Synthetic musk emissions from wastewater aeration basins

Wastewater aeration basins at publicly owned treatment works (POTWs) can be emission sources for gaseous or aerosolized sewage material. In the present study, particle and gas phase emissions of synthetic musks from covered and uncovered aeration basins were measured. Galaxolide (HHCB), tonalide (AHTN), and celestolide (ADBI) were the most abundant, ranging from 6704 to 344,306 ng m⁻³, 45-3816 ng m⁻³, and 2-148 ng m⁻³ in the gas phase with particle phase concentrations 3 orders of magnitude lower. The musk species were not significantly removed from the exhaust air by an odor control system, yielding substantial daily emission fluxes (∼200 g d⁻¹ for HHCB) into the atmosphere. However, simple dispersion modeling showed that the treatment plants are unlikely to be a major contributor to ambient air concentrations of these species. Emission of synthetic musk species during wastewater treatment is a substantial fate process; more than 14% of the influent HHCB is emitted to the atmosphere in a POTW as opposed to the <1% predicted by an octanol-water partition coefficient and fugacity-based US EPA fate model. The substantial atmospheric emission of these compounds is most likely due to active stripping that occurs in the aeration basins by bubbling air through the sludge.     

AERATED ROCK FILTERS FOR ENHANCED AMMONIA AND FAECAL COLIFORM REMOVAL FROM FACULTATIVE POND EFFLUENTS

Nitrogen removal from wastewater is rapidly becoming an essential but expensive upgrade for many small wastewater treatment works in the UK. Using a pilot-scale waste stabilization pond effluent, this paper highlights a low-cost upgrading unit, capable of removing BOD, SS, ammonia and faecal colliforms. Results are given for 12 months of operation and it is suggested that these units could be used by the water companies when ammonia removal is necessary to meet with current legislative demands and prevent eutrophication of receiving watercourses.     

Mechanisms for naphthalene removal during electrolytic aeration

Batch tests were performed to investigate chemical and physical processes that may result during electrolytic aeration of a contaminated aquifer using naphthalene as a model contaminant. Naphthalene degradation of 58-66% took place electrolytically and occurred at the same rates at a pH of 4 and 7. 1,4-naphthoquinone was identified as a product of the electrolysis. Stripping due to gases produced at the electrodes did not result in any naphthalene loss. Hydrogen peroxide (which may be produced at the cathode) did not have any effect on naphthalene, but the addition of ferrous iron (which may be present in aquifers) resulted in 67-99% disappearance of naphthalene. Chlorine (which may be produced from the anodic oxidation of chloride) can effectively degrade naphthalene at pH of 4, but not at a pH of 7. Mono-, di- and poly chloronaphthalenes were identified as oxidation products. Ferric iron coagulation (due to the oxidation of ferrous iron) did not significantly contribute to naphthalene loss. Overall, electrolytic oxidation and chemical oxidation due to the electrolytic by-products formed are significant abiotic processes that could occur and should be accounted for if bioremediation of PAH-contaminated sites via electrolytic aeration is considered. Possible undesirable products such as chlorinated compounds may be formed when significant amounts of chlorides are present.     

An aeration energy model for an immersed membrane bioreactor

A simple model for evaluating energy demand arising from aeration of an MBR is presented based on a combination of empirical data for the membrane aeration and biokinetic modelling for the biological aeration. The model assumes that aeration of the membrane provides a proportion of the dissolved oxygen demanded for the biotreatment. The model also assumes, based on literature information sources, a linear relationship between membrane permeability and membrane aeration up to a threshold value, beyond which permeability is unchanged with membrane aeration. The model was benchmarked against two full-scale plant to obtain the most appropriate and conservative value of the slope of the flux:aeration curve and the blower efficiency. Benchmarking in this way produced a match to within 20% of all key process plant operational parameters.The model demonstrated that significant reductions in aeration energy could be obtained through operation at lower flux and reducing the membrane aeration requirement accordingly, so-called “proportional aeration” at lower flows. Similarly, increasing oxygen transfer from membrane aeration would also be expected to decrease energy demand. A sensitivity analysis of some of the key parameters revealed that, of the key operating parameters, loading, SOTE and MLSS concentration remain the most critical in determining energy demand. It is suggested that a key parameter representing membrane aeration in MBRs is the mean in-module air upflow velocity U, since this gives a reasonable representation of the shear applied through membrane aeration. U was found to vary between 0.04 and 0.1 m/s across a number of modern large pilot and full-scale plant.An analysis reveals that significant reductions in energy demand are attained through operating at lower MLSS levels and membrane fluxes. Evidence provided from recent controlled pilot trials implies that halving the flux can reduce the aeration is suggested whereby the number of membrane tanks on line and/or the membrane aeration intensity is adjusted according to the flow, and thus flux, so as to reduce the overall aeration energy demand.     

