Crystal Structure and EPR Spectra of cis—Dioxo—molybdenum（V） Complex with o—Aminophenol

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Electrochemical Studies on the Interactions of Dipyridophenazine Complex of Ruthenium and Herring Sperm DNA

Cyclic voltammetry (CV) and single-step chronocoulometry were used to study the interaction of [Ru(phen)2dppz]2 (phen=l,10-phenanthroline; dppz=dipyrido[3,2-a:2‘,3‘-c]phen-azine) with herring sperm DNA. The addition of DNA caused a diminution in the peak current and a positive shift in the peak potential of the complex of [Ru(phen)2dppz]2 . The 12 mV positive shift in the peak potential of [Ru(phen)2dppz]^2 indicates that [Ru(phen)2dppz]^2 binds 2.6 times more strongly to DNA than its reductive form. In addition, by using fluorimetric and UV-spectrophotometric methods and studies of denatured DNA and the effect of NaC1 solution, it was also found that the binding mode was intercalation. The decrease of peak current is proportional to the concentration of DNA, which can be applied to estimate DNA concentration.     

THE OPIAL INEQUALITY IN R~N

Where n is a bounded smooth dornain in RN, A.u = Z k(IVuIp--'e) is the p1aPlacei = 1operator, p 2 2, q E be, ff) are some given real number. By this result, we deduce the famousOpial inequality in RN.As we know, the solvabiliy of problem (1) resuIts from whether the minimumcan be achieved. If (2) is achieved, the attained function W(x) is the nontrivial solution ofproblem (1) corre8ponding to A = A1(p, q, n) and ^ = ^1(p, ql n) is the corresponding ndnimumeigenvalue. Since q i8 8maller …     

独居石微晶玻璃中玻璃相含量的红外光谱定量测定

独居石微晶玻璃由偏磷酸盐玻璃和独居石两相组成。玻璃和独居石的红外吸收谱带彼此不相重叠,且1275和616cm~(-1)谱带的吸收强度随玻璃相的含量变化而变化。两谱带的对数吸光度比值与玻璃相含量(w％)的相关系数r=0.9975,其回归方程为y=48.356 25.93x。合成独居石的IR谱中952和616cm~(-1)谱带的吸光度比值也随不同的Ce_2O_3/La_2O_3比值规律变化。其r=0.9917,回归方程为y=0.2211exp(0.0221x)。高的相关性表明IR技术可在磷酸盐微晶玻璃物相定量分析中得到实际应用。     

Synthesis of Covalently-linked Linear Donor-Acceptor Copolymers Containing Porphyrins and Oligothiophenes

The construction of macro-molecular system containing multiple redox centers or photosensitizers is aimportant subject in the design of molecular electronidevices.1,2 For such objectives, systematization of donor-redox center-acceptor triad molecules into largmolecular systems is one of the most feasible approaches, because the exquisite incorporation of thphotosensitizers and suitable electron donors and/oacceptors into a polymeric chain is useful for varioumolecular electronic systems.3-5 Th…     

Interpolation for weak Orlicz spaces with M_Δ condition

An interpolation theorem for weak Orlicz spaces generalized by N-functions satisfying MΔ condition is given. It is proved to be true for weak Orlicz martingale spaces by weak atomic decomposition of weak Hardy martingale spaces. And applying the interpolation theorem, we obtain some embedding relationships among weak Orlicz martingale spaces.     

低插损平坦谱响应阵列波导光栅解复用器优化设计

通过在输入波导与输入平板波导之间加入一种模式转换结构,获得了一个具有平坦光谱响应,低插损,光谱响应对称的阵列波导光栅型波分复用器,该模式转换结构由一个与输入波导的输出端连接的第一锥形波导,一个与此锥形波导输出端连接的细直波导,一个与细直波导输出端连接的第二个锥形波导以及一个连接输入平板波导和第二个锥形波导的梯形波导组成,通过优化设计梯形波导和第二个锥形波导的形状可以获得较宽的1dB通带带宽和较低的插损,同时光谱响应具有非常好的平坦性,而且通过对第一个锥形波导和细直波导的优化设计,在不引入明显的额外插损的条件下,能大大减小由于输入波导的弯曲引入的光谱响应的不平坦.     

金纳米粒子自组装薄膜的光谱学研究

采用柠檬酸钠还原氯金酸制备了金胶体，通过静电自组装制备了金纳米粒子薄膜，利用紫外-可见光吸收光谱等对金纳米粒子薄膜进行了光谱学研究，紫外-可见光吸收光谱表明所制备的金溶胶为单分散体系，根据自组装薄膜的X-射线衍射谱，由谢乐公式估算金纳米粒子的粒径约为21nm；X-射线光电子能谱显示氯金酸的还原反应比较完全，金主要以Au^0的价态存在，金胶体粒子通过静电吸引机制组装到PDDA改性的衬底表面；紫外-可见光吸收光谱和表面增强拉曼光谱显示，由于粒子间的电磁耦合，自组装金纳米粒子薄膜表现出协同等离子体共振吸收行为和表面增强拉曼散射效应。     

A RELATIVE BENEFIT ALGORITHM FOR BASIC ECONOMIC LOT SIZE PROBLEM

1 IntroductionMany problems in inventory control, production planning can be formulated in terms of asimple economic lot size model proposed by H.M.wagner and T.M.Whitin(1958). Since 1958, theManne-Wagner-Ehitin model has received considerable attention, and several hundred paPershave directly or ndirectly discus8ed this model; most Of these paper8 have either eXtended thismodel or proYided efficient algorithms for production problems that arise in it. (In particular,see Florian, Lenstra…     

结构动力模型修正方法的比较研究及评估

在实际工程中,由结构动力模型得到的计算值与通过试验获得的测量值间往往存在偏差,为了能够精确预测结构的动力响应,依据测量信息修正存在的动力模型是非常必要的.对现有几种有效的用于结构动力模型修正的理论方法(包括基于敏感性分析的矩阵型法、基于神经网络算法的参数型法和基于遗传优化算法的方法)做了详细的综述;介绍了这些方法的步骤和研究进展;并分析了这些动力模型修正方法在工程运用中存在的一些实际问题,如不完整的模态测量值、模型修正的鲁棒性、模型修正的计算效率和收敛性等.最后,通过对一实际的五层钢框架的动力模型修正,比较了这几种方法的优缺点,提出了今后需要解决的问题.