氟硼酸钾对镁合金的除铁作用及组织结构的影响

通过热力学计算和实验,研究了氟硼酸钾(KBF4)对AZ91镁合金熔体除铁的可行性和除铁效果.结果表明:在740℃,加入镁合金量1.2%的KBF4进行精炼处理,并保温静置30 min,可使合金中铁含量从0.0237%降到0.0032%.5%NaCI溶液浸蚀实验表明,镁合金的腐蚀速率从除铁前的55.3 mg·cm-2·day-1降到除铁后的4.5 mg·cm-2·day-1.在利用KBF4对镁合金熔体除铁的同时,又能使合金晶粒得到显著细化.     

加工态与铸造态的AZ40镁合金阳圾氧化耐蚀性对比

利用正交试验确定了阳极氧化电解液配方,通过比较铸造态和加工态AZ40镁合金金相组织、阳极氧化膜表面形貌、极化曲线,解释加工状态对AZ40镁合金阳极氧化耐蚀性的影响.结果表明,加工态镁合金的腐蚀速率为87.732 02 mg/(m2.h),铸造态镁合金的腐蚀速率为106.37 mg/(m2·h).由于加工态镁合金的合金元素参与阳极氧化,使膜层结合更致密,表面几乎没有裂纹,对基体更具有保护性.     

净化处理对Mg-Gd-Y-Zr镁合金耐蚀性的影响(英文)

在真空和非真空条件下对Mg-Gd-Y-Zr镁合金进行过滤净化处理。利用OM和SEM方法分析合金中夹杂物的种类、形貌、尺寸分布和体积分数;利用盐雾实验和电化学测试研究Mg-Gd-Y-Zr镁合金中夹杂物对合金耐蚀性的影响。结果表明:过滤净化处理可以有效地去除合金中的夹杂物;通过净化处理,合金中的夹杂物平均尺寸从12.7μm减小到2.0μm,夹杂物的平均体积分数从0.30%降低到0.04%;随着合金中夹杂物尺寸的减小,盐雾腐蚀实验中合金的腐蚀速率从38.8g/(m2·d)减少到2.4g/(m2·d);在电化学实验中,腐蚀电流密度减小,极化电阻升高,Mg-Gd-Y-Zr镁合金的耐蚀性得到了提高。     

Mn含量对含铁AZ91镁合金铸态组织与性能的影响

本文采用金相显微镜(OM)、X射线衍射分析(XRD)、INSTRON5882万能材料试验机和失重法研究了Mn含量(WMn=0.1%、0.2%、0.5%和0.9%)对含铁AZ91镁合金的铸态显微组织、力学性能和腐蚀性能的影响.研究结果表明:在本试验条件下,合金的铸态组织主要由α一Mg+β-Mg17Al12+Al16Mn等相组成;适宜的Mn加入量可以细化合金组织,提高合金的力学性能;含Mn量为0.2%时可获得较好的力学性能,其抗拉强度和伸长率分别为149MPa和1.40%;Mn的加入还能显著提高含铁AZ91镁合金的耐蚀性能,当Mn含量由0.1%增加到0.9%时,合金的腐蚀速率由41.7mg/(cm2·d)降为0.7mg/(cm2·d).     

镁合金微弧氧化膜的SiO2溶胶封孔处理研究

以正硅酸乙酯为原料,乙醇为溶剂,盐酸为催化剂制备了SiO2溶胶封孔剂.该封孔剂的傅立叶红外光谱(FTIR)中含有Si-O-Si键的伸缩振动吸收峰,证明了SiO2微粒存在,而且干凝胶的Si-O-Si键的伸缩振动吸收峰强度不随热处理温度的变化而变化,表明封孔剂有良好的高温稳定性.SiO2溶胶封孔剂可浸入镁合金微弧氧化膜的微孔,形成有效封孔.封孔处理可使镁合金微弧氧化试样的腐蚀速率由106 mg/(m2·h)降至32 mg/(m2·h),而且封孔处理还可显著提高镁合金微弧氧化试样在410 ℃下的抗氧化性能,对镁合金基体有很好的保护作用.     

