高能高速等离子喷涂纳米Al_2O_3-13%TiO_2涂层的显微组织与性能

本文采用高能高速等离子喷涂方法制备了纳米Al2O3-13%TiO2(质量分数)涂层.通过X射线衍射法(XRD)分析了涂层物相成分,利用电子扫描显微镜(SEM)观察涂层截面组织形貌,并测量涂层显微硬度与结合强度.结果表明:该涂层具有独特的显微组织结构;涂层的维氏显微硬度达到了1134HV0.1;结合强度超过64MPa.     

转炉烟道电弧超音速喷涂涂层性能分析试验

针对转炉烟道的工况及失效形式,为提高烟道的使用寿命,设计了一种电弧超音速喷涂工艺制备的以镍铬合金为主的3层复合涂层,金相观察、显微硬度分析、高温氧化试验及抗热震性能测试表明,复合涂层与基体结合强度高,耐磨耐蚀性能优良。     

高能球磨制备NiCr-Cr_2O_3-BaF_2/CaF_2复合粉末及其爆炸喷涂层的性能

为了制备高性能复合涂层,以70%NiCr、20%Cr2O3及10%BaF2/CaF2为原料,采用高能球磨方法制备了复合粉体,并通过特定的爆炸喷涂工艺制得复合涂层。利用扫描电子显微镜(SEM)、能谱分析(EDS)、X射线衍射(XRD)等对球磨后粉体和喷涂层的微观形貌、组织结构、成分及物相组成进行了分析。根据HB5143-96测定了爆炸喷涂复合涂层与基体间的结合强度。结果表明:随球磨时间的延长,粉体球形化程度逐步加大,颗粒尺寸逐步减小,粒度分布趋于集中,颗粒成分及结构均匀性逐步提高;当球磨11h后,粉体中的BaF2和CaF2固溶于NiCr合金,Cr2O3颗粒在NiCr基体内部镶嵌;通过爆炸喷涂将球磨粉喷涂在不锈钢基体上,其涂层微观组织均匀致密,显微硬度Hv为578,涂层与基体结合强度为67MPa,综合性能优于混合粉喷涂层。     

超音速等离子喷涂法制备PbTiO3涂层的表征

利用超音速等离子喷涂在调质45钢表面制备PbTiO3涂层,运用扫描电镜(SEM)、X射线衍射(XRD)及能谱分析(EDS)等手段对所制备涂层的组织形貌和物相成分进行表征与分析;并利用显微硬度仪和纳米压痕仪对涂层的力学性能进行表征。结果表明:PbTiO3涂层表面为黄黑色,涂层光滑平整,孔隙率为1.5%;涂层为典型的层状结构,基体与PbTiO3涂层间的结合为机械结合,通过多个试样测量其结合强度的平均值为50.875MPa;纳米压痕仪测得涂层的表面硬度为7.858 GPa,弹性模量为139.308 GPa,显微硬度达到648.6HV0.1,涂层具有优良的力学性能;涂层主要成分为PbTiO3相。通过超音速等离子喷涂制备的涂层具有较好的综合性能,为后期在其表面沉积耐磨涂层打下了良好的基础。     

反应等离子熔覆原位合成TiN复合涂层微观组织及显微硬度研究

Ti N相具有高的硬度和强度,在涂层中被作为强化相来增强涂层的硬度,被广泛应用于提高涂层的耐磨性。采用反应等离子熔覆技术,以纯Ti粉末为原料,采用合适的等离子熔覆参数,在不锈钢基体表面原位合成制备了Ti N复合涂层。采用扫描电镜(SEM),能谱仪(EDS),X射线衍射(XRD)测试手段,分析了涂层内显微组织;利用显微硬度计测量了涂层的显微硬度,通过压痕计算了涂层的断裂韧性。结果表明:涂层微观组织为胞状树枝晶Ti N相弥散分布于Ti相与α-Fe相构成的共晶上。复合涂层具有较高的硬度,达到HV0.3996,涂层在不同加载下的压痕尺寸效应较明显,平均显微硬度从0.98 N时HV1021降到4.90 N时HV832,涂层显微硬度压痕在4.90 N加载时出现裂纹,复合涂层具有较好的韧性,4.90 N加载下平均断裂韧性为5.15 MPa·m。     

