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1.
Jianping Lai Wen Hu Amit Datye Jingbei Liu Jan Schroers Udo D.Schwarz Jiaxin Yu 《材料科学技术学报》2021,84(25):97-104
A high-throughput approach based on magnetron co-sputtering of alloy libraries is employed to inves-tigate mechanical properties of crystalline and amorphous alloys in a ternary palladium(Pd)-tungsten(W)-silicon(Si)system with the aim to reveal the difference in plastic deformation response and extract the relevant structure-property relationships of the alloys in the system.It was found that in contrast to crystalline alloys,the amorphous ones,i.e.,metallic glasses,exhibited a much smaller fluctuation range in the plasticity parameters(Er2/H and Wp/Wt),indicating a significant difference in the plastic deformation mechanism controlling the mechanical properties for the respective alloys.We propose that the inho-mogeneous deformation of amorphous alloys localized in thin shear bands is responsible for the weaker compositional dependence of both plasticity parameters,while dislocation gliding in crystalline materials is significantly more dependent on the exact structure,thus resulting in a larger scattering range.Based on the representative efficient cluster packing model,a set of composition-dependent atomic structural models is proposed to figure out the structure-property relationships of amorphous alloys in Pd-W-Si alloy system. 相似文献
2.
C.E.BORJA I.A.FIGUEROA O.LOZADA-FLORES M.ESTRADA G.A.LARA-RODRíGUEZ J.A.VERDUZCO 《中国有色金属学会会刊》2018,(6)
分析ZrCuAlNi系大块金属玻璃的非晶形成能力、热学和力学性能。运用密实堆积和动态脆性指数模型从理论上确定合金的成分。采用铜模吸铸法在氩气保护下制备圆柱形和圆锥形铸锭。用X射线衍射表征圆锥形铸锭以便确定非晶结构。结果表明:两种合金的临界非晶直径为3 mm。用差示扫描量热法(DSC)分析其热行为,加热速率分别为0.5、0.67和0.83 K/s。γ参数、过冷液相区ΔT_x和约化玻璃转变温度T_(rg)等这些实验所得的参数均表明其具有高的非晶形成能力。非晶成分显示其脆性指数为40。合金的压缩试验采用的应变速率为0.016 s~(-1),得到弹性模量约为83 GPa,总应变约为5%,屈服强度为1.6 GPa,硬度为4 GPa。运用密实堆积和动态脆性指数模拟可以预测ZrCuAlNi系合金的非晶形成成分。 相似文献
3.
目前,德国纺织机械和高性能材料技术研究所(ITM)正对刨花金属短纤维纺制纱线的工艺过程进行广泛的调查研究。为顺利纺纱,必须考虑这类纤维的高耐磨性、高脆性和高刚性等特性,以及它们较高的塑性变形和粘滑运动倾向。基于传统成纱工艺,开发出以刨花金属短纤维为原料,经拉伸断裂、牵伸和纺纱过程制备纯金属纱线的纺纱工艺链。基于目前的研究,由刨花金属短纤维制备纯金属纱线的可行性已得以证实。所得金属纤维在高性能、低成本技术应用方面具有较高的潜力。 相似文献
4.
Suying Xu Adam C. Sedgwick Souad A. Elfeky Wenbo Chen Ashley S. Jones George T. Williams A. Toby A. Jenkins Steven D. Bull John S. Fossey Tony D. James 《Frontiers of Chemical Science and Engineering》2020,14(1):112
A boronic acid-based anthracene fluorescent probe was functionalised with an acrylamide unit to incorporate into a hydrogel system for monosaccharide detection. In solution, the fluorescent probe displayed a strong fluorescence turn-on response upon exposure to fructose, and an expected trend in apparent binding constants, as judged by a fluorescence response where D-fructose>D-galactose>D-mannose>D-glucose. The hydrogel incorporating the boronic acid monomer demonstrated the ability to detect monosaccharides by fluorescence with the same overall trend as the monomer in solution with the addition of D-fructose resulting in a 10-fold enhancement (≤0.25 mol/L). 相似文献
5.
