Hydrogen liberation from the dehydrocoupling of dimethylamine–borane at room temperature by using novel and highly monodispersed RuPtNi nanocatalysts decorated with graphene oxide

Addressed herein, we reported the fabrication of the graphene oxide (GO) supported monodispersed ruthenium–platinum–nickel (RuPtNi) nanomaterials (3.40 ± 0.32 nm) to be utilized as a catalyst in the process of dimethylamine borane (DMAB) dehydrogenation. The nanoparticles were fabricated through the ultrasonication method by co-reducing the Ru³⁺, Pt²⁺ and Ni²⁺ cations and then the nanomaterials were characterized by X-ray diffraction (XRD), Raman spectroscopy, transmission electron microscopy (TEM), high resolution transmission electron microscopy (HRTEM), electron energy loss spectroscopy (EELS), inductively coupled plasma optical emission spectrometry (ICP-OES), and X-ray photoelectron spectroscopy (XPS). The fabricated nanomaterials showed outstanding efficiency and remarkable reusability in addition to their record catalytic activity at low temperatures and with extreme low concentrations. They had a significantly high turnover frequency (TOF) (727 h^?1) and low activation energy (E_a) (49.43 ± 2 kJ mol^?1) for DMAB dehydrocoupling. To the best of our knowledge, RuPtNi@GO NPs become a very promising candidate as the best catalyst ever.     

Diversity and functional characteristics of lactic acid bacteria from traditional kefir grains

Traditional kefir grains were collected from distinct parts of Turkey, and their microbial profile was determined. A wide bacterial biota was observed formed by distinct lactic acid bacteria (LAB) in which Lactococcus lactis strains appeared to be dominant. Yeast species were also identified in kefir grains. Significant levels of antifungal and antibacterial activities were monitored in kefir isolates. All tested LAB produced an exopolysaccharide (EPS) containing glucose and galactose, and some strains formed a fructan‐type EPS. Importantly, low levels of antibiotic resistance were observed among the kefir isolates.     

Performance Analysis of a New MAC Protocol for Wireless Cognitive Radio Networks

Wireless Personal Communications - In this study, network performance analysis of a newly proposed cognitive radio wireless network (CRWN) medium access control (MAC) protocol is investigated in...     

Millimeter-wave Ground-based Synthetic Aperture Radar Imaging for Foreign Object Debris Detection: Experimental Studies at Short Ranges

In this paper, millimeter-wave imaging of foreign object debris (FOD)-type objects on the ground is studied with the help of ground-based synthetic aperture radar (GB-SAR) technique. To test the feasibility of detecting runway FODs with this technique, some preliminary experiments are conducted within short antenna-to-target ranges of small imaging patches. An automated stripmap GB-SAR system with stepped-frequency transmission is constructed together with a quasi-monostatic data collection operation. The imaging experiments for various braces and screws are then carried out by using 32–36?GHz and 90–95?GHz frequency bands of the millimeter-wave. Images reconstructed by a matched-filter based algorithm are analyzed to determine the proper system parameters for an efficient imaging and to comprehend the factors against a successful detection. Results demonstrate the capability of GB-SAR imaging in accurately locating these FOD-like targets under near-range operating conditions.