MnCl2对镁合金废旧料组织性能的影响

利用等离子发射光谱仪、金相分析、电镜、万能电子材料试验机、腐蚀试验等方法研究了含有不同量的MnCl2熔剂对镁合金废旧料的力学性能、组织、断口形貌以及腐蚀行为的影响。研究表明,MnCl2可以降低镁合金废旧料中的Fe含量,同时会增加镁合金的Mn量,使用含MnCl2的熔剂可将镁废旧料中的Fe含量降到0 0072%以下。采用含MnCl2的熔剂可以提高试样的σb和δ。当合金中的Mn量超过一定程度后,对镁合金的力学性能会产生不利的影响。金相观察表明,净化处理对断口形貌无明显的影响,不改变AZ91镁合金的断裂机理,断口均成准解理断裂。腐蚀试验表明,采用含30%MnCl2的熔剂可以使试样的腐蚀速率从20 9mg/(cm2·d)降到6 4mg/(cm2·d)。     

Na2B4O7对镁合金旧料组织和性能的影响

利用等离子发射光谱仪、电镜、X衍射、万能材料试验机、腐蚀试验等手段研究了不同Na2B4O7含量的熔剂对镁合金废旧料的力学性能、相组成、断口形貌以及腐蚀行为的影响.研究表明,使用含Na2B4O7的熔剂可以使镁合金旧料中Fe的质量分数降低到0.004%以下,同时提高材料的抗拉强度和伸长率.腐蚀试验表明含Na2B4O7的质量分数为20%的熔剂可以使材料的腐蚀速率从15.1 mg*cm-2*d-1降低到0.4 mg*cm-2*d-1.电镜观察和X衍射表明,净化处理对断口形貌和相组成没有明显影响.最后分析了Na2B4O7除铁的机理,认为Fe与B形成某种化合物沉淀下来是主要原因.     

添加稀土Er于熔剂中对铸态AZ91镁合金组织与性能的影响

研究了熔炼时在熔剂(42%MnCl2 53%LiCl 5?F2,质量分数,%)中添加稀土Er对铸态AZ91镁合金显微组织、力学性能、断口形貌以及腐蚀行为的影响。结果表明:在熔剂中添加稀土Er能够去除镁合金熔炼过程中产生的熔剂夹杂,净化镁合金熔体,提高铸态AZ91镁合金的拉伸性能和耐腐蚀性能;当熔剂中添加10%的稀土Er时,镁合金的抗拉强度σb和伸长率δ分别从156MPa和1.8%上升到最大值220MPa和4.1%;同时,镁合金在5%NaCl水溶液中的腐蚀速率从1.20mg/(cm2.d)下降到最小值0.15mg/(cm2.d);然而,随着稀土Er在熔剂中添加量的进一步提高,合金中开始有φ-(Al7ErMn5)和τ-(Al66.7Mg23.3Er10)等含有稀土Er的相生成,消耗了合金中的Al和Mn元素,改变了β-(Mg17Al12)相的形态;而且沿枝晶界附近分布的粗大φ-(Al7ErMn5)相降低了枝晶之间的结合力,使得合金的σb和δ下降;同时,部分网状的β-(Mg17Al12)相断裂,呈离散的块状,导致合金的腐蚀速率增加;熔剂中添加稀土Er不改变镁合金的断裂机理,断裂机制仍为准解理断裂。     

稀土元素La对Mg-6Al-5Pb镁合金组织和腐蚀电化学行为的影响

利用扫描电镜(SEM)、X射线衍射(XRD)等检测分析稀土元素La对Mg-6%Al-5%Pb(AP65)镁合金(质量分数)显微组织的影响,并采用恒电流法、动电位极化扫描法和析氢法研究La含量对AP65镁合金的腐蚀电化学性能的影响。结果表明:加入La能够使AP65镁合金α-Mg组织得到细化,生成针状稀土相Mg80(Al,La)17和块状稀土相Mg17(Al,La)12;添加La提高了AP65镁合金的电化学活性、耐腐蚀性能和阳极效率,使AP65的平均电位负移;当La含量为2%(质量分数)时,平均电位最负为-1.73 V(vs SCE)。添加6%La使AP65镁合金的平均析氢速率从1.75 m L/(cm2·h)下降到0.02 m L/(cm2·h),并且使阳极效率从74.30%上升到82.31%。     

