共查询到18条相似文献,搜索用时 781 毫秒
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研究以氟橡胶为基体树脂,炭黑、石墨和碳纤维为导电填料的导电复合高分子材料中,炭黑、石墨、碳纤维及三者之间的配比和混炼时间对复合材料导电性能和机械性能的影响,制备出体积电阻率小于1Ω·cm的氟橡胶复合导电材料。 相似文献
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高分子基导电复合材料非线性导电行为及其机理(Ⅱ)量子力学隧道效应理论 总被引:1,自引:0,他引:1
简述了高分子基导电复合材料非线性导电行为的概念,详细讨论了高分子基导电复合材料非线性导电行为的机理——量子力学隧道效应理论及其它理论。高分子基导电复合材料的非线性导电行为是几种效应的综合过程:当导电填料的体积分数较小时,导电粒子无法形成导电通道,此时只有量子力学隧道效应在起作用;当导电填料的体积分数较大时,复合材料的导电行为是导电通道和隧道效应共同作用的结果。 相似文献
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To prepare composites with anisotropic conductive networks, electrical conductive polymer composites (CPCs) consisting of polypropylene (PP) and carbon nanotubes (CNTs) filled polyethylene (PE) are fabricated through high speed thin-wall injection molding. Morphological study demonstrates that CNTs are localized in PE phase while the alternating multilayer structure with different polymer phases elongated as well as conductive network oriented parallel to flow direction is observed. To form such alternating layered structure, the dispersed phases are firstly deformed into discontinuous layers, and finally further deformed into wide and regular continuous alternating layers. In term of the mechanism behind this, the good viscosity match, low interfacial tension between different polymer components, short relaxation time and high shear rate are thought as important issues. The anisotropic conductive behavior of these CPCs, i.e. conductive in longitudinal (parallel to flow direction) and transverse (perpendicular to flow direction) direction but non-conductive in thickness direction, is contributed by the insulating PP layer which cuts off the conductive networks in the core layer. More importantly, much better electromagnetic interference (EMI) shielding ability is obtained for these CPCs with alternating multilayer conductive networks comparing with the same polymer blends with isotropic conductive networks, despite of the fact that much lower resistivity is obtained for the later. This indicates great potential of these anisotropic CPCs for electronic applications. Moreover, this study has shed some light on the potential use of such alternating multi-layered structure to prepare a range of multi-functional materials. 相似文献
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BACKGROUND: Conductive polymer composites (CPCs) can be obtained by filling polymer matrices with electrically conductive particles, and have a wide variety of potential applications. In the work reported, the biodegradable polymer poly(lactic acid) (PLA) as a partially miscible blend with poly(propylene carbonate) (PPC) was used as a polymer matrix. Carbon black (CB) was used as the conducting filler. RESULTS: Fourier transform infrared spectroscopy revealed interactions between matrix and CB filler; this interaction was stronger in PPC‐blend‐CB than in PLA‐blend‐CB composites. A rheology study showed that low‐viscosity PPC could improve the fluidity of the CPCs, but decrease that of CB. With increasing CB content, the enforcement effect, storage modulus and glass transition temperature increased, but the elongation at break decreased. CPCs exhibited the lowest electrical percolation thresholds of 1.39 vol.% CB when the content of PPC in PLA‐blend‐PPC was 40 wt%. The conductivity of CPCs containing 5.33 vol.% CB and 40 wt% PPC reached 1.57 S cm?1. Scanning electron microscopy revealed that CB exhibits a preference for dispersion in the low‐viscosity phase (PPC) of the multiphase matrix. CONCLUSION: In the presence of CB, partially miscible PLA‐blend‐PPC could form multi‐percolation CPCs. Moreover, the combination of PLA and PPC with CB broadens novel application of both renewable polymers and CPCs. Copyright © 2008 Society of Chemical Industry 相似文献
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The insulator-conductor transition of conductive polymer composites (CPCs) can be ascribed to the fabrication of conductive networks, and the morphology of conductive networks plays a significant role in the electrical conductivity. This study presents CPCs with inherent morphology tunability which can be controlled by kinetic methods (i.e., mixing procedures and sequences, and polymer melt viscosity). Polypropylene (PP)/styrene-butadiene-styrene block copolymer (SBS) (50/50, in volume)/10 phr (parts per hundred of the polymer matrix) conductive carbon black (CB) composites prepared by different compounding sequences (PP/CB composites mixed with SBS, SBS/CB composites mixed with PP, and PP/SBS blend mixed with CB) are named as PC10S, SC10P, and PSC10. With the difference between the phase morphologies, distribution, and dispersion of CB, the PP/SBS/CB composites realize seven orders of magnitude difference in resistivity. The volume resistivity (ρv) of PC10S SC10P and PSC10 are 1.57 × 101, 1.68 × 102, and 4.88 × 108 Ω m, respectively. 相似文献
