纳米Ce1-xCoxO2-δ固溶体的水热合成及表征

采用水热方法, 在络合剂及氧化剂的辅助下合成出传统方法难以合成的Ce1-xCoxO2-δ固溶体. XRD结果表明, Ce1-xCoxO2-δ固溶体具有立方萤石结构; 产物的平均粒度约为4 nm. 小半径、低价态Co离子的掺杂导致晶格收缩. 结合XRD和Raman表征结果确定固溶体的固溶限约为x=0.06. 紫外光谱分析结果表明, Co离子以混合价态(+2, +3)存在于CeO2晶格中, 随着钴掺杂量的增大, 带隙逐渐蓝移. 低于固溶限样品的室温体相电导率随着钴含量增大而提高.     

Hydrothermal Synthesis and Characterization of Ce_(1-x)Mn_xO_(2-δ) Solid Solutions

Nanocrystals of Ce1-xMnxO2-δ(x=0.00,0.05,0.10,0.15,and 0.20) were synthesized by a hydrothermal reaction route.The solid solutions crystallized in a cubic fluorite structure with a particle size in the range of 11～15 nm.The incorporation of Mn ions in CeO2 resulted in a lattice volume reduction.Mn ions showed a mixed valence state of +2,+3 and +4 in CeO2 lattice.An obvious red-shift of the absorption threshold edge was observed from the UV-visible spectrum.Compared with the bulk CeO2,Ce1-xMnxO2-δ nanocrystals exhibited a lower releasing oxygen temperature as indicated by TPR technique.     

流动注射胶束电化学发光测定过氧化氢的研究

建立了一种简易、快速检测过氧化氢的流动注射电化学发光法。本法基于铂丝阳极在 1.3 V(vs.Ag Cl/Ag)时 ,在含有 Na2 CO3 -Na HCO3 缓冲溶液的 KCl支持电解质中现场产生试剂 ,当注入过氧化氢溶液后即产生电化学发光。加入 Triton X-10 0形成的胶束能增强这一体系的发光强度。该法测定过氧化氢的线性范围为 1.0×10 -7～ 1.0× 10 -5 mol/L,对 4.0× 10 -7mol/L的过氧化氢进行 11次测定的相对标准偏差为 2 .6%。用这一方法对雨水中的过氧化氢进行了测定 ,结果满意。     

直角三角形的一个性质推广及应用

在直角三角形中,我们知道有 定理I宜角三角形中,斜边上高的倒数的平方等于两直角边倒数的平方和。 将其向空间推广,可得 定班2已知三棱锥C一ABC,匕AOB。乙BOC。乙CO才二0.,棱O刁、OB、OC分别为Rt△OAB中, 1一二土 O力名。.由定理l得+公:.(,,今7Ca、b、c, 证明h为高,则 又在Rt△ODC中,OE土DC,E为垂足,则 止_,*七+J_- O万,一O方:’玉:·将(1)代入上式,得(图1)才:一泰+小+二一人+ 命-,.’刁刀上OC典;+1.‘若C.作OD土A刀交月刀于D,则OC上OD,在,通刀止OD,.、AB土面ODC,从 少33而AB上O君,又O百一DC,.’.OE一面汉BC,即O…     

汉江上游沉积记录的北宋时期古洪水事件文献考证

基于对近年来汉江上游古洪水水文学研究成果的整理和分析,结合文献记载和气候背景分析,对汉江上游5个沉积剖面记录的北宋时期古洪水事件进行了文献考证.研究结果表明,北宋时期为洪水频发期;洪水灾害的影响范围、灾情的严重性以及洪痕沉积规律等表明,汉江上游5个沉积剖面记录的古洪水事件可能是北宋太平兴国七年（982年）六月的一次特大洪水事件.依据树轮、冰芯、石笋等气候代用性指标及历史文献记载,北宋太平兴国七年（982年）正处于北宋980年代气候突变时期,此次古洪水事件可能是对当时气候异常多变的瞬时响应.该研究结果可为汉江上游防洪减灾和水利工程建设提供科学依据.     