镁合金表面微弧氧化/自组装复合膜的耐蚀性能

目的 提高镁合金基体的耐蚀性能.方法 采用微弧氧化工艺对镁合金进行预处理,再通过自组装技术处理,在镁合金表面制备微弧氧化/十六烷基三甲氧基硅烷自组装复合膜层.通过SEM、EDS对复合膜的微观组织结构进行分析,并通过XPS、拉曼光谱分析了复合膜的表面成分,利用电化学阻抗谱、极化曲线、盐雾实验和浸泡实验检测了复合膜层的耐腐蚀性能.结果 复合膜均匀覆盖在镁合金表面,且复合膜较为光滑,主要含有C、O、F、Si等元素.经过自组装处理后,膜层从亲水性转为疏水性,接触角达到145.07°.经电化学性能测试,复合膜的Rct值能达到2.242×106?·cm2,与微弧氧化膜相比,增大了2个数量级;此外,复合膜的腐蚀电流密度为1.314×10-8 A/cm2,与微弧氧化膜相比也降低了2个数量级,具有较好的耐腐蚀性.浸泡120 h后,复合膜的腐蚀电流密度仍有1.061×10-5 A/cm2,盐雾实验进行120 h也没有出现明显的腐蚀现象.结论 自组装技术明显提高了镁合金基体的耐蚀性能,微弧氧化膜在一定程度上增强了自组装膜层对基材的粘附力.由于复合膜的疏水性使得水滴在膜层表面停留的时间减少,所以膜层的耐蚀性会随着疏水性增大而大大提高.     

新型的治疗阿尔茨海默氏症药物(1-二甲基磷酰基-2,2,2-三氯)-乙基-1-醇烟酸醋对体外神经细胞的作用

目的: 观察本实验室合成的一种治疗阿尔茨海默氏症(AD)的药物(1-二甲基磷酰基-2, 2, 2 -三氯)-乙基^-1-醇烟酸醋(NMF),对体外培养的皮层神经细胞活性的影响以及对海人藻酸(KA)所致的神经损伤的保护作用。方法: 采用体外培养皮层神经元的方法,解剖分离 15 d胚胎小鼠皮层神经细胞, 接种于 96孔板,48 h 后加药并培养 72 h,以 MIT 法 观察 NMF 对小鼠皮层神经细胞活性的影响;同时将接种于 24 孔板的细胞预先给予 NMF,d 3 时加或不加KA处理后,以台盼蓝染色鉴别并计数死、活细胞,可得出细胞的存活率。结果: NMF 明显促进胎鼠皮层神经元活性,其中 NMF1、0. 1、10nmol·L^-1促进神经元活性增殖率分别高达 34.7%、37.4%、36. 7%, NMF 明显促进正常胎鼠皮层神经元存活卒,与对照组比较,10nmol·L^-1 NMF 对皮层神经元的存活率分别提高 39.3%、73.5%。 NMF能显著 对抗 KA 所致的神经元损伤,与 KA 损伤组相比, NMF0.1、10、10nmol·L^-1对损伤皮层神经元的保护率分别为 77.30%、80.10%、84.15%。结论: NMF 明 显促进胎鼠皮层神经元的洁性、提高正常皮层神经元,的存活卒,并能有效地保护KA所致的神经元损伤,提示 NMF 是一种很有潜力的治疗 AD 的药物。     

Three-Dimensional Growth of Coherent Ferrite in Austenite: A Molecular Dynamics Study

Coherent second phase often exhibits anisotropic morphology with specifi c orientations with respect to both the second and the matrix phases. As a key feature of microstructure, the morphology of the coherent particles is essential for understanding the second-phase strengthening eff ect in various industrial alloys. This letter reports anisotropic growth of coherent ferrite from austenite matrix in pure iron based on molecular dynamics simulation. We found that the ferrite grain tends to grow into an elongated plate-like shape, independent of its initial confi guration. The fi nal shape of the ferrite is closely related to the misfi t between the two phases, with the longest direction and the broad facet of the plate being, respectively, consistent with the best matching direction and the best matching plane calculated via the Burgers vector content(BVC) method. The strain energy calculation in the framework of Eshelby's inclusion theory verifi es that the simulated orientation of the coherent ferrite is energetically favorable. It is anticipated that the BVC method will be applicable in analysis of anisotropic growth and morphology of coherent second phase in other phase transformation systems.     

