A Novel Ternary Composite of Polyurethane/Polyaniline/Nanosilica with Antistatic Property and Excellent Mechanical Strength: Preparation and Mechanism

Chinese Journal of Polymer Science - Antistatic and strength properties are of vital importance for polyurethane rubber used in moving parts of many industrial instruments. Herein, polyurethane was...     

Effects of high pressure on the Raman and fluorescence emission spectra of two novel 1,3,4-oxadiazole derivatives

The effects of pressure on the fluorescence emission and Raman spectra of 1,4-bis[（4-methyloxyphenyl）-1,3,4-oxadiazolyl]- 2,5-bisheptyloxyphenylene （OXD-2） and on the fluorescence emission spectra of 1,4-bis[（4-methylphenyl）- 1,3,4-oxadiazolyl]phenylene （OXD-1） are investigated using a diamond anvil cell. With the increase of pressure, the intensity of the fluorescence emission increases and reaches maxima at 13GPa for OXD-1 and at 9.6GPa for OXD-2. The effect of pressure on the peak position of the emission shows a similar trend, red shift with the increase of pressure. But at higher pressures, the intensity of emission drops down dramatically. The Raman spectra of OXD-2 indicate that there appears a structural change at ca 3GPa.     

A ligand-free copper(I) oxide catalyzed strategy for the N-arylation of azoles in water

A simple and practical protocol has been developed for the cross-coupling of azoles and aryl iodides under ligand-free copper(I) oxide catalyzed conditions in water. The protocol uses tetrabutylammonium bromide (TBAB) as the phase-transfer catalyst, and water as the solvent, and shows good tolerance towards various functional groups.     

Phase Transition Behavior of LiCr 0.35 Mn0.65O2 under High Pressure by Electrical Conductivity Measurement

The electrical conductivity of powdered LiCr 0.35 Mn0.65O2 is measured under high pressure up to 26.22 GPa in the temperature range 300-413 K by using a diamond anvil cell. It is found that both conductivity and activation enthalpy change discontinuously at 5.36 GPa and 21.66 GPa. In the pressure range 1.10-5.36 GPa, pressure increases the activation enthalpy and reduces the carrier scattering, which finally leads to the conductivity increase. In the pressure ranges 6.32-21.66 GPa and 22.60-26.22 GPa, the activation enthalpy decreases with pressure increasing, which has a positive contribution to electrical conductivity increase. Two pressure-induced structural phase transitions are found by in-situ x-ray diffraction under high pressure, which results in the discontinuous changes of conductivity and activation enthalpy.     

基于Add-drop型微环谐振腔的硅基高速电光调制器设计

相比于传统的All-pass型微环谐振腔硅基电光调制器, Add-drop型微环谐振腔可提供更多的设计自由度, 使调制器在不改变杂质掺杂浓度的情况下就能在调制带宽和消光比性能上获得均衡考虑. 本文设计了基于Add-drop型微环谐振腔的高速、且在低调制电压下实现大消光比的硅基电光调制器, 所用微环谐振腔的半径仅仅为20 μm. 重点分析了直波导与微环谐振腔的耦合对调制器性能的影响, 发现较小的Drop端耦合系数有利于消光比的提高, 但是不能同时达到最佳的调制带宽, 因此设计上存在一个带宽和消光比性能上的折中考虑. 根据优化设计的结果进行了实际器件的制作和测试. 静态光谱测试表明, 在3 V反向偏置电压的作用下, 调制器的消光比最大可达12 dB. 动态电光响应测试中, 在仅仅1.2 V的信号幅值电压下测得了8 Gbps数据传输速率的清晰眼图. 关键词： 电光调制器 绝缘体上的硅 微环谐振腔 载流子色散效应     

