Gd含量对06Cr19Ni10不锈钢热中子屏蔽性能及微观组织的影响

针对核电站对中子屏蔽材料结构功能一体化的需求，开展了Gd含量对06Cr19Ni10不锈钢热中子屏蔽性能及微观组织的影响研究，通过热中子屏蔽计算仿真分析，并以此为指导开展了不同Gd含量的Gd-06Cr19Ni10熔炼和轧制试验，采用OM、SEM等方法对不锈钢试样进行分析检测，结果表明：Gd的添加可以细化06Cr19Ni10不锈钢晶粒，但易形成脆性的Ni-Gd第二相，随着Gd含量的提高，Ni-Gd第二相面积百分数也明显增加，使得06Cr19Ni10不锈钢塑性下降，轧制性能明显降低。结合热中子屏蔽计算分析和轧制试验结果，认为Gd含量为1.7wt.%左右时Gd-06Cr19Ni10可以获得较为均衡的热中子屏蔽性能和材料轧制性能。     

耐高温射线屏蔽材料的制备及性能

核能应用技术的发展对射线屏蔽材料提出了耐高温、抗辐照等要求.氢化锆因其高的氢含量和在高温、射线辐照下的结构稳定性被认为是优良的快中子屏蔽材料,但难以制成大尺寸块体.研究了氢化锆与金属基体材料的反应,采用粉末冶金法获得了对快中子、热中子和γ射线均具有显著屏蔽效果的致密块体屏蔽材料.该材料在600℃仍不会明显脱氢,是一种综...     

电磁屏蔽材料及其测试技术研究

随着电磁污染及电磁波泄漏的日益严重,以电磁干扰（EMI）屏蔽材料为代表的电磁防护材料已经广泛应用在军用、民用电子设备中。目前,利用本征电磁性能制备的金属型EMI屏蔽材料,将高导电层与绝缘基体相结合的涂覆型EMI屏蔽材料,以及具有优良柔性的EMI屏蔽织物已经能够大批量生产。具有柔性、透明、可变形的新型EMI屏蔽材料日益增多,满足市场对材料多功能性、极端环境适用性、加工装配便捷性的新需求。EMI屏蔽测试技术在现有近场、远场测试技术基础上也呈现多元化、精细化的发展趋势。     

钛基RuO2-Ta2O5涂层电极材料的电容性能分析

采用热分解方法在钛基体上制备了(36%)RuO2-(64%)Ta2O5混合氧化物涂层。采用X射线衍射(XRD)、扫描电镜(SEM)、循环伏安(CV)以及恒流充放电测试研究了涂层电极的组织结构、表面形貌以及电容性能。结果表明:(36%)RuO2-(64%)Ta2O5涂层以非晶氧化物为基体,带有少量纳米微晶RuO2的组织结构。在酸性溶液中,在50～900 mV/s的扫描速度下,Ti/(36%)RuO2-(64%)Ta2O5涂层电极的伏安曲线都具有近似矩形形状,表现出良好的电容特性和功率特性。以5 mA/cm2和10 mA/cm2放电,比电容分别为525.5 F/g和495.1 F/g。在经历2000次循环充放电后,电极的电荷储存能力仍未衰减,显示其优异的循环稳定性。     

SmGdCe_2O_7陶瓷材料的热膨胀系数及热导率

以Sm2O3、Gd2O3和Ce O2为原材料,采用固相反应法制备了Sm Gd Ce2O7陶瓷材料,用X射线衍射分析了其相结构,采用扫描电镜(SEM)和电子能谱(EDS)分析其显微组织和元素组成,用推杆膨胀法和激光脉冲法测试了其热膨胀系数和热导率。结果表明,所制备的Sm Gd Ce2O7具有典型的萤石结构,其微观组织致密,晶界清晰。Gd3+离子较小的离子半径使其热膨胀系数低于Sm2Ce2O7,基质原子与取代原子之间质量及尺寸之间的差别,使其具有比Sm2Ce2O7更低的热导率,该材料有潜力用作新型热障涂层表面的陶瓷层材料。     

