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1.
作者首次发现了Si3N4-MgO-CeO2系陶瓷在烧结过程中玻璃相自动析晶这一独特现象.对于Si3N4-MgO-CeO2系陶瓷在1450℃,MgO-CeO2就会与Si3N4颗粒表面的SiO2反应形成硅酸盐液相,冷却后则成为玻璃相保留在烧结体中;当烧结温度高于1550℃时,作者发现,CeO2仍留在玻璃相中,但MgO会自动析晶出来,其结果是大大减少了烧结体中严重影响其高温性能的玻璃相的含量,对于提高烧结氮化硅陶瓷的高温性能有重要作用  相似文献   

2.
综述了SiC颗粒弥散强化Si3N4基陶瓷材料的研究近况,根据Si3N4和SiC的不同烧结机理对Si3N4/SiCp复相陶瓷材料烧结机理以及SiCp的掺入对材料可烧结性的影响进行了理论上的探讨将SiCp粒子的尺寸对Si3N4/SiCp复相陶瓷材料显微结构和力学性能的影响与材料可烧结性之间的关系进行了分析通过比较热压Si3N4/SiCp复相陶瓷材料和Si3N4/纳米SiCp复相陶瓷材料中SiCp含量对材料显微结构和力学性能的影响,对SiCp弥散强化Si3N4基陶瓷材料的强化效果和强化机理进行了初步的分析  相似文献   

3.
超高压烧结Si3N4陶瓷断口形貌与韧性的研究   总被引:1,自引:1,他引:0  
研究不同制作条件下Si3N4陶瓷断口形貌与韧性的关系,当温度在1160~1340℃烧结时断口平面凹凸不平起伏很大,具有较好的韧性.当加入烧结助剂总量达质量百分数9%时,过多的烧结助剂会形成低熔点化合物存在于片层组织之间,降低了Si3N4陶瓷的强度与韧性.  相似文献   

4.
综述了SiC闰弥散强化Si3N4基陶瓷材料的研究近况,根据Si3N4和SiC的不同烧结机理对Si3N4/SiCp复相陶瓷材料烧结机理以及SiCp的掺入对材料可烧结性的影响进行了理论上的探讨。将SiCp粒子的尺寸对Si3N4/SiCp复相陶瓷材料显微结构和力学性能的影响与材料可烧结性之间的关系进行了分析,通过比较热压Si3N4/SiCp复相陶瓷材料和Si3N4/纳米SiCp复相陶瓷材料中SiCp一地  相似文献   

5.
ZrO2对Si3N4陶瓷烧结性能的影响   总被引:2,自引:0,他引:2  
对添加ZrO伯Si3N4陶瓷烧结性能的研究表明,一方面ZrO2可作为一种烧结助剂,促进液相烧结;另一方面它也以四方相形式弥散分布于Si3N4晶粒间,以提高材料的强韧性,试验结果表明:常压烧结下,ZrO2的质量分数为0.18时,材料强韧性最好。  相似文献   

6.
自韧化氮化硅陶瓷研究   总被引:4,自引:0,他引:4  
对热压烧结自韧化Si3N4陶瓷的工艺参数诸如助烧剂量,烧结时间和温度等与材料显微组织,相组成及力学性能间的关系进行了研究。在致密化前提下且烧剂量较少时,有利于材料显微组织的均匀化和力学性能的提高。  相似文献   

7.
Si3N4-MgO-CeO2陶瓷烧结过程中的致密化与相变   总被引:3,自引:0,他引:3  
氮化硅陶瓷有极大的应用潜力,但由于其强共价键,很难烧结致密化。采用了一种新的MgO-CeO2复合烧结助剂,利用X射线衍射、透射电镜等手段研究了MgO-CeO2复合烧结助剂对氮化硅陶瓷致密化和相变过程的影响,结果发现对Si3N4-MgO-CeO2陶瓷,在1450℃就会有大量液相出现,1500~1550℃为快速致密化阶段,而α-Si3N4→β-Si3N4相变主要发生在1550~1600℃,相变过程滞后于致密化过程。常压烧结Si3N4-MgO-CeO2陶瓷,强度达948MPa,因此,MgO-CeO2是一种非常有效的氮化硅的烧结助剂。  相似文献   