柔性耐磨复合涂层的研制

采用滚压工艺,将一定配比的金属粉末(WC-Co,NiCrBSi)与连接物混合制备成具有良好柔韧性的金属布,用作复合涂层原材料,通过真空钎焊方法制备WC-Co/NiCrBSi耐磨复合涂层,复合涂层内聚强度及涂层/基体结合强度分别达100～140 MPa和300～360 MPa,其水砂磨损性能高于WC-Co/NiCrBSi火焰堆焊层及CoCrW堆焊层磨损性能。     

大气等离子喷涂WC-12Co涂层的组织结构与性能研究

采用大气等离子喷涂(APS)方法在45钢基体上制备了WC-12Co涂层。用扫描电子显微镜(SEM)、X射线衍射仪(XRD)对涂层的微观形貌和成分进行了分析;采用显微硬度计和万能试验机分别测定了涂层的显微硬度和结合强度;并用SRV-Ⅳ摩擦磨损试验机测试了涂层的摩擦磨损性能。结果表明:WC-12Co涂层组织均匀致密,在喷涂过程中仅少量的WC发生了氧化分解,生成W_2C和Co_3W_3C相。涂层力学性能优异,结合强度平均值为50.63 MPa,涂层表面平均硬度为85.7 HR15N,截面平均显微硬度为1 053.8 HV0.3。相对于304不锈钢,等离子喷涂WC-12Co涂层具有十分优良的耐磨损性能,在室温(25℃)至300℃范围内,WC-12Co涂层的磨损机制为磨粒磨损。     

面向工程机械绿色再制造的超音速火焰喷涂碳化钨硬面涂层的性能

绿色再制造工程在上世纪八十年代国际上兴起,并成为发展最快的新型研究领域和新兴产业之一。本文利用超音速火焰喷涂技术制备WC-12Co涂层,探讨了该涂层在磨损失效的ZL50C型装载机驱动桥差速器的十字轴领域的应用可能性。通过光学显微镜、扫描电子显微镜、X射线、显微硬度计和拉伸测试对所制备的涂层进行了评定,以硬度为目标,所获的优化工艺参数为:丙烷压力为0.45MPa,流量为17L/min,氧气压力为0.65MPa,流量为167L/min,喷涂距离为275mm。通过优化工艺参数制备的WC-12Co涂层致密,孔隙率低于1%,涂层由WC、Co和部分分解的W2C等组成;涂层的显微硬度为1100HV0.1左右,结合强度超过63.7MPa。通过在十字轴的表面制备了厚度约500μm的WC-12Co涂层,恢复了轴的直径尺寸,并大大改善了十字轴的耐磨性,该类涂层适用于十字轴等耐磨工程机械零部件的再制造。     

HVOF制备纳米WC-10Co4Cr涂层的微观组织及抗冲蚀性能

为提高水轮机表面抗泥沙冲蚀性能,本实验采用超音速火焰喷涂技术(HVOF)在不锈钢(0Cr13Ni5Mo)基体上分别制备微米和纳米结构的WC-10Co4Cr涂层。通过扫描电子显微镜(SEM)分析不同结构WC-10Co4Cr粉末和涂层的微观组织结构,并对涂层的显微硬度、结合强度和抗冲蚀性能进行对比,探讨涂层泥沙冲蚀机理。结果表明:HVOF制备的纳米结构WC-10Co4Cr涂层组织致密,涂层的显微硬度、结合强度高于微米涂层,冲蚀质量损失远小于微米涂层;纳米结构可细化涂层晶粒,增强涂层的显微硬度和韧性,提高涂层的抗微切削和抗疲劳剥落性能,有利于涂层的抗泥沙冲蚀性能。     

粉末粒度对超音速火焰喷涂WC-10Co4Cr涂层性能的影响

采用超音速火焰喷涂工艺对两种不同粒度范围的WC-10Co4Cr粉末进行了涂层制备,分析了粉末粒度对喷涂涂层的微观组织、相结构、磨粒磨损及电化学腐蚀性能的影响。结果表明,粉末粒度较小时沉积的涂层结构致密、孔隙率低,具有较好的抗磨粒磨损性能和耐腐蚀性能。通过进一步粉末粒度的优选,获得了显微硬度大于1300HV0.3、孔隙率小于0.1%、结合强度90MPa、中性盐雾性能超过500h的WC-10Co4Cr耐磨防腐涂层。     

