Dielectric performance and conductive mechanism of KNN-based ceramics prepared via sol–gel core–shell process

Journal of Materials Science: Materials in Electronics - 0.95(Li0.02Na0.50K0.48)(Nb0.95Sb0.05)O3–0.05AgTaO3@BaZrO3 (LNKNbSAT@BZ) lead-free ceramics were prepared via a sol–gel...     

Extinction and Non-extinction of Solutions to a Fast Diffusion p-Laplace Equation with Logarithmic Non-linearity

This paper deals with a class of fast diffusion p-Laplace equation with logarithmic non-linearity in a bounded smooth domain with homogeneous Dirichlet boundary condition. By using energy estimates and some ordinary differential inequalities, we study the conditions on extinction and non-extinction of global solutions. The results of this paper extend and complete the previous studies on this equation.

     

Double pyrovanadates CaMgV2O7: Formation mechanism,phase structure,and thermodynamic properties

A double pyrovanadate CaMgV₂O₇ sample was synthesized via a facile solid-state route under an air atmosphere. The nonequilibrium formation pathways of the CaMgV₂O₇ were investigated via powder X-ray diffraction. A multistep reactions path (metavanadates–pyrovanadates–double pyrovanadate CaMgV₂O₇) was proposed to describe the formation of the CaMgV₂O₇ considering the thermodynamic and kinetic factors. The cell unit parameters of the CaMgV₂O₇ sample indicated the crystallization according to a monoclinic system with space group P12/c1(14), and the lattice parameters of a = 6.756 Å, b = 14.495 Å, c = 11.253 Å, β = 99.12, and V = 108.806 Å³. X-ray photoelectron spectroscopy also confirmed the +5 oxidation state vanadium in CaMgV₂O₇. The endothermic effects at 1033 and 1143 K were related to the incongruent melting and liquidus temperatures of CaMgV₂O₇, respectively. The comprehensive thermodynamic properties of CaMgV₂O₇ were established in both low- and high-temperature regions, utilizing a physical property measurement system and multi-high-temperature calorimetry (96 lines). The heat capacity (200 J mol K⁻¹) and entropy (198 J mol K⁻¹) at 298.15 K were computed based on the low-temperature heat capacity values, and the enthalpy of formation at 298.15 K was also estimated. The fitted high-temperature capacity can be used to obtain the changes in the enthalpy, entropy, and Gibbs free energy. This study is part of building a reliable thermodynamic database of the CaO–MgO–V₂O₅ system.     

基于SOI衬底的宽带低损耗声表面波滤波器研究

使用结构为42°Y-X LiTaO₃(600 nm)/SiO₂(500 nm)/Si的SOI衬底，通过抑制横向模式等优化设计，研制了单端谐振器和声表面波滤波器。经测试，谐振器的谐振频率为1.5 GHz，品质因数(Q)值高达4 000；滤波器的中心频率为1 370 MHz，插入损耗为-1.2 dB，1 dB带宽为74 MHz，相对带宽达到5.4%，阻带抑制大于40 dB，且温度系数在-55~+85 ℃时优于-9×10^-6/℃。该产品具有高频、宽带、低损耗、低温漂、高阻带抑制的特点，其性能指标优异，具有很好的实用性。     

Phosphorus-doped silicon nanoparticles as high performance LIB negative electrode

Journal of Materials Science - Silicon is getting much attention as the promising next-generation negative electrode materials for lithium-ion batteries with the advantages of abundance, high...     

依托"大数据行业应用"虚拟教研室培养跨学科人才

在实施国家大数据战略和创新型国家建设的引导下,培养跨学科思维与能力是创新型人才培养的核心要求.大数据是一个典型的学科交叉的技术,资源分散是当前高校大数据人才培养存在的主要问题.该文以长沙理工大学"大数据行业应用"虚拟教研室建设为例,打造"大数据"特色跨学科跨专业教学组织,从课程体系、实践环节、师资队伍、质量监督等方面提出建设措施,为培养跨学科创新型复合型人才提供参考.     

分析化学实验课程中融入思政教育的探索与实践

高校专业课程思政建设要求落实立德树人和铸魂育人的根本任务,将实践教育和科学精神的培养相结合,培养专业扎实,具有责任感和使命意识的人才,构建全课程全方位的育人教育。分析化学实验课是化学必修的实践课程,从课前准备、实验操作以及课后探讨分析中,将课程思政教育渐进式融入,帮助学生构建将小我融入大我的科学精神和使命意识,真正将教书和育人有机统一,培育科学创新和理想信念坚定的专业人才。