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Li Lin Hua Deng Xiang Gao Shuangmei Zhang Emiliano Bilotti Ton Peijs Qiang Fu 《Polymer International》2013,62(1):134-140
Eutectic metal particles and carbon nanotubes are incorporated into a thermoplastic polyurethane matrix through a simple but efficient method, melt compounding, to tune the resistivity–strain behavior of conductive polymer composite (CPC) fibers. Such a combination of conductive fillers is rarely used for CPCs in the literature. To characterize the strain‐sensing properties of these fibers, both linear and dynamic strain loadings are carried out. It is noted that a higher metal content in the fibers results in higher strain sensitivity. These strain‐sensing results are discussed through a morphological study combined with a model based on the classic tunneling model of Simmons. It is suggested that a high tunneling barrier height is preferred in order to achieve higher strain sensitivity. Copyright © 2012 Society of Chemical Industry 相似文献
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Constructing the microcellular structure in the conductive polymer composites (CPCs) is a promising approach to improve the sensitivity and durability of the piezoresistive sensor. Selectively placing the conductive fillers, to form the segregated network between the polymer region, can effectively improve the electric performance of CPCs. However, few researches have focused on the influence of the polymer bead size on the segregated network and the large-scale production of spherical polymer beads with low cost is still difficult to realize. Herein, plenty of regular-shaped poly(butylene adipate-co-terephthalate) (PBAT) beads were manufactured through underwater pelletizing process, which was further coated with carbon nanotube (CNT) particles with the assistance of ball milling technology, and eventually the sensor was successfully fabricated through supercritical carbon dioxide (scCO2) bead foaming technology. The lightweight and flexible sensor exhibited the uniform cell structure with the mean cell size of 51.0 μm and cell density of 3.9 × 108 cells/cm3 when the pelletizing cutter speed was 2500 rpm and the foaming temperature was 117.5°C. And the conductivity of the sensor reached 6.5 S/m incorporated with 3 wt% CNT, which possessed high sensitivity, good stability and long-term durability, attributed to its excellent microcellular structure and segregated conductive network. 相似文献
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Yi‐Chuan Zhang Kun Dai Huan Pang Qiao‐Ji Luo Zhong‐Ming Li Wei‐Qin Zhang 《应用聚合物科学杂志》2012,124(3):1808-1814
An anisotropically conductive polymer composite (ACPC) based on conductive carbon black (CB) and binary polymer blend of polyethylene (PE) and polyethylene terephthalate (PET) was successfully fabricated under shear and elongational flow fields. The PET phase formed in situ the aligned conductive microfibrils whose surfaces were coated by CB particles. This ACPC material exhibited a strong electrical anisotropy within a broad temperature range. When the ACPC samples were subjected to isothermal treatment (IT), they showed anomalous variations of the positive temperature coefficient (PTC) and negative temperature coefficient (NTC) effects. The PTC intensity was attenuated gradually with the increase of the IT time, and the NTC intensity was nearly eliminated after IT of 8 or 16 h. Beyond 16 h, the resistivity in the NTC region rose anomalously with the temperature after the elimination of NTC effect, which was the result of much transformation from the potential pathways to the intrinsic pathways due to the disordering of oriented conductive microfibrils. When the amount of potential pathways was very small, the effect of the intrinsic pathway separation surmounts that of the potential pathways, leading to the anomalous resistivity increase in the NTC region. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012 相似文献