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采用马弗炉在600℃下将蒸干的MDEA溶液灼烧2h,用(1+99)硝酸溶液浸提、过滤,再用硫氰酸汞分光光度法测定滤液中的氯离子.经试验该方法干扰少,准确度高,回收率在91.0%~100.1%,样品测定精密度(RSD)为 5.7%. 相似文献
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建立了牙刷刷毛中16种邻苯二甲酸酯的气相色谱-质谱(GC-MS)检测方法.样品经超声提取后,采用外标法选择离子扫描模式(SIM)进行定量分析.16种邻苯二甲酸酯在0.1~20 mg/L范围内呈现良好的线性关系,相关系数均大于0.999.检出限为0.05 mg/kg,平均回收率为74.5%~109.1%,相对标准偏差(RSD,n=6)为2.3%~9.1%.该方法样品处理简单,分析时间短,定量准确,适用于牙刷刷毛中邻苯二甲酸酯的分析检测. 相似文献
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乌兰布和沙漠与黄河沉积物磷的形态分析 总被引:1,自引:0,他引:1
本文用改进的SEDEX方法,对乌兰布和沙样和黄河上游沉积物进行了磷的形态提取分析,研究了乌兰布和沙漠不同粒径沙洋的各形态磷的差异及其与黄河沉积物各形态磷的关系。分析结果表明乌兰布和沙样130~150μm粒径的Ca-P、De-P、Or-P都比小于63μm粒径含量小。乌兰布和沙样和黄河上游沉积物无机磷的含量远远比有机磷的要高,其顺序为Ca-P>De-P>Fe-P>Or-P>可交换态磷。原样和100~120目(130~150μm)样品的可交换磷以化学吸附为主,而250目以上(<63μm)的样品则以物理吸附为主。 相似文献
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建立了溶剂提取气相色谱/质谱法测定油墨中苯系物含量的方法.以甲醇提取样品苯系物,气相色谱质谱联用法测定,外标法定量,同时检测样品中8种苯系物含量.在优化的实验条件下,该方法的线性关系良好,线性范围(0.1~50)μg/mL加标回收率在92.69%~101.52%之间,相对标准偏差在3.16%~5.06%之间.该方法操作简单,准确度和精密度较高,是一种检测油墨产品中苯系物含量的有效方法. 相似文献
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乙烯酮(双乙烯酮)是十分重要的化工中间体,其下游产品较多。江苏某化工厂开发生产乙烯酮(双乙烯酮)下游产品三十多个,年生产规模三万多吨,是国内以乙烯酮(双乙烯酮)为中间体生产精细化学品的综合骨干企业。针对乙烯酮(双乙烯酮)下游产品废水特点,该厂结合企业实际,开展了产品优化,结构调整,清洁生产,资源循环利用,节水降耗等工作,从源头削减了污染物的生产。同时投资二千多万元新建预处理装置三套,6000m3/d废水生化处理装置一套,使全厂乙烯酮(双乙烯酮)下游产品的废水得到了有效的治理。 相似文献
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The miscibility of various amorphous polybutadienes with mixed microstructures of 1,4 addition units (cis, 1,4 and trans 1,4) and 1,2 addition units have been investigated. The studies here involved optical transparency, differential scanning calorimetry, and small angle light scattering. It was found that a 90 percent (cis) 1, 4 addition polybutadiene was immiscible with high (91 percent) 1,2 addition polybutadiene. Reduction of the 1,2 content to 71 percent induced an upper critical solution temperature (UCST) with the cis 1,4 polymer. Polybutadienes with 50 percent and 10 percent 1,2 contents were miscible above the crystalline melting temperature of the cis 1,4 polybutadiene. Immiscibility of the 91 percent 1,2 addition polymer was also found with a 10 percent 1,2 polybutadiene. The latter polymer also exhibits an UCST with the 71 percent 1,2 polymer. The results are used to interpret the characteristics of blends of polybutadienes of varying microstructure. 相似文献
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以F类粉煤灰为例,详细介绍了测定粉煤灰中烧失量的步骤、计算数学模型、影响测量不确定度的因素以及各项测量不确定度分量评定,人员、设备、材料、方法、环境都是影响测量不确定的因素。 相似文献
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The objective of the study was to explore the effect of the degree of deacetylation (DD) of the chitosan used on the degradation rate and rate constant during ultrasonic degradation. Chitin was extracted from red shrimp process waste. Four different DD chitosans were prepared from chitin by alkali deacetylation. Those chitosans were degraded by ultrasonic radiation to different molecular weights. Changes of the molecular weight were determined by light scattering, and data of molecular weight changes were used to calculate the degradation rate and rate constant. The results were as follows: The molecular weight of chitosans decreased with an increasing ultrasonication time. The curves of the molecular weight versus the ultrasonication time were broken at 1‐h treatment. The degradation rate and rate constant of sonolysis decreased with an increasing ultrasonication time. This may be because the chances of being attacked by the cavitation energy increased with an increasing molecular weight species and may be because smaller molecular weight species have shorter relaxation times and, thus, can alleviate the sonication stress easier. However, the degradation rate and rate constant of sonolysis increased with an increasing DD of the chitosan used. This may be because the flexibilitier molecules of higher DD chitosans are more susceptible to the shear force of elongation flow generated by the cavitation field or due to the bond energy difference of acetamido and β‐1,4‐glucoside linkage or hydrogen bonds. Breakage of the β‐1,4‐glucoside linkage will result in lower molecular weight and an increasing reaction rate and rate constant. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 3526–3531, 2003 相似文献
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我厂3号回转窑(Φ4m×60m)生产线在1996年年底由SP窑(产量912t/d)改为NSP窑(产量1320t/d),预分解系统为四级旋风预热器带离线式分解炉 相似文献
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