计对样品进行表征,研究了不同合成条件对产物形貌和催化性能的影响.UV-Vis漫反射谱表明产物在紫外和可见光区域均有吸收.样品的光催化性能通过降解RhB溶液来评价.结果表明:180℃,pH=2下合成24h获得的Bi2WO6紫外光催化性能最好,反应速率常数为0.03688/min.还讨论了不同pH值对合成样品催化性能的影响.催化剂的稳定性实验通过180℃,pH=2下合成24h获得的Bi2WO6多次催化实验来评估,结果表明4次循环实验后,样品的催化性能未有明显地衰减.在可见光下照射150min,催化剂对染料的降解率达到38%. 相似文献
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张金咏 《武汉理工大学学报(材料科学英文版)》2001,(2)
It was reported that TiB2 gains grew fast during sintering was a main cause for its properties degrading. In this paper the HP-sintering mechanics of TiB2 was studied and the results show that grains grow very fast when the sintering temperature is near 1800℃ . From the sintering dynamics, it can be concluded that grain fast growing results in boundary-transporting processing, during which grain boundary work as fast tunnel for material transporting. 相似文献
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Effects of Al2O3 and Ni as the additives on the sinterability, microstructure and mechanical properties were systematic studied. The experimental results show that only a relative density about 96.2% of hot-pressing TiB2-30%Al2O3 can be attained due to the plate-like TiB2 particle and its random orientation and excessive Al2O3 grain growth. When sintering temperature is higher than 1 700 ℃, TiB2 grain growth can be found, which obvious improves flexural strength of TiB2 matrix but decreases toughness. It seems that mechanical properties of TiB2-Al2O3 composites are mainly depended on relative density besides grain growth. otherwise, they will be determined by relative density and TiB2 matrix strength together. Anyway, Al2O3 addition can weaken the grain boundary and thus improve the toughness of the materials. A flexural strength of 529 MPa, Vickers hardness of 24.8 GPa and indentation toughness of 4.56 MPa·m1/2 can be achieved inTiB2-30vol% Al2O3. 相似文献
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Fe-Ni-Al mixtures as hot-pressing sintering additive to Titanium diboride (TiB2) were studied. It is found that liquid alloy formed under high temperature hardly has effects on the densification behaviors
of TiB2-independent. Fe-Ni-Al additive just works as filler between TiB2 particles and does not change the TiB2-independent sintering behaviors. Pressing mode has a great effect on the liquid flowing between TiB2 particles. Multiple-steps pressing mode will give more time and space for the liquid flowing and improve the relative density
of TiB2-Fe-Ni-Al cermet. 相似文献
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采用直流电弧等离子体设备(自行研制)制备金属氮化物纳米粒子,探讨了直流电弧等离子体条件下(高的热性能、高的化学反应活性、高的冷却速率、可控的气氛)氮化反应机理和金属氮化物纳米粒子的成核、生长机制.研究结果表明:反应温度和过饱和度及反应气体压力是影响成核、生长速率与临界成核半径的主要因素,冷却介质是影响产物粒度的关键因素.调整适当的工艺参数,可制备出平均粒径小于20 nm的AlN和小于80 nm的TiN纳米粒子,粉末粒径分布窄,形貌均匀且无团聚. 相似文献
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用溶胶-凝胶法制备了质量比m(Al2O3)/m(SiO2)分别为72/28、74/26和76/24(称为样品72/28、样品74/26和样品76/24)不同组成的莫来石单相胶,将单相胶在1 000℃下热处理2h,然后用放电等离子烧结技术分别在1 450、1 500、1 550℃烧结10 min,样品相对密度均可达97%以上.对烧结体的微观结构进行扫描电镜分析,结果表明;随着先驱体组成中SiO2含量降低,长轴晶的形成温度升高.3种样品的红外透波率均随烧结温度的上升而下降,其中样品72/28由于晶粒大小和气孔尺寸均较小,其透波率均高于相应烧结温度的另外两个样品.样品74/26在1 550℃烧结时,由于形成的长轴晶的直径与红外波长相当致使散射损失严重,透波率急剧下降,而样品76/24由于等轴晶的尺寸与红外波长相当,再加上第二相的形成造成的散射,使其透波率均较低. 相似文献