8.
测定了销-盘式热压Si3N4/3Cr2W8V钢摩擦副在室温干摩擦磨损条件下的的摩擦系数及Si3N4销的磨损系数.对陶瓷销的磨损面进行了SEM显微形貌观察、X射线分析;并探讨了陶瓷销的磨损机理.研究结果表明:Si3N4陶瓷的磨损以微区脆性断裂为主要机理.  相似文献   

9.
测定了销-盘式热压Si3N4/3Cr2W8V钢摩擦副在室温干摩擦磨损条件下的摩擦系数及Si3N4销的磨损系数,对陶瓷销的磨损面进行了SEM显微形貌观察,X射线分析;并探讨了陶瓷销的磨损机理。研究结果表明:Si3N4陶瓷的磨损以微区脆性断裂为主要机理。  相似文献   

10.
重点研究了Al2O3 /ZrSiO4 富铝体系反应烧结制备过程中的晶相变化,以及Al2O3/SiO2 比对反应烧结的影响,进而研究了添加Cr2O3 对反应烧结的影响.研究表明,在反应烧结过程中,莫来石的生成明显滞后于ZrSiO4 的分解;在相同温度下,ZrSiO4 的分解程度随Al2O3 的加入量的增加而提高.添加Cr2O3 使莫来石的稳定生成温度提高,此外,Cr2O3 的引入有助于Al2O3 向莫来石中的固溶  相似文献   

11.
There are numerous geometric objects stored in the spatial databases. An importance function in a spatial database is that users can browse the geometric objects as a map efficiently. Thus the spatial database should display the geometric objects users concern about swiftly onto the display window. This process includes two operations:retrieve data from database and then draw them onto screen. Accordingly, to improve the efficiency, we should try to reduce time of both retrieving object and displaying them. The former can be achieved with the aid of spatial index such as R-tree, the latter require to simplify the objects. Simplification means that objects are shown with sufficient but not with unnecessary detail which depend on the scale of browse. So the major problem is how to retrieve data at different detail level efficiently. This paper introduces the implementation of a multi-scale index in the spatial database SISP (Spatial Information Shared Platform) which is generalized from R-tree. The difference between the generalization and the R-tree lies on two facets: One is that every node and geometric object in the generalization is assigned with a importance value which denote the importance of them, and every vertex in the objects are assigned with a importance value,too. The importance value can be use to decide which data should be retrieve from disk in a query. The other difference is that geometric objects in the generalization are divided into one or more sub-blocks, and vertexes are total ordered by their importance value. With the help of the generalized R-tree, one can easily retrieve data at different detail levels.Some experiments are performed on real-life data to evaluate the performance of solutions that separately use normal spatial index and multi-scale spatial index. The results show that the solution using multi-scale index in SISP is satisfying.  相似文献   

12.
The discovery of the prolific Ordovician Red River reservoirs in 1995 in southeastern Saskatchewan was the catalyst for extensive exploration activity which resulted in the discovery of more than 15 new Red River pools. The best yields of Red River production to date have been from dolomite reservoirs. Understanding the processes of dolomitization is, therefore, crucial for the prediction of the connectivity, spatial distribution and heterogeneity of dolomite reservoirs.The Red River reservoirs in the Midale area consist of 3~4 thin dolomitized zones, with a total thickness of about 20 m, which occur at the top of the Yeoman Formation. Two types of replacement dolomite were recognized in the Red River reservoir: dolomitized burrow infills and dolomitized host matrix. The spatial distribution of dolomite suggests that burrowing organisms played an important role in facilitating the fluid flow in the backfilled sediments. This resulted in penecontemporaneous dolomitization of burrow infills by normal seawater. The dolomite in the host matrix is interpreted as having occurred at shallow burial by evaporitic seawater during precipitation of Lake Almar anhydrite that immediately overlies the Yeoman Formation. However, the low δ18O values of dolomited burrow infills (-5.9‰~ -7.8‰, PDB) and matrix dolomites (-6.6‰~ -8.1‰, avg. -7.4‰ PDB) compared to the estimated values for the late Ordovician marine dolomite could be attributed to modification and alteration of dolomite at higher temperatures during deeper burial, which could also be responsible for its 87Sr/86Sr ratios (0.7084~0.7088) that are higher than suggested for the late Ordovician seawaters (0.7078~0.7080). The trace amounts of saddle dolomite cement in the Red River carbonates are probably related to "cannibalization" of earlier replacement dolomite during the chemical compaction.  相似文献   