爆炸喷涂Cr_3C_2-35NiCr涂层的组织及性能研究

采用爆炸喷涂技术(D-gun)制备Cr3C2-35NiCr涂层。采用扫描电子显微镜(SEM)、电子探针(EPMA)、X射线衍射仪(XRD)对涂层微观结构、成分和相组成进行了分析,此外采用光学显微镜、显微硬度仪、拉伸试验机、摩擦磨损试验机等设备分别对涂层的孔隙率、硬度、断裂韧度、结合强度、磨损性能和热震性能进行了测试分析。试验结果表明:爆炸喷涂制备的Cr3C2-35NiCr涂层孔隙率为0.52%,显微硬度为HV803,断裂韧度为4.55MPa?m0.5,结合强度大于87.5MPa;涂层磨损性能和热震性能的测试结果表明,Cr3C2-35NiCr涂层室温摩擦系数为0.6,经受750℃下50次热震(水冷试验)无剥落。     

超音速火焰喷涂WC-12Co涂层抗磨粒磨损性能研究

采用超音速火焰(HVOF)喷涂工艺在316L不锈钢基体上制备了WC-12Co涂层,测试了涂层的结合强度、显微硬度、气孔率以及抗磨粒磨损性能。并利用XRD对喷涂粉末及涂层进行了相结构分析,用扫描电子显微镜对喷涂粉末、磨粒磨损前后的涂层表面形貌进行了观察。结果表明:在喷涂过程中,仅有很少量的WC粒子发生氧化脱碳。涂层的结合强度和显微硬度高,组织结构致密。在相同的实验条件下,316L的磨粒磨损量是WC-12Co涂层的95倍,这表明HVOF制备的WC-12Co涂层具有优异的抗磨粒磨损性能。     

Laser modification of detonation-gun sprayed ferro-boron coatings on AISI 304L SS

This study reports the synthesis of Ferro boron coatings deposited over AISI 304L austenitic stainless steel substrate using D-Gun (Detonation gun) technique. The microstructure, adhesion and wear properties of the coating were investigated using X-ray diffraction, optical microscopy, scanning electron microscopy, micro-hardness measurements and pin-on-disc wear tests. Hardness of the coated surface was found to increase from 350 HV to about 1600 HV on laser modification. The effect of laser treatment on the microstructural modification of coating is also described.     

Friction Stir Surfacing Route: Effective Strategy for the Enhancement of Wear Resistance of Titanium Alloy

Titanium alloys are widely used in aerospace applications due to their properties like high strength to weight ratio, good corrosion and creep resistance. Poor wear resistance of these alloys limits their use in tribological applications. Friction surfacing technique is now recognized as an effective solution to surface engineer the light weight high strength alloys to make them suitable for general engineering applications involving wear and corrosion. The present work pertains to a study on wear resistance of surface coating of boron carbide on Ti–6Al–4V alloy using friction surfacing technique. Coating was formed by placing the boron carbide powder into the holes of predetermined depth on the surface and was characterized by metallography, electron probe micro analysis and dry sliding wear testing. The present study revealed that titanium alloy could be friction surfaced with boron carbide powder. The coating exhibited excellent wear resistance, which is attributed to the formation of strong metallurgical bond with the substrate. In the present work an attempt has also been made to compare the wear behaviour of surface composite layer on titanium alloy with that of conventionally used engineering materials such as mild steel and austenitic stainless steel. Wear data clearly revealed that wear resistance of friction stir surfaced composite layer is better than that of mild steel and stainless steel. This study demonstrated that friction stir surfacing is an effective strategy for the enhancement of wear resistance of titanium alloys.     

用于瓦楞辊防护的WC-12Co涂层组织和性能研究

采用团聚烧结法制备了一种含有纳米粒子的新型瓦楞辊专用WC-12Co喷涂粉末,并使用超音速火焰喷涂工艺（HVOF）制备了该粉末的两种涂层。测试了涂层的结合强度、显微硬度、气孔率、开裂韧性和单道次沉积厚度。并利用XRD对喷涂粉末及涂层进行了相结构分析,用扫描电子显微镜和金相显微镜对喷涂粉末、涂层的组织结构进行了观察,并与进...     

