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1.
Aminosilane bearing bulky substituents on nitrogen: LH2(L=Me2Si(NDipp-)2 , Dipp=2,6-diisopropylphenyl) was reacted with BuLi in toluene. The resulting bulky chelating dianion Me2Si(NDipp-)2 was used to synthesize the unusual spirocyclic heterotriatomic complex [Me2Si(NDipp)2]2Sn (1) by its reaction with SnCl4 and the bulky heterotriatomic complex Me2Si(NDipp)2SnPh2 (2) with Ph2SnCl2.1 belongs to the monoclinic system, space group P21/n with a=13.193(2), b=20.663(3), c=20.403(3), β=99.954(2)o, V=5478.3(15)3 , C55H85.5N4Si2Sn, Mr=977.64, Z=4, Dc=1.185Mg/m3 , μ(MoKα)=0.547mm-1 , F(000)=2086, S=1.000, the final R=0.0614 and wR=0.1322 for 14446 observed reflections (I2σ(I)) and R=0.0797 and wR=0.1456 for all data. 2 belongs to the triclinic system, space group Pī with a=10.36(15), b=13.204(7), c=14.363(7), α=90.214(10), β=106.182(7), γ=109.854(8)o, V=1764.4(15)3 , C38H50N2SiSn, Mr=681.58, Z=2, Dc=1.283 Mg/m3 , μ(MoKα)=0.785 mm-1 , F(000)=712, S=1.002, the final R=0.0498 and wR=0.0955 for 7533 observed reflections (I2σ(I)) and R=0.0676 and wR=0.1018 for all data. In the structure of 1, the tin atom is located in the spirocyclic center of the two fused four-membered SnN 2 Si rings. The two complexes were characterized by 1H NMR, elemental analysis, and single-crystal X-ray structural analysis. 相似文献
2.
近几年,钙钛矿/硅异质结叠层太阳电池发展迅速,效率已经从13.7%提升到29.1%.由于叠层电池器件的制作工艺复杂,而叠层太阳电池中的光学损失对转换效率的影响很大,所以通过光学模拟进而获得高效电池至关重要.本文首先从商业软件和自建模型两方面概述了光学模拟的方法,接着从反射损失和寄生吸收两方面针对光学模拟研究进展进行了总结和分析,最后指出了叠层电池光学模拟过程中需要注意的问题.钙钛矿/硅异质结叠层太阳电池的转换效率极限最高可达40%,具备很大的提升空间,结合模拟工作的研究,叠层电池的发展将会取得更大的进步. 相似文献
3.
丁毅 《数学物理学报(B辑英文版)》1990,(2)
In this paper we consider the eigenvalue problem of semilinear elliptic equation in R~n(n≥~3)-△u+α(x)u=λf(x, u), u∈H~1(R~n). 相似文献
4.
5.
Low energy neutron induced fission of 235U is studied in the framework of the multi-modal fission model. The fission fragment properties, such as the yields, the average total kinetic energy distribution and the average neutron separation energy, are investigated for incident neutron energies from thermal to 6.0 MeV. The multi-modal fission approach is also used to evaluate the prompt fission neutron multiplicity and spectra for the neutron-induced fission of 235U with an improved version of the Los Alamos ... 相似文献
6.
Analysis of prompt fission neutron spectrum and multiplicity for 237Np(n,f) in the frame of multi-modal Los Alamos model 下载免费PDF全文
The improved version of Los Alamos model with the multi-modal fission approach is used to analyse the prompt fission neutron spectrum and multiplicity for the neutron-induced fission of 237Np. The spectra of neutrons emitted from fragments for the three most dominant fission modes (standard Ⅰ, standard Ⅱ and superlong) are calculated separately and the total spectrum is synthesized. The multi-modal parameters contained in the spectrum model are determined on the basis of experimental data of fission fragment mass distributions. The calculated total prompt fission neutron spectrum and multiplicity are better agreement with the experimental data than those obtained from the conventional treatment of the Los Alamos model. 相似文献
7.
时空联合调制型空间外差干涉成像光谱仪(TS-SHIS)推扫图像中有明显的干涉条纹,这会导致传统的图像配准方法对TS-SHIS推扫图像配准计算结果的影响较大。鉴于此,提出一种基于目标干涉数据的自适应条纹模板构建方法,采用该方法消除TS-SHIS推扫图像中的干涉条纹,并利用曲面拟合加梯度法对消条纹后的推扫图像进行图像配准。仿真及实验研究结果表明,所提方法能够有效消除TS-SHIS推扫图像中零光程差处的干涉条纹;干涉条纹对配准计算的影响得到抑制;消条纹处理对图像配准计算结果的影响在0.02 pixel以内。 相似文献
8.
Semi-quantitative study on the Staebler--Wronski effect of hydrogenated amorphous silicon films prepared with HW-ECR-CVD system 总被引:1,自引:0,他引:1 下载免费PDF全文
The method of numerical simulation is used to fit the relationship between
the photoconductivity in films and the illumination time. The generation and
process rule of kinds of different charged defect states during illumination
are revealed. It is found surprisingly that the initial photoconductivity
determines directly the total account of photoconductivity degradation of
sample. 相似文献
9.
A series of a-Si:H films are deposited by hot wire assisted microwave
electron cyclotron resonant chemical vapour deposition
(HW-MWECR-CVD), subsequently exposed under simulated illumination for
three hours. This paper studies the microstructure change during
illumination by Fourier Transformation Infrared (FTIR) spectra. There
are two typical transformation tendencies of microstructure after
illumination. It proposes a model of light induced structural change
based on the experimental results. It is found that all samples
follow the same mechanism during illumination, and intrinsic
structure of samples affect the total H content. 相似文献
10.
大麦酯酶同工酶酶谱的聚类分析与遗传研究 总被引:4,自引:0,他引:4
采用聚丙烯酰胺凝胶电泳对主要产于我国不同地区的33份近缘野生大麦及其19份栽培大麦,以及它们间杂交的27个组合F1植株的叶片进行了酯酶同工酶分析.结果表明,52份材料可分成11个酶谱类型,聚类分析说明,同一亚种或同一变种,地理来源不同,酶谱表现不同.地理来源相同或相近的不同亚种或不同变种,酯酶同工酶酶谱一般表现出相同或相近.杂交组合F1中酶谱出现3种类型:偏亲本型,杂种型和互补型.其中以互补型为多.凡出现杂种酶带或互补酶带的植株,在穗长和株高上都表现出杂种优势的特征.对近缘野生大麦和栽培大麦的酶谱以及与地理距离的关系和酯酶同工酶在大麦中的应用进行了讨论. 相似文献