全文获取类型
收费全文 | 735篇 |
免费 | 50篇 |
国内免费 | 3篇 |
学科分类
工业技术 | 788篇 |
出版年
2024年 | 1篇 |
2023年 | 14篇 |
2022年 | 32篇 |
2021年 | 46篇 |
2020年 | 43篇 |
2019年 | 39篇 |
2018年 | 38篇 |
2017年 | 33篇 |
2016年 | 31篇 |
2015年 | 37篇 |
2014年 | 42篇 |
2013年 | 56篇 |
2012年 | 56篇 |
2011年 | 43篇 |
2010年 | 26篇 |
2009年 | 23篇 |
2008年 | 27篇 |
2007年 | 26篇 |
2006年 | 17篇 |
2005年 | 15篇 |
2004年 | 12篇 |
2003年 | 10篇 |
2002年 | 12篇 |
2001年 | 6篇 |
2000年 | 3篇 |
1999年 | 7篇 |
1998年 | 6篇 |
1997年 | 7篇 |
1996年 | 8篇 |
1995年 | 7篇 |
1994年 | 6篇 |
1993年 | 11篇 |
1992年 | 6篇 |
1991年 | 5篇 |
1990年 | 3篇 |
1989年 | 2篇 |
1988年 | 5篇 |
1987年 | 2篇 |
1986年 | 3篇 |
1985年 | 2篇 |
1983年 | 3篇 |
1982年 | 3篇 |
1981年 | 4篇 |
1980年 | 2篇 |
1979年 | 4篇 |
1977年 | 1篇 |
1975年 | 1篇 |
1967年 | 1篇 |
1966年 | 1篇 |
排序方式: 共有788条查询结果,搜索用时 15 毫秒
1.
Md. Abdur Rahim Shamim Mahbub Md. Kamrul Islam Sk. Md. Ali Ahsan Shahed Rana Malik Abdul Rub Anish Khan Md. Anamul Hoque 《Journal of surfactants and detergents》2020,23(2):457-470
Conductometric and cloud point (CP) measurement studies have been performed to investigate the interaction of tetradecyltrimethylammonium bromide (TTAB) and Triton® X-100 (TX-100) with ciprofloxacin hydrochloride (CFH) in different solvents over the temperature range of 295.15–315.15 K. CFH is used for the treatment of various bacterial infections. The observed critical micelle concentration (CMC) values of TTAB were found to be reduced in the presence of electrolytes (Na2SO4/Na3PO4), and this reduction proceeds with the elevation of salt concentration. The order of the CMC of TTAB follows the trend: > >. The observed CMC values of TTAB were found to increase with increasing temperature and decrease with increasing concentration of CFH in aqueous medium. The values of Gibbs free energy of micellization () for the TTAB/TTAB + CFH mixture were found to be negative, implying spontaneous micellization. The estimated CP of TX-100 decreases with increasing concentration of TX-100 in aqueous medium. The CP values first decrease with increasing concentration of CFH and then increase at higher concentration of CFH almost in all cases investigated. The values of free energy of clouding were found to be positive in all cases studied implying that phase separation of TX-100 was nonspontaneous. The other thermodynamic parameters associated with the micellization of TTAB and the phase separation of TX-100 were estimated and explained. 相似文献
2.
3.
4.
Uzma Arif Nawaz M. Rana Shafia Qureshi Imran Haider Elmasry Yasser Hussain Shafiq 《Theoretical Foundations of Chemical Engineering》2020,54(6):1327-1339
Theoretical Foundations of Chemical Engineering - In this study, the simulations for first-order chemical reactions (constructive and destructive) in the flow of the Casson fluid with... 相似文献
5.
6.
7.
Rajangam Vinodh Prem Jyoti Sing Rana Chandu VV Muralee Gopi Zongmin Yang Raji Atchudan Kandan Venkatachalam Hee‐Je Kim 《Polymer International》2019,68(5):929-935
We successfully synthesized 13X zeolite using a hydrothermal method. Then, composites of polyaniline (PANI) with 13X zeolite and PANI–13X with platinum were prepared by chemical oxidative polymerization and chemical reduction, respectively. Field emission scanning electron microscopy, X‐ray diffraction, Raman spectroscopy and Brunauer–Emmett–Teller techniques were used to characterize the PANI–Pt and PANI–Pt–13X composites. Further, the electrocatalytic activity towards methanol oxidation of the synthesized catalysts was explored using cyclic voltammetry in 1 mol L?1 CH3OH + 0.5 mol L?1 H2SO4 solution. From the obtained results, PANI–Pt–13X shows superior performance compared to PANI–Pt towards methanol oxidation and electrical conductivity. Hence, the 13X zeolite‐incorporated PANI–Pt composite could be an efficient catalyst for direct methanol fuel cell applications. © 2019 Society of Chemical Industry 相似文献
8.
9.
Khani Ali Eskandani Morteza Derakhshankhah Hossein Soleimani Khadijeh Nakhjavani Sattar Akbari Massoumi Bakhshali Jahanban-Esfahlan Rana Moloudi Kave Jaymand Mehdi 《Journal of Polymer Research》2022,29(4):1-10
Journal of Polymer Research - Derivatives of formyl pyrazole were synthesized by the reaction of acetophenone, 4-methyl acetophenone, 3-acetyl furan, 3-acetyl thiophen and phenyl hydrazine... 相似文献
10.
Poly(ethylene oxide)‐g‐gellan polysaccharide nanocarriers for controlled gastrointestinal delivery of simvastatin 下载免费PDF全文
Herein, a novel gellan polysaccharide‐based amphiphilic copolymer was synthesized for the development of simvastatin‐loaded micellar nanoparticles. The nanoparticles were explored for their controlled drug release and improved pharmacodynamic potentials. The copolymer was characterized by Fourier transform infrared spectroscopy (FTIR) and elemental analysis. The onset of copolymer micellization was detected by fluorescence spectroscopy. Simvastatin was loaded into micellar particles by solvent evaporation method and the particles were then characterized by microscopic and light scattering techniques. The physical state of drug was studied by X‐ray diffraction analysis. Pharmacodynamic assessment of the micellar preparations was done on rabbit models. The copolymer formed micellar nanoparticles in water. Critical micellar concentration was 9.12mg/l. The micellar particles (426.8–912.6nm) entrapped a maximum of 18.86% drug. Higher negative zeta potential indicated physical stability of micellar systems. A simple diffusion mechanism was operative in the event of comparatively faster drug release in pH6.8 phosphate buffer solution. No significant drug‐copolymer interaction was traced by FTIR spectroscopy. The amorphization of drug into micellar particles reduced LDL‐cholesterol level by ~45% in hyperlipidemic rabbits and this was about 2.5 times higher than pure drug dispersion. Copolymer micellar nanoparticles of simvastatin could control cholesterol level in hyperlipidemic rabbits and thus had potential in drug delivery applications. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 42399. 相似文献