磷灰石结构荧光粉Ba10(PO4)6F2:Ce3+,Tb3+的合成、发光和能量传递

采用高温固相法合成了系列Ce~(3+)和Ce~(3+)/Tb~(3+)激活的具有磷灰石结构荧光粉Ba_(10)(PO_4)_6F_2。用X射线衍射(XRD)、扫描电镜(SEM)、激发和发射(PLE和PL)光谱对样品进行了表征分析。研究结果表明:所合成的荧光粉Ba_(10)(PO_4)_6F_2∶Ce~(3+),Tb~(3+)具有氟磷灰石结构,样品微观呈现不规则形貌。荧光粉Ba10-x(PO4)6F2∶x Ce~(3+)的相对发射强度随着x增加而增强,当x=0.09时,荧光强度达到最大。荧光粉Ba_(10)(PO_4)_6F_2∶Ce~(3+),Tb~(3+)的激发光谱为240～330 nm的宽带,发射光谱呈现出Ce~(3+)的5d→4f跃迁紫外光(335和358 nm)发射和Tb~(3+)的4f→4f跃迁绿光(542 nm)发射。光谱特性表明,发光过程中存在Ce~(3+)→Tb~(3+)能量传递,能量传递效率可以达到60%。计算Ce~(3+)和Tb~(3+)的临界距离为0.79 nm,能量传递机理是偶极-偶极交互作用。此外,详细论述了Ce~(3+)和Tb~(3+)之间的能量传递和发光的过程。通过调节Tb~(3+)的掺杂浓度,对荧光粉发光色坐标与Tb~(3+)的掺杂浓度之间的关系也进行了研究,随着Tb~(3+)的掺杂量从0增加0.52,荧光粉Ba_(10)(PO_4)_6F_2∶Ce~(3+),Tb~(3+)的发射光谱色坐标可以从(0.149 4,0.045 1)蓝色区变化到(0.280 1,0.585 3)绿色区。     

Doublet bands at borders of A ≈ 130 island of chiral candidates: Case study of ~(120)I

Positive-parity doublet bands were reported in ~(120)I. Based on these, we discuss the corresponding experimental characteristics, including rotational alignment, and re-examine the corresponding configuration assignment.The self-consistent tilted axis cranking relativistic mean-field calculations indicate that the doublet bands are built on the configuration πh_(11/2)■νh_(11/2)~(-1). By adopting the two quasiparticles coupled with a triaxial rotor model, the excitation energies, energy staggering parameter S(I), B(M1)/B(E2), effective angles, and K plots are discussed and compared with available data. The obtained results support the interpretation of chiral doublet bands for the positive-parity doublet bands in ~(120)I, and hence identify this nucleus as the border of the A ≈ 130 island of chiral candidates.     

利用电导率测量方法研究不同粒径ZnS高压相变过程

利用在金刚石对顶砧上集成的金属电极,对不同粒径的ZnS材料进行了高压原位电导率测量. 粒径为2 μm的体材料ZnS在15 GPa时,电导率迅速增大5个数量级,表明体材料ZnS此时发生了从闪锌矿到岩盐矿的结构相变. 而粒径6 nm的纳米材料ZnS的结构相变压力为21 GPa. 电导率测量结果还表明纳米 ZnS比体材料ZnS还具有更宽的迟滞区间.     

铁电双层膜的反转动力学行为

基于Landau-Khalatnikov运动方程,本文研究了含有表面过渡层和铁电界面耦合的反转动力学行为(包括平均极化、反转时间、反转电流和矫顽场).研究结果表明:在铁电双层膜系统中存在一个竞争的机理,即表面过渡层与界面耦合的竞争作用.我们发现在双层膜反转过程中出现了反常行为,这些反常行为归因于表面过渡层与界面耦合之间的竞争.表面过渡层与界面耦合的共同行为对铁电双层膜的动力学特性起到了决定性的作用.     

Spin-1 pyrochlore antiferromagnets: Theory,model, and materials’ survey

Pyrochlore magnets can be a unique platform to demonstrate numerous important concepts and applications of frustrated magnetic physics in modern condensed matter physics. Most works on pyrochlore magnets deal with the interacting spin-1/2 local moments, while much less works have studied the spin-1 systems. We here review the physics with interacting spin-1 local moments on the pyrochlore lattice to illustrate the potentially interesting physics associated with spin-1 magnets. The generic pyrochlore spin-1 model includes the antiferromagnetic Heisenberg interaction, the Dzyaloshinskii– Moriya interaction and the single-ion spin anisotropy. The global phase diagram of this generic spin model is reviewed, and the relation between different quantum phases in the phase diagram is clarified. The critical properties of the transition from the parent quantum paramagnet to the proximate orders are discussed. The presence of quantum order by disorder in the parts of the ordered phases is analyzed. The elementary excitations with respect to the ground states are further reviewed, and the topological natures of these excitations are carefully addressed. The materials’ relevance of the spin-1 pyrochlore magnets are finally reviewed. This review may provide insights about the interesting spin-1 local moments on frustrated systems.