Fabrication of PbSO4 negative electrode of lead-acid battery with high performance

Journal of Solid State Electrochemistry - This paper reports the preparation and electrochemical properties of the PbSO4 negative electrode with polyvinyl alcohol (PVA) and sodium polystyrene...     

Racemic and enantioselective total synthesis of heliespirones A&C

An account of the total synthesis of(±)-,(+)-heliespirone A and(±)-,(-)-heliespirone C is presented.In the first-generation total synthesis,we found rac-24a could be easily transformed to rac-heliespirones A&C in a biomimic way.Taking the disappointing diastereoselectivity of prenylation from 3 to 4,the nonselective dihydroxylation from 4 to 5 and the lenthy route in strategy A into account,we designed a different synthetic plan targeting a highly enantioselective,concise and protective-group free synthesis...     

A critical transition rule for broadening exponent of fluctuation and its effect on dissipation in chemical reaction-heat conduction coupling systems

A stochastic model of chemical reaction-heat conduction-diffusion for a one-dimensional gaseous system under Dirichlet or zero-fluxes boundary conditions is proposed in this paper. Based on this model,we extend the theory of the broadening exponent of critical fluctuations to cover the chemical reaction-heat conduction coupling systems as an asymptotic property of the corresponding Markovian master equation (ME),and establish a valid stochastic thermodynamics for such systems. As an illustration,the non-iso...     

弹塑性本构关系的Ilyushin应变空间理论研究进展

Ｉｌｙｕｓｈｉｎ提出五维偏应变矢量空间中的一般弹塑性本构理论，将应力表示为变形迹内蕴几何学参数的泛函，适合于描写复杂加载下金属材料的塑性响应特性。本文对其实验和理论两方面的研究进展作了综述，涉及关于塑性响应矢量特性的“局部确定性”假设，标量特性的“延心原理”假设及Ｉｌｙｕｓｈｉｎ关于矢量空间的“特殊各向同性”假设等的实验研究和验证，微分型和积分型本构模型的建立及所含本构泛函的形式和确定。     

Normal scalar curvature and a pinching theorem in S~m×R and H~m×R

We obtain an inequality in Sm×R and Hm×R which is similar to DDVV conjecture.As an application,we show that a minimal submanifold in H m×R with nonnegative scalar curvature must be a surface of the type γ×R,where γ is a geodesic in H m.In addition,we get a pinching theorem in Sm×R.     

射流抛光误差分析与材料去除稳定性研究

研究了射流抛光材料去除面形不呈理想的对称形和重复抛光材料去除量的波动不稳性,分析认为射流抛光过程稳定性和误差因素会影响材料去除的不稳定性.分析了射流系统的误差影响因素,其主要由压力波动、磨粒沉降作用和流体的紊动作用等部分组成,并研究了各误差影响因素的产生机理和对材料去除的影响.通过仿真和实验分析,得到压力波动、磨粒沉降...     

非零色散位移光纤的制造新工艺研究

介绍了一种新的改进化学气相沉积法(MCVD)+气相轴向沉积法(VAD)预制棒制备工艺,该工艺按照归一化波导结构进行工艺设计和参数控制,即采用MCVD法制备归一化结构参数轴向一致的芯棒,然后采用VAD法轴向沉积相应的外包层,从而得到波导结构轴向均匀一致的预制棒.采用新工艺实验研究了非零色散位移光纤的制造过程,成功制造了波...     

运动轨迹对抛光误差的影响分析和轨迹优化研究

针对现有光学加工抛光头运动方式由于光栅形或螺旋形等对称扫描方式带来的运动轨迹间的迭代误差,提出随机轨迹抛光运动方式.随机轨迹方法通过随机轨迹算法随机生成镜面离散点的抛光顺序和抛光轨迹,采用随机轨迹驻留时间补偿方法控制镜面离散点的驻留时间,对各个点进行相应大小的材料去除.实验结果显示,随机轨迹方法产生的抛光运动轨迹表现为...     

减压涂层—氯化钙改进石墨炉原子吸收法测定米粉中钼

在减压条件下。在全热解石墨管上涂La,使GFAAS测Mo的灵敏度大幅度提高。采用CaCl_2作基体改进剂,可消除测米粉中Mo时常见的干扰。特征质量为16.298/0.0044A.S,检出限为0.76ng/ml。经样品测定检验,方法的准确度和精密度均获满意结果。     

Preparation of PO4^3-, P2O7^4- Anion-Pillared Nanocrystalline Mg-Al and Zn-Al Layered Double Hydroxides in Microwave Fields

Using nanocrystalline [Mg-Al-CO3] and [Zn-Al-CO3] as precursors, [Mg-Al-PO4],[Zn-Al-PO4], [Mg-Al-P2O7] and [Zn-Al-P2O7] have been successfully synthesized by a direct reaction with the free PO4^3- or P2O7^4- using the microwave techniques and the anion-exchange method. And the samples thus obtained were characterized by TEM, FT-IR and XRD. The results show that the initial interlayer carbonate ions can be completely replaced by the free PO4^3- or P2O7^4- under controlled microwave conditions employed for a short time.