Performance evaluation of a novel CCHP system integrated with MCFC,ISCC and LiBr refrigeration system

This paper proposes a novel combined cooling, heating, and power (CCHP) system integrated with molten carbonate fuel cell (MCFC), integrated solar gas-steam combined cycle (ISCC), and double-effect absorption lithium bromide refrigeration (DEALBR) system. According to the principle of energy cascade utilization, part of the high-temperature waste gas discharged by MCFC is led to the heat recovery steam generator (HRSG) for further waste heat utilization, and the other part of the high-temperature waste gas is led to the MCFC cathode to produce CO₃^2?, and solar energy is used to replace part of the heating load of a high-pressure economizer in HRSG. Aspen Plus software is used for modeling, and the effects of key factors on the system performances are analyzed and evaluated by using the exergy analysis method. The results show that the new CCHP system can produce 494.1 MW of electric power, 7557.09 kW of cooling load and 57,956.25 kW of heating load. Both the exergy efficiency and the energy efficiency of the new system are 61.69% and 61.64%, respectively. Comparing the research results of new system with similar systems, it is found that the new CCHP system has better ability to do work, lower CO₂ emission, and can meet the cooling load, heating load and electric power requirements of the user side at the same time.     

A new solar and geothermal based integrated ammonia fuel cell system for multigeneration

In this study, a new solar and geothermal based integrated system is developed for multigeneration of electricity, fresh water, hydrogen and cooling. The system also entails a solar integrated ammonia fuel cell subsystem. Furthermore, a reverse osmosis desalination system is used for fresh water production and a proton exchange membrane based hydrogen production system is employed. Moreover, an absorption cooling system is utilized for district cooling via available system waste heat. The system designed is assessed thermodynamically through approaches of energy and exergy analyses. The overall energy efficiency is determined to be 42.3%. Also, the overall exergy efficiency is assessed, and it is found to be 21.3%. The exergy destruction rates in system components are also analysed and the absorption cooling system generator as well as geothermal flash chamber are found to have comparatively higher exergy destruction rates of 2370.2 kW and 643.3 kW, respectively. In addition, the effects of varying system parameters on the system performance are studied through a parametric analyses of the overall system and associated subsystems.     

Energy,exergy and exergo-environmental impact assessment of a solid oxide fuel cell coupled with absorption chiller & cascaded closed loop ORC for multi-generation

A novel solid oxide fuel cell (SOFC) multigeneration system fueled by biogas derived from agricultural waste (maize silage) is designed and analyzed from the view point of energy and exergy analysis. The system is proposed in order to limit the greenhouse gas emissions as it uses a renewable energy source as a fuel. Electricity, domestic hot water, hydrogen and cooling load are produced simultaneously by the system. The system includes a solid oxide fuel cell; which is the primary mover, a biogas digester subsystem, a cascaded closed loop organic Rankine cycle, a single effect LiBr-water absorption refrigeration cycle, and a proton exchange membrane electrolyzer subsystem. The proposed cascaded closed-loop ORC cycle is considered as one of the advanced heat recovery technologies that significantly improve thermal efficiency of integrated systems. The thermal performance of the proposed system is observed to be higher in comparison to the simple ORC and the recuperated ORC cycles. The integration of a splitter to govern the flue gas separation ratio is also introduced in this study to cater for particular needs/demands. The separation ratio can be used to vary the cooling load or the additional power supplied by the ORC to the system. It is deduced that net electrical power, cooling load, heating capacity of the domestic hot water and total energy and exergy efficiency are 789.7 kW, 317.3 kW, 65.75 kW, 69.86% and 47.4% respectively under integral design conditions. Using a parametric approach, the effects of main parameters on the output of the device are analyzed. Current density is an important parameter for system performance. Increasing the current density leads to increased power produced by the system, decreased exergy efficiency in the system and increased energy efficiency. After-burner, air and fuel heat exchangers are observed to have the highest exergy destruction rates. Lower current density values are desirable for better exergy-based sustainability from the exergetic environmental impact assessment. Higher current density values have negative effect on the environment.     

Study on activated carbon/HFO-1234ze(E) based adsorption cooling cycle

In this study, the dynamic behavior of a 4-bed adsorption chiller was analyzed employing highly porous activated carbon of type Maxsorb III as the adsorbent and R1234ze(E), which global warming potential (GWP) is as low as 9, as the refrigerant. The simulated results in terms of heat transfer fluid temperatures, cycle average cooling capacity and coefficient of performance (COP) were obtained numerically. With 80 kg of Maxsorb III, the system is able to produce 2 kW of cooling power at driving heat source temperature of 85 °C which can be obtained from waste heat or solar energy. In particular, it can be powered by the waste heat from the internal combustion engine and therefore is suitable for automobile air-conditioning applications.     