The critical properties of the mixed manganite La0.67–x Y x Ba0.23Ca0.1Mn O3 with x=0.10 and x=0.15 around the paramagnetic(PM)-ferromagnetic(FM) phase transition were investigated through various techniques. These involved modified Arrott plots, Kouvel-Fisher method and Widom scaling relation. Magnetic data, analyzed in the critical region, using the above methods, yielded the critical exponents for(x=0.10) La0.57Y0.10Ba0.23Ca0.1Mn O3(β=0.312±0.002 and γ=1.147±0.003 at T C=299.23±0.05 K). Moreover, the estimated critical exponents of(x=0.15) La0.52Y0.15Ba0.23Ca0.1Mn O3 were β=0.286±0.004 and γ=0.943±0.002 at T C=289.53±0.06 K. The critical exponents’ values were close to the theoretical values of 3D-Ising model and tricritical mean-field model. These results suggested that the present composition should be close to a tricritical point in the La0.67–x Y x Ba0.23Ca0.1Mn O3 phase diagram. Expressing the field dependence as ΔS M∝H n allowed us to establish a relationship between the exponent n and the critical exponents of the material and to propose a phenomenological universal curve for the field dependence of ΔS M. 相似文献
6.
7.
已经开发了一个有限元模型,研究表面粗糙和带槽纸质可渗透的湿式离合器的接合特性。采用有限元方法(Galerkin)离散修正雷诺和力平衡方程式,采用等参量方程式解所描述的有关内何学。通过Patir和Cheng(1978)的通用流量模型模拟表面粗糙度的影响。在表面粗糙状况下,采用Greenwond和William son(1966)方法计算负荷分配,采用开发的有限元模型研究所加负荷的影响,以及湿式离合器摩擦材料的渗透率和槽出入口尺寸的接合特性(即转矩、油压、接合时间和油膜厚度)。研究结果表明,所加负荷、摩擦材料渗透率和槽宽度对接合特性的影响显著。高的配合面压力增大了峰值和减少了接合时间但显著增大了峰值转矩,宽油槽减少峰值转矩和增加了接合时间。对于本模型油槽深度对接合特性的影响不太明显。 相似文献
8.
The present study is concerned with the computational fluid dynamics(CFD) simulation of turbulent dispersion of immiscible liquids, namely, water–silicone oil and water–benzene through Kenics static mixers using the Eulerian–Eulerian and Eulerian–Lagrangian approaches of the ANSYS Fluent 16.0 software. To study the droplet size distribution(DSD), the Eulerian formulation incorporating a population balance model(PBM) was employed. For the Eulerian–Lagrangian approach, a discrete phase model(DPM) in conjunction with the Eulerian approach for continuous phase simulation was used to predict the residence time distribution(RTD) of droplets.In both approaches, a shear stress transport(SST) k-ω turbulence model was used. For validation purposes, the simulated results were compared with the experimental data and theoretical values for the Fanning friction factor, Sauter mean diameter and the mean residence time. The reliability of the computational model was further assessed by comparing the results with the available empirical correlations for Fanning friction factor and Sauter mean diameter. In addition, the influence of important geometrical and operational parameters, including the number of mixing elements and Weber number, was studied. It was found that the proposed models are capable of predicting the performance of the Kenics static mixer reasonably well. 相似文献
9.
Xingchao WANG Chunjian PAN Carlos E. ROMERO Zongliang QIAO Arindam BANERJEE Carlos RUBIO-MAYA Lehua PAN 《Frontiers in Energy》2022,16(2):246
A comprehensive thermo-economic model combining a geothermal heat mining system and a direct supercritical CO2 turbine expansion electric power generation system was proposed in this paper. Assisted by this integrated model, thermo-economic and optimization analyses for the key design parameters of the whole system including the geothermal well pattern and operational conditions were performed to obtain a minimal levelized cost of electricity (LCOE). Specifically, in geothermal heat extraction simulation, an integrated wellbore-reservoir system model (T2Well/ECO2N) was used to generate a database for creating a fast, predictive, and compatible geothermal heat mining model by employing a response surface methodology. A parametric study was conducted to demonstrate the impact of turbine discharge pressure, injection and production well distance, CO2 injection flowrate, CO2 injection temperature, and monitored production well bottom pressure on LCOE, system thermal efficiency, and capital cost. It was found that for a 100 MWe power plant, a minimal LCOE of $0.177/kWh was achieved for a 20-year steady operation without considering CO2 sequestration credit. In addition, when CO2 sequestration credit is $1.00/t, an LCOE breakeven point compared to a conventional geothermal power plant is achieved and a breakpoint for generating electric power generation at no cost was achieved for a sequestration credit of $2.05/t. 相似文献
10.
生产费用的增加和矿石品位的下降,这是美国和全世界露天矿山的普遍趋势。所以,为了保持市场竞争能力,各公司必须不断改善他们对于人力和生产设备的利用情况。杜瓦尔(Duval)公司对于采矿费用一向是很敏感的,其部分原因是铜-钼矿体品位较低。为此,位于亚利桑那州塔克森(Tucson)以南、采剥总量为21.8万吨(240000 相似文献