(Gd0.8Ca0.2)2Ce2O6.6陶瓷的制备及热导率

以Gd2O3、CeO2和CaO为原料,采用固相反应法制备(Gd0.8Ca0.2)2Ce2O6.6陶瓷材料。用X射线衍射(XRD)技术和扫描电镜(SEM)研究样品的相组成和微观组织,用激光脉冲法测试样品的热扩散系数。结果表明,所制备的样品具有单一的萤石结构,组织致密且晶界清晰,其在800℃的热导率仅为YSZ陶瓷的89%,较低热导率表明该材料有潜力用作新型热障涂层用陶瓷材料。     

掺杂离子对Gd2O2S:Eu3+磷光体结构和发光性能的影响

采用高温固相反应法制备出新型红色长余辉发光材料Gd2O2S:Eu3+,Xn+(X为Mg、Si、Ti中的一种或两种),研究掺杂离子对Gd2O2S:Eu3+磷光体的晶体结构、形貌粒度和发光性能的影响。通过X射线粉末衍射(XRD)、扫描电镜(SEM)和分光光度计等对合成产物进行分析与表征。结果表明:掺杂离子没有改变Gd2O2S:Eu3+磷光体的晶体结构,颗粒的形貌为类球形,分散性良好。同时,掺杂离子显著地延长发光材料Gd2O2S:Eu3+的余辉时间,并显示纯正的红色发光。     

稀土元素Gd和Sm对AZ81镁合金组织及力学性能的影响

利用气体保护下感应熔炼方法制备了AZ81+(Gd+Sm)合金,采用光学金相(OM)、扫描电镜(SEM)、X射线衍射分析(XRD)、能谱分析(EDX)和拉伸性能测试等手段,对合金进行了显微组织、力学性能以及断口形貌分析。研究表明:Gd和Sm的添加使得合金晶粒得到细化,在稀土总含量为2%时细化效果最为明显,基体中形成了稀土-铝化合物Al2Sm和Al2Gd。随着Sm和Gd含量的增加,AZ81合金的室温和高温下的抗拉强度先升高后降低,稀土添加量在2%~3%时取得最好的强化效果,过量稀土恶化了组织,降低了性能。     

Gd2 O3 -Yb2 O3 -Y2 O3 -ZrO2 热障涂层材料的热物理性能

目的通过多元稀土氧化物掺杂改性YSZ,提高传统热障涂层的性能。方法使用化学共沉淀法制备不同掺杂量的Gd2O3-Yb2O3-Y2O3-Zr O2(GYYZO)材料,并分别使用冷等静压-烧结和等离子喷涂工艺制备块材和涂层。通过测试块材的热导率和热膨胀系数,分析评价材料的热物理性能。对高温退火处理后的涂层进行X射线衍射分析,评价不同成分涂层的高温相稳定性。结果氧化锆基材料的热导率和热膨胀系数随总掺杂量升高而降低。氧化锆中稀土氧化物总掺杂量为5.5%~9.84%(摩尔分数)时,在1000℃下的热导率为1.25~1.56 W/(m·K),相对8YSZ材料下降了22%~37.5%;在200~1300℃的热膨胀系数为(10~11.1)×10-6/K,与传统8YSZ材料相当。在1400℃长时间退火处理后,低掺杂量GYYZO涂层中的单斜相含量明显低于8YSZ涂层。结论多元稀土氧化物掺杂改性氧化锆材料具有良好的高温相稳定性、低热导率和适当的热膨胀系数,可以作为高性能热障涂层的备选材料。     

