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建立了自动电位滴定仪测定铜产品中氯化物的方法。以Ag Titrode电极作指示电极,选择DET模式确定等当点,用硝酸调节pH3,在乙醇—水溶液中滴定测得结果。该方法适用于硫酸铜、氧化铜、硫化铜和碱式氯化铜等铜产品中氯化物的测定,方法检出限为0.005 mg,加标回收率为98%~101%。 相似文献
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取一定量的电泳漆槽液,用蒸馏水稀释后,加入醋酸铵缓冲溶液,使溶液pH=6.5~6.8。以铜离子选择电极为指示电极,饱和甘汞电极为参比电极,用铜试剂标准溶液进行电位滴定。用二级微商法计算滴定终点,而间接求出电泳漆槽液中Zn^2+的含量。以铅离子选择电极为指示电极,用硝酸铅标准溶液进行电位滴定,用类似的方法即可测定电泳漆槽液中PO^3-4的含量。 相似文献
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三聚氰酸纯度化学分析方法 总被引:4,自引:0,他引:4
在水及非水介质中 ,用指示剂及电极电位判断终点 ,以酸碱滴定方法测定三聚氰酸纯度。结果表明 :用电位滴定和非水滴定较准确 ,相对误差分别为 0 .2 %和 0 .7%。 相似文献
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采用电位滴定法,以Ag NO3为滴定剂,银电极为指示电极,双盐桥饱和甘汞电极为参比电极,在低温酸性甲醛/异丙醇溶液中,连续滴定氯化钠和双氰胺钠溶液,以二阶微商法确定滴定终点,测定了双氰胺钠及其杂质氯化钠的含量。其原理是利用双氰胺银和氯化银溶度积的差异,在连续滴定过程中会出现两个电位突跃,从而实现分别滴定。实验优化了溶剂的配比及用量,在10 m L甲醛(Na OH中和)+80 m L异丙醇+1 m L硝酸介质中,冰浴条件下测定时,分析结果误差最小。用企业提供的标样验证了方法的准确性,对未知样中双氰胺钠及杂质氯化钠含量的测定结果满意。 相似文献
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在精密银量滴定中终点的判别是困难的。原因是滴定形成的卤化银既是沉淀,又会感光变暗,妨碍用指示剂观察终点。虽然电位滴定是有效的解决途径,但过去基于指示电极的重现性及灵敏度存在问题,并未广泛应用。近年来,离子选择性电极的发展,揭示了作为指示电极的可能性,据知一些单位也作了电位滴定试验。唯未作关于电位滴 相似文献
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在精密银量滴定中终点的判别较难。原因是滴定形成的卤化银是沉淀且又会感光变暗,妨碍用指示剂观察终点。虽然电位滴定是有效的解决途径,但过去由于指示电极的重现性及灵敏度存在问题,故未广泛应用。近年来,离子选择性电极的发展,为选择指示电极提供了新的可能性。据了解一些单位也作了电位滴定试验,但未见有关电位滴定精密度实验的报导。本文介绍的用硫离子选择性电 相似文献
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The selective recovery of vanadium from an effluent of a manufacturing process for titanium white (oxide) has been made. The process retained is based on the partial neutralization of the effluent by means of calcium carbonate and on the separation of metal hydroxides from calcium sulfate and the solution. The hydroxides are thereafter calcined in the presence of a sodium salt, so that sodium vanadate may then be extracted by washing with water. Vanadium is finally precipitated by the addition of ammonium chloride or pH adjustment. The experimental results obtained in the laboratory study of the effluent neutralization, the calcination and leaching of the hydroxides and the vanadium precipitation are presented and discussed. The yields obtained in the various stages and their interdependance are also discussed. 相似文献
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Turaga P. Prasad Vemuri V. Ramasastry 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1977,27(2):409-414
The rate equation developed in our earlier studies has been analysed and discussed. It has been found that the rate of oxidation of ferrous hydroxide suspensions obtained by the addition of calcium hydroxide, sodium and calcium carbonates, ammonium and sodium hydroxides follows zero order kinetics. 相似文献
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Hwee Yoong Felicia Gok Jianhneg Shen Shahram Emami Martin J. T. Reaney 《Journal of the American Oil Chemists' Society》2013,90(2):291-298