Diffusion and Phase Transformation at the Interface between an Austenitic Substrate and a Thermally Sprayed Coating of Ledeburitic Cold‐Work Tool Steel

An overlay coating against wear or corrosion on components is required for various technical applications. Thermal spraying is a well‐established and near‐net‐shape deposition method. In this work, high‐velocity oxy‐fuel spraying of two different ledeburitic cold‐work tool steels was employed to produce wear‐resistant Fe‐base coatings on a stainless steel substrate. This work focuses on the investigation of diffusion processes across the coating/substrate interface. Specimens were heat‐treated for different dwell times and then analyzed by means of EBSD, XRD, OM, as well as SEM. Results of phase formation and diffusion profiles were compared with equilibrium and diffusion calculations obtained with ThermoCALC® and DICTRA®. The influence of diffusion processes across the coating/substrate interface on the mechanical properties, such as adhesive bond strength and hardness, was investigated by shear tests and microhardness profiles.     

制备工艺方法对 NiCrFeMo 涂层组织和性能影响研究

采用等离子喷涂、 超音速火焰喷涂和冷喷涂工艺制备了 NiCrFeMo 涂层, 并对涂层的金相性能、 不同基体 材料下涂层的结合性能、 不同温度下涂层的耐磨性能进行了检测。 实验结果表明： 采用冷喷涂工艺制备的涂层孔 隙率最低, 对应涂层的结合强度最高, 但冷喷涂工艺制备的涂层对基体材料较为敏感, 而超音速火焰喷涂和等离 子喷涂受基体材料影响不大。 在室温下, 冷喷涂涂层显示出较优的耐磨性能, 在高温下超音速火焰喷涂涂层显示 出较优的耐磨性能。     

Microstructure and Mechanical Properties of Electroslag Strip and Explosively Clad Low Alloy Steel: Stainless Steel Joints

The surface properties such as wear, corrosion, oxidation resistance etc., can be improved by using suitable cladding technique. The most commonly used cladding material is stainless steel for cladding on carbon and low alloy steel base materials. Mechanical properties are considered important for satisfactory performance of clad joints used in several defence applications. In this work, cladding of a high strength low alloy steel with stainless steel was carried out using explosive cladding and electroslag strip cladding processes. The relationship between mechanical properties and microstructure of clad materials was evaluated. The bond interface in explosively clad material shows a wavy interface compared to strip clad interface. Electron probe microanalysis revealed that inter-diffusion of elements was significant in strip clad joints and insignificant in explosively clad joints. Shear strength, notch tensile strength and impact toughness of explosive clad joints are much superior compared to those in strip clad joints.     

超音速火焰喷涂 Fe 基非晶耐磨涂层的组织与性能

采用超音速火焰喷涂 (HVOF) 在 304 不锈钢基体上制备了 FeSiBP 非晶涂层, 利用扫描电子显微镜、 X 射 线衍射仪、 维氏显微硬度计、 摩擦磨损试验机、 三维光学轮廓仪等设备对涂层的组织结构、 摩擦性能和磨损机制 进行了深入分析。 结果表明： 涂层大部分为非晶态, 非晶含量随着热量输入的增大呈先增加后减少的趋势。 当喷 涂参数为煤油流量 5.5 GPH, 氧气流量 2000 SCFH, 送粉器转速 4 RPM, 喷涂距离 360 mm 时, 涂层非晶含量可 达 83.8%, 硬度 857 HV0.2, 耐磨性是 304 不锈钢基体的 2.52 倍。     

反应等离子喷涂TiN复相涂层的组织与性能研究

采用工业纯钛粉,利用反应等离子喷涂技术,在45钢表面原位合成TiN复相涂层。利用X射线衍射仪分析了涂层的物相组成,采用扫描电镜观察涂层的组织结构、显微压痕、断口和磨损形貌,采用能谱仪分析压痕微区成分,测试了涂层的显微硬度和耐磨性能。结果表明:复相涂层由TiN、TiN0.3、Ti3O组成;涂层具有典型的层状组织结构,且层与层之间、层与基体之间结合较好;涂层的显微硬度为983~1 254 HV0.1;显微压痕形状清晰、规则,且压痕周围无翘边现象;断口形貌说明涂层具有一定的韧性,为介于陶瓷材料与韧性材料之间的混合断裂机制;涂层在低载荷时耐磨性能最佳。