Gd1-xAlyOz:Eux梯度组合芯片的组织结构和发光性能

将组合材料芯片技术用于Gd1-xAlyOz:Eux荧光材料的研究。通过离子束溅射沉积和两步热处理技术制备Gd1-xAlyOz:Eux梯度组合材料芯片。通过X射线衍射和扫描电镜二次电子像分析发现：根据钆铝配比的不同在组合材料芯片上形成了相应的钆铝酸盐晶相;Gd4Al2O9(GAM)和GdAlO3(GAP)作为Gd2O3-Al2O3中的稳定晶体相,其单相多晶薄膜较容易形成。紫外激发发光照相记录表明Gd1-xAlyOz:Eux可以发射明亮的红色荧光 (Eu3+ 的5D0–7F2发射,主峰值615 nm）,且对于Eu3+掺杂,GAP是最好的钆铝酸盐基体相。材料芯片的照相筛选结果和发射光谱、吸收光谱的分析结果一致。     

新型的治疗阿尔茨海默氏症药物(1-二甲基磷酰基-2,2,2-三氯)-乙基-1-醇烟酸醋对体外神经细胞的作用

目的: 观察本实验室合成的一种治疗阿尔茨海默氏症(AD)的药物(1-二甲基磷酰基-2, 2, 2 -三氯)-乙基^-1-醇烟酸醋(NMF),对体外培养的皮层神经细胞活性的影响以及对海人藻酸(KA)所致的神经损伤的保护作用。方法: 采用体外培养皮层神经元的方法,解剖分离 15 d胚胎小鼠皮层神经细胞, 接种于 96孔板,48 h 后加药并培养 72 h,以 MIT 法 观察 NMF 对小鼠皮层神经细胞活性的影响;同时将接种于 24 孔板的细胞预先给予 NMF,d 3 时加或不加KA处理后,以台盼蓝染色鉴别并计数死、活细胞,可得出细胞的存活率。结果: NMF 明显促进胎鼠皮层神经元活性,其中 NMF1、0. 1、10nmol·L^-1促进神经元活性增殖率分别高达 34.7%、37.4%、36. 7%, NMF 明显促进正常胎鼠皮层神经元存活卒,与对照组比较,10nmol·L^-1 NMF 对皮层神经元的存活率分别提高 39.3%、73.5%。 NMF能显著 对抗 KA 所致的神经元损伤,与 KA 损伤组相比, NMF0.1、10、10nmol·L^-1对损伤皮层神经元的保护率分别为 77.30%、80.10%、84.15%。结论: NMF 明 显促进胎鼠皮层神经元的洁性、提高正常皮层神经元,的存活卒,并能有效地保护KA所致的神经元损伤,提示 NMF 是一种很有潜力的治疗 AD 的药物。     

Three-Dimensional Growth of Coherent Ferrite in Austenite: A Molecular Dynamics Study

Coherent second phase often exhibits anisotropic morphology with specifi c orientations with respect to both the second and the matrix phases. As a key feature of microstructure, the morphology of the coherent particles is essential for understanding the second-phase strengthening eff ect in various industrial alloys. This letter reports anisotropic growth of coherent ferrite from austenite matrix in pure iron based on molecular dynamics simulation. We found that the ferrite grain tends to grow into an elongated plate-like shape, independent of its initial confi guration. The fi nal shape of the ferrite is closely related to the misfi t between the two phases, with the longest direction and the broad facet of the plate being, respectively, consistent with the best matching direction and the best matching plane calculated via the Burgers vector content(BVC) method. The strain energy calculation in the framework of Eshelby's inclusion theory verifi es that the simulated orientation of the coherent ferrite is energetically favorable. It is anticipated that the BVC method will be applicable in analysis of anisotropic growth and morphology of coherent second phase in other phase transformation systems.     