13.
AcomputergeneratorforrandomlylayeredstructuresYUJia shun1,2,HEZhen hua2(1.TheInstituteofGeologicalandNuclearSciences,NewZealand;2.StateKeyLaboratoryofOilandGasReservoirGeologyandExploitation,ChengduUniversityofTechnology,China)Abstract:Analgorithmisintrod…  相似文献   

14.
Instead of following Fock’s expansion,we solve the Schrodinger equation for some quantum mechanical manybody systems such as electrons in atoms and charged excitons in quantum wells in a similar way in hyperspherical coordinates by expanding the wave functions into orthonormal complete basis sets of the hyperspherical hannonics(HHs)of hyperangles and generalized Laguerre polynomials(GLPs)of the hyperradius.This leads the equation to  相似文献   

15.
Future mobile communication systems aim at providing very high data transmission rates, even in high-mobility scenarios such as high-speed wheel-track trains, maglev trains, highway vehicles, airplanes, guided missiles or spacecraft. A particularly important commercial application is the strong and increasing worldwide demand for high- speed broadband wireless communications (up to 574.8 km/ h test speeds or 380 km/h commercial speeds) in railways, providing data, voice and video services for applications such as onboard entertainment services to passengers, train control, train dispatch, train sensor status handling and sur- veillance. In such high-mobility scenarios, there are a number of communication challenges, including fast hand- over, location updating, high-speed channel modeling, estimation and equalization, anti-Doppler spreading tech- niques, fast power control, and dedicated network architec- ture. Because signal transmission in very high-speed scenarios will inevitably experience serious deterioration, it is imperative to develop key broadband mobile communi- cation techniques for such high-speed vehicles.  相似文献   

16.
17.
本文叙述了对海南岛及其毗邻大陆边缘白垩纪到第四纪地层岩石进行古地磁研究的全部工作过程。通过分析岩石中剩余磁矢量的磁偏角及磁倾角的变化,提出海南岛白垩纪以来经历的构造演化模式如下:早期伴随顺时针旋转而向南迁移,后期伴随逆时针转动并向北运移。联系该地区及邻区的地质、地球物理资料,对海南岛上述的构造地体运动提出以下认识:北部湾内早期有一拉张作用,主要是该作用使湾内地壳显著伸长减薄,形成北部湾盆地。从而导致了海南岛的早期构造运动,而海南岛后期的构造运动则主要是受南海海底扩张的影响。海南地体运动规律的阐明对于了解北部湾油气盆地的形成演化有重要的理论和实际意义。  相似文献   

18.
Being the primary media of geographical information and the elementary objects manipulated, almost all of maps adopt the layer-based model to represent geographic information in the existent GIS. However, it is difficult to extend the map represented in layer-based model. Furthermore, in Web-Based GIS, It is slow to transmit the spatial data for map viewing. In this paper, for solving the questions above, we have proposed a new method for representing the spatial data. That is scale-based model. In this model we represent maps in three levels: scale-view, block, and spatial object, and organize the maps in a set of map layers, named Scale-View, which associates some given scales.Lastly, a prototype Web-Based GIS using the proposed spatial data representation is described briefly.  相似文献   

19.
Various applications relevant to the exciton dynamics,such as the organic solar cell,the large-area organic light-emitting diodes and the thermoelectricity,are operating under temperature gradient.The potential abnormal behavior of the exicton dynamics driven by the temperature difference may affect the efficiency and performance of the corresponding devices.In the above situations,the exciton dynamics under temperature difference is mixed with  相似文献   

20.
The elongation method,originally proposed by Imamura was further developed for many years in our group.As a method towards O(N)with high efficiency and high accuracy for any dimensional systems.This treatment designed for one-dimensional(ID)polymers is now available for three-dimensional(3D)systems,but geometry optimization is now possible only for 1D-systems.As an approach toward post-Hartree-Fock,it was also extended to  相似文献   

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