Effect of Short-Time Aging on the Pitting Corrosion Behavior of a Novel Lean Duplex Stainless Steel 2002

The effect of short-time aging in the temperature range between 400 and 1000 °C on the pitting corrosion behavior and mechanical property of a novel lean duplex stainless steel(LDSS) 2002 was investigated through the potentiostatic critical pitting temperature(CPT) tests and the Charpy impact tests. Both the pitting corrosion resistance and the toughness of aged specimens degraded due to the precipitation of detrimental secondary phases and the most significant reduction of CPT and impact energy emerged at 650 °C concurrently. The CPT of LDSS 2002 specimen aged at 650 °C decreased by 28 °C, and the impact energy dropped from 69 to 29 J/cm~2 compared with the solution-annealed sample. Transmission electron microscopy characterization showed that the main precipitates in LDSS 2002 were Cr_2N and M_(23)C_6 along the ferrite–austenite grain boundaries.     

INTRODUCTION TO PATENTS

The invention provides a method of making a mold which can reduce SOx generation rate while preventing decrease in hardening rate in the case of using sulfuric acid for a hardener composition. The method has a mixture step in which fire-resistant particles, a hardener composition and a binder composition are mixed to obtain a composition for a mold. The hardener composition contains sulfuric acid. In the mixture step, sodium carbonate is added. A molar ratio of the sulfuric acid to the sodium carbonate is 0.5 or more and 4.0 or less.     

China Foundry Week 2014

China Foundry Week, hosted by the Foundry Institution of Chinese Mechanical Engineering Society （FICMES） each year, is a large academic event in China. It is one of the ten high-impact activities sponsored by the Chinese Mechanical Engineering Society.     

17th Conference of Hydrodynamic and Electromechanical Control Engineering Call for papers

正1.Contents In order to promote the academic exchanges and technical communication of the research in the field of fluid power transmission and control,fluid control engineering specialized committee of the Chinese Society of Theoretical and Applied Mechanics will hold the 17th Conference of Hydrodynamic and Electromechanical Control Engineering on July 27-29,2014 in Tibet,Lhasa city.     

Information for Contributors

正The Transactions of Nonferrous Metals Society of China,founded in 1991 and sponsored by The Nonferrous Metals Society of China,is published monthly now and mainly contains reports of original research which reflect the new progresses in the field of nonferrous metals science and technology,including mineral processing,extraction metallurgy,metallic materials and heat treatments,metal working,physical metallurgy,powder metallurgy,with the emphasis     

Preface

<正>We are pleased to present this Special Issue of Transactions of Nonferrous Metals Society of China containing selected papers from the First Asian Conference on Aluminum Alloys(ACAA-2013),held in Beijing,China,13–17 October 2013.This conference has been initiated,with approval of     

Information for Contributors

The Transactions of Nonferrous Metals Society of China, founded in 1991 and sponsored by The Nonferrous Metals Society of China, is published monthly now and mainly contains reports of original research which reflect the new progresses in the field of nonferrous metals science and technology, including mineral processing, extraction metallurgy, metallic materials and heat treatments, metal working, physical metallurgy, powder metallurgy, with the emphasis on fundamental science. It is the unique preeminent publication in English for scientists, engineers, under/post-graduates on the field of nonferrous metals industry. This journal is covered by many famous abstract/index systems and databases such as SCI Expanded, Ei Compendex Plus, 1NSPEC, CA, METADEX, AJ and JICST.     

Formulas of Tension of Continuous Rolling Process

The development of computer controlled continuous rolling process calls for a mathematical expression that can express the inequality condition of "constant flow". Tension is the link of the continuous rolling process. From the condition of dynamic equilibrium, a differential equation of tension is given out. On the basis of the physical rules established from the industrial practice and experimental studies, the law of volume constancy, the linear relation of forward slip and tension, the state equation of continuous rolling, the formula of dynamic tension, and the formula of static tension have been obtained. These formulae reflect the functional relations between tensions, thickness, roll velocity, and time in the continuous rolling process. It is implied that the continuous rolling process is a gradually steady, controllable, and measurable dynamic system. An assumption of predicting the thickness of a steel plate using these tension formulae is also put forward.