Effect of Short-Time Aging on the Pitting Corrosion Behavior of a Novel Lean Duplex Stainless Steel 2002

The effect of short-time aging in the temperature range between 400 and 1000 °C on the pitting corrosion behavior and mechanical property of a novel lean duplex stainless steel(LDSS) 2002 was investigated through the potentiostatic critical pitting temperature(CPT) tests and the Charpy impact tests. Both the pitting corrosion resistance and the toughness of aged specimens degraded due to the precipitation of detrimental secondary phases and the most significant reduction of CPT and impact energy emerged at 650 °C concurrently. The CPT of LDSS 2002 specimen aged at 650 °C decreased by 28 °C, and the impact energy dropped from 69 to 29 J/cm~2 compared with the solution-annealed sample. Transmission electron microscopy characterization showed that the main precipitates in LDSS 2002 were Cr_2N and M_(23)C_6 along the ferrite–austenite grain boundaries.     

Information for Contributors

正The Transactions of Nonferrous Metals Society of China,founded in 1991 and sponsored by The Nonferrous Metals Society of China,is published monthly now and mainly contains reports of original research which reflect the new progresses in the field of nonferrous metals science and technology,including mineral processing,extraction metallurgy,metallic materials and heat treatments,metal working,physical metallurgy,powder metallurgy,with the emphasis     

Preface

<正>We are pleased to present this Special Issue of Transactions of Nonferrous Metals Society of China containing selected papers from the First Asian Conference on Aluminum Alloys(ACAA-2013),held in Beijing,China,13–17 October 2013.This conference has been initiated,with approval of     

Information for Contributors

The Transactions of Nonferrous Metals Society of China, founded in 1991 and sponsored by The Nonferrous Metals Society of China, is published monthly now and mainly contains reports of original research which reflect the new progresses in the field of nonferrous metals science and technology, including mineral processing, extraction metallurgy, metallic materials and heat treatments, metal working, physical metallurgy, powder metallurgy, with the emphasis on fundamental science. It is the unique preeminent publication in English for scientists, engineers, under/post-graduates on the field of nonferrous metals industry. This journal is covered by many famous abstract/index systems and databases such as SCI Expanded, Ei Compendex Plus, 1NSPEC, CA, METADEX, AJ and JICST.     

INTRODUCTION TO PATENTS

The invention provides a method of making a mold which can reduce SOx generation rate while preventing decrease in hardening rate in the case of using sulfuric acid for a hardener composition. The method has a mixture step in which fire-resistant particles, a hardener composition and a binder composition are mixed to obtain a composition for a mold. The hardener composition contains sulfuric acid. In the mixture step, sodium carbonate is added. A molar ratio of the sulfuric acid to the sodium carbonate is 0.5 or more and 4.0 or less.     

China Foundry Week 2014

China Foundry Week, hosted by the Foundry Institution of Chinese Mechanical Engineering Society （FICMES） each year, is a large academic event in China. It is one of the ten high-impact activities sponsored by the Chinese Mechanical Engineering Society.     

17th Conference of Hydrodynamic and Electromechanical Control Engineering Call for papers

正1.Contents In order to promote the academic exchanges and technical communication of the research in the field of fluid power transmission and control,fluid control engineering specialized committee of the Chinese Society of Theoretical and Applied Mechanics will hold the 17th Conference of Hydrodynamic and Electromechanical Control Engineering on July 27-29,2014 in Tibet,Lhasa city.     

Formulas of Tension of Continuous Rolling Process

The development of computer controlled continuous rolling process calls for a mathematical expression that can express the inequality condition of "constant flow". Tension is the link of the continuous rolling process. From the condition of dynamic equilibrium, a differential equation of tension is given out. On the basis of the physical rules established from the industrial practice and experimental studies, the law of volume constancy, the linear relation of forward slip and tension, the state equation of continuous rolling, the formula of dynamic tension, and the formula of static tension have been obtained. These formulae reflect the functional relations between tensions, thickness, roll velocity, and time in the continuous rolling process. It is implied that the continuous rolling process is a gradually steady, controllable, and measurable dynamic system. An assumption of predicting the thickness of a steel plate using these tension formulae is also put forward.