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亚甲基蓝和Ag^+在活性炭纤维上的共吸附
引用本文:陈水挟,陆耘,曾汉民.亚甲基蓝和Ag^+在活性炭纤维上的共吸附[J].材料研究学报,1998,12(5):539-542.
作者姓名:陈水挟  陆耘  曾汉民
作者单位:中山大学!广州市,510275(陈水挟,陆耘),中山大学材料科学研究所!广州市,510275(曾汉民)
基金项目:国家“863”计划资助!960344
摘    要:研究了水蒸汽活化和化学活化两类活性纤维(ACF)对水溶液中单组分亚甲基蓝和Ag(NH3)^+2以及两者共存时的吸附特征,ACF对水溶液中亚甲基蓝的吸附量主要取决于其表面积和孔分布,ACF对Ag^+的还原一吸附能力则主要取决其表面的化学性质,相同条件下,化学活化的ACF对银离子的还原吸附量(300mg.g^-1)比水蒸活化的ACF的还原-吸附量(100mg.g^-1)高,溶液中亚甲基蓝的存在显著改变

关 键 词:活性炭纤维  共吸附  亚甲基蓝    氧化还原
收稿时间:1998-10-25
修稿时间:1998-10-25

THE COADSORPTION OF Ag~+ AND METHYLENE BLUE ON ACFs
CHEN Shdria,LU Yun,ZENG Hanmin.THE COADSORPTION OF Ag~+ AND METHYLENE BLUE ON ACFs[J].Chinese Journal of Materials Research,1998,12(5):539-542.
Authors:CHEN Shdria  LU Yun  ZENG Hanmin
Affiliation:CHEN Shdria,LU Yun,ZENG Hanmin (Materials Science Institute,Zhomphan University,Guangzhou )
Abstract:Single component adsorption and coadsorption behavior of Ag(NH3); and methylene blue on two kinds of ACFs, aCtivated with steam and ZnCl2 respectively, were studied. The adsorption of methylene blue on these two kinds of ACFs could be described with Langmuir equation quite well.The amounts of methylene blue adsorbed on ACFs mainly depended on the specific sudece area and pore size distribution of ACF. The reduction-adsorption amount of Ag by ACFs however, depend on the sudece chemistry of ACFs. It was shown that the reduction-adsorption amounts of Ag by ZCSACF or ZCSACF which was activated by ZnCl2 were about 300mg.g-1 carbon, which was 3 times of that by SACF activated by steam. The reduction-adsorption capacities of Ag by SACF was enhanced by the peence of methylene blue. The reduction-adsorption amount of Ag on SACF at the presence of methylene blue could reach as high as 600mg.g-1 carbon.
Keywords:activated carbon fiber  coadsorption  methylene blue  silver  redox
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