Exergy analysis of an integrated solid oxide fuel cell and organic Rankine cycle for cooling, heating and power production

The study examines a novel system that combined a solid oxide fuel cell (SOFC) and an organic Rankine cycle (ORC) for cooling, heating and power production (trigeneration) through exergy analysis. The system consists of an SOFC, an ORC, a heat exchanger and a single-effect absorption chiller. The system is modeled to produce a net electricity of around 500 kW. The study reveals that there is 3-25% gain on exergy efficiency when trigeneration is used compared with the power cycle only. Also, the study shows that as the current density of the SOFC increases, the exergy efficiencies of power cycle, cooling cogeneration, heating cogeneration and trigeneration decreases. In addition, it was shown that the effect of changing the turbine inlet pressure and ORC pump inlet temperature are insignificant on the exergy efficiencies of the power cycle, cooling cogeneration, heating cogeneration and trigeneration. Also, the study reveals that the significant sources of exergy destruction are the ORC evaporator, air heat exchanger at the SOFC inlet and heating process heat exchanger.     

Energy,exergy, and environmental (3E) assessments of an integrated molten carbonate fuel cell (MCFC), Stirling engine and organic Rankine cycle (ORC) cogeneration system fed by a biomass-fueled gasifier

In this paper, a novel syngas-fed combined cogeneration plant, integrating a biomass gasifier, a molten carbonate fuel cell (MCFC), a heat recovery steam generator (HRSG) unit, a Stirling engine, and an organic Rankine cycle (ORC), is introduced and thermodynamically analyzed to recognize its potentials compared to the previous solo/combined systems. For the proposed system, energetic, exergetic as well as environmental evaluations are performed. Based on the results, the gasifier and the fuel cell have a significant contribution to the exergy destruction of the system. Through a parametric study, the current density and the stack temperature difference are known as the main effective factors on the plant performance. Meanwhile, dividing the whole system into three sub-models, i.e., model (1): power production plant including the gasifier and MCFC without including Stirling engine, HRSG, and ORC unit, model (2): the cogeneration system without ORC unit, and model (3): the whole cogeneration system, an environmental impact assessment is carried out regarding CO₂ emission. Considering paper as biomass revealed that maximum value of exergy efficiency is 50.18% with CO₂ emissions of 28.9 × 10⁻² t.MWh⁻¹ which compared to the solo MCFC system indicates 28.40% increase and 13.3 × 10⁻² t.MWh⁻¹ decrease in exergy efficiency and CO₂ emission, respectively.     

Fuel cell energy generation and recovery cycle analysis for residential application

Today’s concern regarding limited fossil fuel resources and their contribution to environmental pollution have changed the general trend to utilization of high efficiency power generation facilities like fuel cells. According to annual reducing capital cost of these utilities, their entrance to commercial level is completely expected. Hot exhaust gases of Solid Oxide Fuel Cells (SOFC) are potentially applicable in heat recovery systems. In the present research, a SOFC with the capacity of 215 kW has been combined with a recovery cycle for the sake of simultaneous of electric power, cooling load and domestic hot water demand of a hotel with 4600 m² area. This case study has been evaluated by energy and exergy analysis regarding exergy loss and second law efficiency in each component. The effect of fuel and air flow rate and also current density as controlling parameters of fuel cell performance have been studied and visual software for energy-exergy analysis and parametric study has been developed. At the end, an economic study of simultaneous energy generation and recovery cycle in comparison with common residential power and energy systems has been done. General results show that based on fuel lower heating value, the maximum efficiency of 83 percent for simultaneous energy generation and heat recovery cycle can be achieved. This efficiency is related to typical climate condition of July in the afternoon, while all the electrical energy, cooling load and 40 percent of hot water demand could be provided by this cycle. About 49 percent of input exergy can be efficiently recovered for energy requirements of building. Generator in absorption chiller and SOFC are the most destructive components of exergy in this system.     