Role of Microstructure and Spectrum Features on the Catalysis Effect of Ce_(1-x)(Nd_(0.5)Eu_(0.5))_xO_(2-δ) Solid Solutions

Nanosized Ce_(1-x)(Nd_(0.5)Eu_(0.5))xO_(2-δ) solid solutions(x = 0.00~0.20) were synthesized by means of hydrothermal method.Then the solid solutions were ball milled with Mg_2Ni and Ni powders for 20 h to get the Mg_2Ni–Ni–5 mol% Ce_(1-x)(Nd_(0.5)Eu_(0.5))xO_(2-δ) composites.The structures and spectrum characteristics of the Ce_(1-x)(Nd_(0.5)Eu_(0.5))xO_(2-δ) solid solutions catalysts were analyzed systemically.XRD results showed that the doped samples exhibited single phase of CeO_2 fluorite structure.The cell parameters and cell volumes were increased with increasing the doped content.Raman spectrum revealed that the peak position of F_(2g) mode shift to higher wavenumbers and the peak corresponding to oxygen vacancies were observed distinctly for the doped samples.UV-Vis technique indicated that the absorption peaks of Eu~(3+) and Nd~(3+) ions appeared; the bandgap energy was decreased linearly.The electrochemical and kinetic properties of the Mg_2Ni–Ni–5 mol% Ce_(1-x)(Nd_(0.5)Eu_(0.5))xO_(2-δ) composites were measured.The maximum discharge capacity was increased from 722.3 mA h/g for x = 0.00 to 819.7 mA h/g for x = 0.16,and the cycle stability S_(20) increased from 25.0%(x = 0.00) to 42.2%(x = 0.20).The kinetic measurement proved that the catalytic activity of composite surfaces and the hydrogen diffusion rate were improved for the composites with doped catalysts,especially for the composites with x = 0.16 and x = 0.20.The catalysis mechanism was analyzed from the point of microstructure and spectrum features of the Ce_(1-x)(Nd_(0.5)Eu_(0.5))xO_(2-δ) solid solutions.     

KIO4-偶氮氯膦mA-邻菲啰啉体系催化光度法测定痕量锰

1引言 现代医学研究表明,微量元素作为机体的营养物质与人体的正常代谢有密切关系.     

纳米Ce_(1-x)(Fe_(0.5)La_(0.5)x)O_(2-δ)固溶体的水热合成及光谱分析

采用水热方法合成Ce1-x(Fe0.5La0.5)xO2-δ固溶体。利用X射线衍射技术(X-ray diffraction tech-nique,XRD)表征样品的相结构,并对固溶体的晶胞参数进行拟合,通过紫外可见漫反射光谱(UV-Vis dif-fraction spectrum)及拉曼光谱(Raman spectrum)表征其电子跃迁性能及由于双离子掺杂所引起的一系列掺杂效应。XRD结果表明,Ce1-x(Fe0.5La0.5)xO2-δ固溶体为CeO2立方萤石结构,当掺杂量增加到x=0.30时出现了微弱的Fe2O3杂相衍射峰;讨论了两种离子在晶格中不同的取代位置。晶胞参数随着掺杂量的增大而逐渐增大,当掺杂量达到x=0.18后保持基本不变。紫外漫反射光谱表明,随着掺杂量的增大,固溶体的带隙吸收边红移,即能隙逐渐减小,Fe离子在CeO2晶格中表现为+3价。Raman光谱F2g振动峰位逐渐向低波数方向移动,同时振动峰逐渐宽化,进一步证明了掺杂离子的影响效应。     

演示光路的一种方法

演示光路的一种方法张国芳（河南南阳师范专科学校）将约１ｃｍ３的普通洗衣肥皂一块放入约３００９的清水中煮化备用．取一只方形玻璃容器（如养鱼缸）容积约３００ｍｌ即可，灌入约单的水，然后滴入制好的肥皂水约１ｍｌ至玻璃杯中的清水变成乳白色、半透明即可．在滴入...