A metal methoxide is more expensive than a metal hydroxide and dissolves in methanol releasing a methoxide ion without producing water. The methoxide ion has a higher reaction rate making it more preferred for industrial biodiesel production. This study describes the preparation of alkoxide catalysts from metal hydroxides and non-volatile, non-toxic polyols. Heating aqueous solutions of metal hydroxides and different polyols (1,2-propanediol, 1,3-propanediol, glycerol, xylitol and sorbitol) under vacuum yielded polyol-derived alkoxide base catalysts (PDABC). Comparison of the drying process for respective sodium hydroxide-polyol combinations at two mole ratios of sodium hydroxide to polyol showed that drying at 2:1 mole ratio (metal hydroxide to polyol) was more efficient than that of 3:1. Dehydration of alkaline solutions containing three or more hydroxyl groups (glycerol, sorbitol and xylitol) was faster than drying similar solutions of diols. The empirical formula determined confirmed that the resulting powders contained mono-sodium substituted alkoxides at 1:1, 2:1 and 3:1 (sodium hydroxide: polyol) mole ratio. Fatty acid methyl esters were prepared from canola oil and methanol using glycerol sodium alkylate as a catalyst. The conversion yield of oil to methyl ester was greater than 99 %. 相似文献
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The resistance of polished plate glass to sodium hydroxide, potassium hydroxide, sodium carbonate, potassium carbonate, and sodium pyrophosphate was studied at various concentrations and temperatures. Test results showed (1) that the hydroxides are less corrosive than many alkaline salts; (2) that temperature has a marked effect on the rate of corrosion; (3) that increasing the solution above 10% does not alter the rate of attack appreciably; and (4) that the amount of stain on glass cannot be used as a measure of the amount of attack. 相似文献
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插层改性水滑石及其对聚丙烯力学和阻燃性的影响 总被引:1,自引:0,他引:1
通过离子交换法制备了十二烷基磺酸钠、酒石酸氢钠、衣康酸改性的水滑石和十二烷基磺酸钠/衣康酸、十二烷基磺酸钠/酒石酸氢钠协同改性的水滑石(LDHs),通过熔融插层法制备得到了LDHs/PP复合材料。采用红外光谱(FTIR)、X射线衍射(XRD)、热重分析(TGA)对水滑石的结构和性能进行了分析表征,研究了LDHs/PP复合材料的力学性能和阻燃性。结果表明:上述几种单一和复合有机酸及盐改性剂都能不同程度地扩大水滑石的层间距;采用酸/盐协同改性的水滑石不仅有机基团含量较高,而且层间距大,显著提高PP的弯曲强度和阻燃性,表明酸和盐复合改性水滑石有显著协同作用及改性水滑石与PP基体相容性好。 相似文献
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The Pd(TPPTS)2Cl2 (TPPTS: triphenylphosphine trisulfonate, sodium salt) complex is immobilized on layered double hydroxides by the ion-exchange method. This heterogeneous catalyst is successfully used in Heck arylation of olefins. The catalyst can be recycled several times with almost consistent activity. 相似文献
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The effect of treatment with 5% sodium carbonate solution on aluminium hydroxides and oxyhydroxides likely to occur in soils has been investigated. Ultrasonic pretreatment, sample to solution ratio and temperature were factors studied. It is shown that particle size and degree of order of the sample influence the amount of alumina dissolved in 5% sodium carbonate solution in a fixed time; it is apparent, however, that both dissolution rate and solubility can be determining factors. Consequently, extraction with alkali at a low temperature and with a low solid: solution ratio is desirable for the preferential dissolution of poorly-ordered aluminous material from soil clays. 相似文献