Sizing analysis of a combined cooling,heating, and power system for a small office building using a wood waste biomass‐fired Stirling engine

When wood chips are available and used to fuel a combined cooling, heating, and power (CCHP) waste heat recovery system, they can represent an economically viable source of biomass energy that can meet a facility's electric and thermal demands. Using a Stirling engine as the CCHP prime mover provides several important advantages over conventional internal combustion engines including no additional processing of the waste wood chips, a potentially higher thermal efficiency, flexibility of fuel sources, and low maintenance. This study shows how the operational characteristics of a constant output, biomass‐fired, Stirling engine‐based CCHP system are affected by the performance of the individual components, including the prime mover, heat recovery system, auxiliary boiler, absorption chiller, and heating coil unit The results are assessed by examining the primary energy consumption and operational cost compared with a reference case. The analysis provides insight on the prime mover sizing and selection of each component to properly implement the system. In addition to examining the effects of each component, the effect of excess electricity production and buyback are considered. Copyright © 2010 John Wiley & Sons, Ltd.     

Energy and exergy performance assessment of a novel solar-based integrated system with hydrogen production

In this study, a new solar power assisted multigeneration system designed and thermodynamically analyzed. In this system, it is designed to perform heating, cooling, drying, hydrogen and power generation with a single energy input. The proposed study consists of seven sub-parts which are namely parabolic dish solar collector, Rankine cycle, organic Rankine cycle, PEM-electrolyzer, double effect absorption cooling, dryer and heat pump. The effects of varying reference temperature, solar irradiation, input and output pressure of high-pressure turbine and pinch point temperature heat recovery steam generator are investigated on the energetic and exergetic performance of integration system. Thermodynamic analysis result outputs show that the energy and exergy performance of overall study are computed as 48.19% and 43.57%, respectively. Moreover, the highest rate of irreversibility has the parabolic dish collector with 24,750 kW, while the lowest rate of irreversibility is calculated as 5745 kW in dryer. In addition, the main contribution of this study is that the solar-assisted multi-generation systems have good potential in terms of energy and exergy efficiency.     

Thermodynamic analysis and assessment of an integrated hydrogen fuel cell system for ships

In this thermodynamic investigation, an integrated energy system based on hydrogen fuel is developed and studied energetically and exergetically. The liquefied hydrogen fueled solid oxide fuel cell (SOFC) based system is then integrated with a steam producing cycle to supply electricity and potable water to ships. The first heat recovery system, after the fuel cells provide thrust for the ship, is by means of a turbine while the second heat recovery system drives the ship's refrigeration cycle. This study includes energy and exergy performance evaluations of SOFC, refrigeration cycle and ship thrust engine systems. Furthermore, the effectiveness of SOFCs and a hydrogen fueled engine in reducing greenhouse gas emissions are assessed parametrically through a case study. The main propulsion, power generation from the solid oxide fuel cells, absorption chiller, and steam bottoming cycle systems together have the overall energy and exergy efficiencies of 41.53% and 37.13%, respectively.     

Energy,exergy and thermoeconomic analysis of a combined cooling,heating and power (CCHP) system with gas turbine prime mover

In this paper energy, exergy and thermoeconomic analysis of a combined cooling, heating and power (CCHP) system has been performed. Applying the first and second laws of thermodynamics and economic analysis, simultaneously, has made a powerful tool for the analysis of energy systems such as CCHP systems. The system integrates air compressor, combustion chamber, gas turbine, dual pressure heat recovery steam generator (HRSG) and absorption chiller to produce cooling, heating and power. In fact, the first and second laws of thermodynamics are combined with thermoeconomic approaches. Next, computational analysis is performed to investigate the effects of below items on the fuel consumption, values of cooling, heating and net power output, the first and second laws efficiencies, exergy destruction in each of the components and total cost of the system. These items include the following: air compressor pressure ratio, turbine inlet temperature, pinch temperatures in dual pressure HRSG, pressure of steam that enters the generator of absorption chiller and process steam pressure. Decision makers may find the methodology explained in this paper very useful for comparison and selection of CCHP systems. Copyright © 2010 John Wiley & Sons, Ltd.     

A novel approach to improve the performance of solar-driven Stirling engine using solar-driven ejector cooling cycle

In this paper, a novel system to enhance the performance of a solar-driven finite speed alpha-type Stirling engine is proposed and evaluated. Part of the concentrated solar energy is used to drive an ejector refrigeration system. The cooling produced in the ejector cooling cycle is used to cool the Stirling engine to enhance its efficiency. Model equations to describe the systems are proposed and solved numerically. The results indicate that the new system produces averagely 3.3 times electrical power more than the conventional one. Moreover, the proposed system improves the Stirling engine efficiency by up to 46% in comparison with 19.15% for the conventional Stirling engine under solar radiation intensity of (1 kW/m²). Also, the results showed that the solar radiation intensity and wind speed are the most influential parameters that affect the proposed system efficiency. The new system is recommended to use in desert climates where high average daily solar radiation intensity, low wind speeds, and water shortage exist. Economic analysis is carried out to determine the feasibility of the proposed system under different economic parameters. It is found that, for instance, the simple payback period is 4.64 years for the new system when the selling price of electricity is 0.35 $/kWh.     

