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针对复合圆柱壳在炸药爆轰作用下的动力学响应及在此过程中伴随的失稳问题,研究了其制造工艺中可能出现的缺陷以及圆柱壳中铜线螺旋角和直径对复合圆柱壳稳定性产生的影响。采用SPH-FEM耦合算法,建立了复合圆柱壳二维细节模型,并提出了一种基于圆柱壳内壁粒子速度历史的失稳判据,计算了在不同参数条件下复合圆柱壳的失稳时间及对应的压缩率,对影响复合圆柱壳稳定性的因素进行了评估。分析结果表明,在复合圆柱壳制备过程中存在的折返层缺陷和铜线直径对复合圆柱壳的稳定性有较大影响,而螺旋角度对其稳定性影响不大。 相似文献
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介绍了在有机物结构、有机反应机理和构象快速转换平衡的教学中培养学生构建空间感观的策略.教学实践表明,这些策略的实施具有较好的效果. 相似文献
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The phenomenon of the near ppˉ-threshold enhancement observed in the J/ψ→γ pp decay is studied by using the enhancement factor method with a simpler one-pion-exchange potential between p and p. The Jost function caused by the mentioned potential is perturbatively calculated in the zero-th order approximation, and the corresponding enhancement factor is obtained. It is found that such a final state interaction offers an important contribution to the decay width near the ppˉ-threshold, although it is not large enough. To explain the decay data, a phenomenological factor G(p) with the form of 285500/(m 2 π + p 2 ) should be introduced. A further calculation including the p-dependent bare T -matrix, a more realistic N ˉ N potential and the contribution from the higher-order wave functions would provide a better understanding of the decay data and even the existence of the baryonium ppˉ. The near ppˉ-threshold behavior of the decay width in the J/ψ→π 0 pp process is also discussed. 相似文献
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溶剂法合成对甲苯甲腈 总被引:1,自引:0,他引:1
对甲苯甲腈是很重要的有机合成中间体,被广泛地应用在药物、染料及其它精细化工产品的合成上。它的主要合成方法有重氮盐的Sandmeyer 反应法^[1],醛肟脱水法^[2]和羧酸脱水法^[3,4]等。从工艺的可行性和经济角度来考虑,由对甲苯甲酸脱水(熔融法)直接制备对甲苯甲腈较为合理,但该法反应物升华严重,升华物易造成管道堵塞,给实际操作带来极大的不便。近年来廖道华等^[5]提出了溶剂法由羧酸直接合成腈的方法,该法与熔融法相比,产品收率高,工艺条件也得到了改善。本文研究对甲苯甲酸在溶剂中同尿素反应制备对甲苯甲腈的工艺条件,与熔融法相比,该方法所得产品收率高,工艺条件也得到了改善,易于工业化生产,值得推广。 相似文献
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The title compound(Sulindac)was prepared from the corresponding sulfinyl compound p-methylsulfinylbenzylbromide by four-step reaction.The sole product(Z)-5-fuoror-2-methyl-1-(p-methylsulfinylbenzylidene)-3-indenylacetic acid(Sulindac)was obtained and the E isomer of it was not found.X-ray single crystal diffraction analysisshowed that the strong intermolecular hydrogen bonding and weak intermolecular hydrogen bonding coexisted inSulindac. 相似文献