联产制冷的能效性能探讨

利用汽轮机抽汽作为吸收式制冷驱动热源的联产制冷，将供电、制冷有机结合在一起，不仅满足制冷要求也改善联产机组效率。通过引入抽汽yong增益概念，揭示了汽轮机抽汽特性规律，在此基础上从联产制冷目的yong效率角度比较了几种制冷方式，分析了汽轮机抽汽参数和相对内效率等因素对联产制冷能效性能影响规律，抽汽的yong增益比是联产制冷yong效率影响起决定作用的因素，所得结论对联产制冷吸收机的合理选用匹配提供有益的指导。     

Performance analysis and optimization of a trigeneration process consisting of a proton-conducting solid oxide fuel cell and a LiBr absorption chiller

In this work, the trigeneration system, consisting of a proton-conducting solid oxide fuel cell (SOFC–H⁺) and a single-stage LiBr absorption chiller, was proposed. The SOFC–H⁺ and single-stage LiBr absorption chiller models were developed through Aspen Plus V10. From the sensitivity analysis, the results show that increases in temperature and fuel utilization can improve the performance of the SOFC–H⁺. Conversely, the air to fuel (A/F) molar ratio and pressure negatively affect the electrical efficiency and overall system efficiency. In the case of the absorption chiller, the coefficient of performance was increased and made stable according to a constant value when the generator temperature was increased from 90 to 100 °C. When the optimization was performed, it was found that the SOFC–H⁺ should be operated at 700 °C and 10 bar with fuel utilization of 0.8 and A/F molar ratio of 2 to achieve a maximum overall efficiency of 93.34%. For the energy and exergy analysis, a combined heat and power SOFC–H⁺ was found to have the highest energy and exergy efficiencies, followed by the trigeneration process. This indicates that the integration of the SOFC–H⁺ and LiBr absorption chiller is possible to efficiently produce electricity, heating and cooling.     

Modelling of an adsorption system driven by engine waste heat for truck cabin A/C. Performance estimation for a standard driving cycle

This paper presents the main characteristics of an innovative cooling system for the air conditioning of a truck cabin, as well as a first estimation of its performance during a standard driving cycle, obtained with a specifically developed vehicle-engine-cooling system overall model. The innovative cooling system consists of a water–zeolite adsorption–desorption system, which employs the waste heat from the engine to produce the cooling of the vehicle cabin. The developed global model is completely dynamic and is able to: reproduce the operation of the engine through a standard driving cycle, evaluate the waste heat available at the engine hydraulic loop; calculate the sequential operation of an adsorption–desorption system, calculate the condensed water per cycle, the cooling effect produced at the evaporator, and finally, the temperature and humidity evolution of the air inside the cabin. The model was validated by experimental data. The experimental tests were performed in a lab-scale adsorption chiller prototype specifically designed and realized to be driven by the low grade waste heat (80–90 °C) from the engine coolant loop of a truck. The experimental activity carried out showed that the chiller is able to generate up to 5 kW of peak cooling power at 10 °C (35 °C of condensation temperature) with a COP of 0.6. The obtained results show that the system could be able to provide a significant amount of the required cooling.     

Parametric analysis of a solar energy based multigeneration plant with SOFC for hydrogen generation

Renewable energy-based hydrogen production plants can offer potential solutions to both ensuring sustainability in energy generation systems and designing environmentally friendly systems. In this combined work, a novel solar energy supported plant is proposed that can generate hydrogen, electricity, heating, cooling and hot water. With the suggested integrated plant, the potential of solar energy usage is increased for energy generation systems. The modeled integrated system generally consists of the solar power cycle, solid oxide fuel cell plant, gas turbine process, supercritical power plant, organic Rankine cycle, cooling cycle, hydrogen production and liquefaction plant, and hot water production sub-system. To conduct a comprehensive thermodynamic performance analysis of the suggested plant, the combined plant is modeled according to thermodynamic equilibrium equations. A performance assessment is also conducted to evaluate the impact of several plant indicators on performance characteristics of integrated system and its sub-parts. Hydrogen production rate in the suggested plant according to the performance analysis performed is realized as 0.0642 kg/s. While maximum exergy destruction rate is seen in the solar power plant with 8279 kW, the cooling plant has the lowest exergy destruction rate as 1098 kW. Also, the highest power generation is obtained from gas turbine cycle with 7053 kW. In addition, energetic and exergetic efficiencies of solar power based combined cycle are found as 56.48% and 54.06%, respectively.     

Solar absorption cooling plant in Seville

A solar/gas cooling plant at the Engineering School of Seville (Spain) was tested during the period 2008-2009. The system is composed of a double-effect LiBr + water absorption chiller of 174 kW nominal cooling capacity, powered by: (1) a pressurized hot water flow delivered by mean of a 352 m² solar field of a linear concentrating Fresnel collector and (2) a direct-fired natural gas burner. The objective of the project is to indentify design improvements for future plants and to serve as a guideline. We focused our attention on the solar collector size and dirtiness, climatology, piping heat losses, operation control and coupling between solar collector and chiller. The daily average Fresnel collector efficiency was 0.35 with a maximum of 0.4. The absorption chiller operated with a daily average coefficient of performance of 1.1-1.25, where the solar energy represented the 75% of generator’s total heat input, and the solar cooling ratio (quotient between useful cooling and insolation incident on the solar field) was 0.44.     

Exergy optimization of a novel hydrogen production plant with fuel cell,heat recovery,and MED using NSGAII genetic algorithm

In the current research, 4E analysis and multi-criteria optimization are applied to the poly generation unit for power, heating, refrigeration, and freshwater generation. This system consists of a solid oxide fuel cell (SOFC), multi-effect thermal vapor desalination (MED-TVC), an organic system with ejector refrigeration (OSER), a heat recovery steam generator (HRSG) and a domestic hot water generator. The mathematical simulation is applied to assess the performance of the plant at design conditions and the genetic algorithm finds the optimum operating point with two different scenarios. Parametric analysis and multi-objective optimization are carried out. Findings represent that the developed plant can provide 257.65 kW power, 12.13 kW, 7.44 kW cooling and heating load, and 0.04 kg/s freshwater with a total cost rate of 10.62 $/h. In this case, the plant energy and exergy efficiency is 73.9% and 71.35% respectively. The results of multi-objective optimization show that these values can be improved to 79% and 73.9% respectively. In addition, the plant cost can be reached to 10.07 $/h in this condition.     

Thermodynamic analysis and assessment of novel ORC- DEC integrated PEMFC system for liquid hydrogen fueled ship application

Proton-exchange membrane fuel cell (PEMFC) and liquid hydrogen are gaining attention as a power generation system and alternative fuel of ship. This study proposes a novel PEMFC system, integrated with the organic Rankine cycle–direct expansion cycle (ORC-DEC), which exploits cold exergy from liquid hydrogen and low temperature waste heat generated by the PEMFC for application in a liquid hydrogen fueled ship. A thermodynamic model of each subsystem was established and analyzed from the economic, energy, and exergy viewpoints. Moreover, parametric analysis was performed to identify the effects of certain key parameters, such as the working fluid in the ORC, pressure exerted by the fuel pump, cooling water temperature of the PEMFC, and the stack current density on the system performance. The results showed that the proposed system could generate 221 kW of additional power. The overall system achieved an exergy and energy efficiency of 43.52 and 40.45%, respectively. The PEMFC system had the largest exergy destruction, followed by the cryogenic heat exchanger. Propane showed the best performance among the several investigated ORC working fluids and the system performance improved with the increase in the cooling water temperature of the PEMFC. The economic analysis showed that the average payback time of ORC-DEC was 11.2 years and the average net present value (NPV) was $295,268 at liquid hydrogen costing $3 to $7, showing the potential viability of the system.     

Integration of a free-piston Stirling engine and a moving grate incinerator

The feasibility of recovering the waste heat from a small-scale incinerator (designed by Industrial Technology Research Institute) and generating electric power by a linear free-piston Stirling engine is investigated in this study. A heat-transfer model is used to simulate the integration system of the Stirling engine and the incinerator. In this model, the external irreversibility is modeled by the finite temperature difference and by the actual heat transfer area, while the internal irreversibility is considered by an internal heat leakage. At a fixed source temperature and a fixed sink temperature, the optimal engine performance can be obtained by the method of Lagrange multipliers.From the energy and mass balances for the interesting incinerator with the feeding rate at 16 t/d, there is enough otherwise wasted energy for powering the Stirling engine and generate more than 50 kW of electricity.