Effect of high power ultrasonic treatment on whey protein foaming quality

High power ultrasonic energy at 20%, 40% and 60% amplitude was applied on whey protein suspension at concentrations of 100, 150 and 200 g kg^?1 for 5, 15 and 25 min to improve its foaming quality. Ultrasound‐treated whey protein suspension at 200 g kg^?1 showed improvement in terms of increased foaming capacity by 18%, foam stability by 35%, consistency index by 18%, storage modulus by 17%, loss modulus by 26% and viscosity by 21% compared with untreated whey protein. For maximally ultrasound‐treated samples of 60% amplitude treated for 25 min, the improved whey protein foams also had a 46% increase in the number of more evenly distributed fine bubbles which had a size smaller than 0.0025 mm³ as imaged using X‐ray microtomography.     

Water-Circulating Aerator: Optimizing Structure and Predicting Water Flow Rate and Oxygen Transfer

Thermal stratification is a common phenomenon in deep lakes and reservoirs, which often results in water-quality deterioration, including such problems as hypolimnetic anoxia, the release of pollutants from sediments, and algal blooms. Hypolimnetic oxygenation and destratification are the two commonly used methods for resolving these water-quality problems. A new water-quality improvement device, the water-circulating aerator, was designed to destratify lakes and reservoirs, by circulation and oxygenation of upper and lower layers of water. The design of the structure of the water-circulating aerator is detailed. Three mathematical models were built to optimize this structure, estimate the rate of water flow in the aerator, and calculate the rate of oxygen transfer from air bubbles to water in the aerator. These models were verified by experiments. The water-circulating aerator system has been successfully applied in a stratified reservoir to increase dissolved oxygen to reduce the releasing of ammonia-nitrogen from sediments under anoxic conditions.     

8-羟基喹啉萃取处理氯化亚铜废水的研究

通过预曝气的方法,简化了氯化亚铜废水溶液的粒子结构,采用8-羟基喹啉作为萃取剂,对曝气后溶液进行萃取实验。考察萃取平衡时间、曝气时间、温度等因素对废水处理效果的影响规律,确定了最佳反应条件,为优化萃取法处理氯化亚铜废水提供技术参考。     

A jet mixing study in two phase gas-liquid systems

All studies concerned with jet mixing have been focused on liquid phase systems and no studies have been found on jet mixing for gas-liquid two phase systems. In the present study the use of jet fluid as a mixer in gas-liquid systems was proposed. Further by installing an experimental setup, the mixing behavior of liquid phase was studied. Gas flow and jet flow are injected to the mixing vessel countercurrently. In this study, the effect of jet injection, location of the conductivity probe, aeration rate and jet Reynolds number on the mixing time are investigated. The created flow pattern was extracted for each condition and the results often analyzed on the basis of them. It is observed that, for low aeration rates, the injection of jet decreases the mixing time considerably. By increasing the aeration rate, the difference in mixing times between the two cases of jet injection and without jet is reduced. Results also show that the closer the probe is to encounter location of the jet and airflow, the lower the mixing time obtained. Dependence of mixing time on the probe location decreases by increasing the mixing intensity and eliminating dead zones. It is obtained, on the basis of Re_j and the amount of jet travelling in the vessel, increasing the aeration rate has different effects on the performance of mixing. Generally, four different trends for the variation of mixing time with increasing the aeration rate are observed.     

Kinetic Energy Approach to Dissolving Axisymmetric Multiphase Plumes

A phenomenological kinetic energy theory of buoyant axisymmetric multiphase plumes is constructed, with particular attention to the modeling of the dispersed phase. The dissolution is treated by means of the Ranz-Marshall equation involving a mass-transfer coefficient dependent on the plume properties. The model is compared with various experiments, yielding satisfactory agreement. A central ingredient in the model is the turbulent correlation parameter I, playing a role analogous to the conventional entrainment coefficient α. We use experimental data to suggest a relationship between I, the initial gas flux at the source, and the depth of the gas release.     

Chute Aerators. II: Hydraulic Design

Chute aerators are applied if cavitation damage on spillways is expected or observed. The aerator efficiency is usually described with the ratio of the air discharge entrained through the air supply ducts and the water discharge, which does however not account for the resulting air concentration distribution within the flow or for air detrainment. The present study investigates the streamwise development of the air transport along the flow downstream of chute aerators. Based on an extensive test program in which six governing parameters were systematically varied, the development of the average and the bottom air concentrations is provided up to the self-aeration point. Based on this information, an optimization of aerators in terms of increased air entrainment and reduced detrainment rates is possible, by assuming minimum required air concentrations. The main parameters influencing the air transport downstream of aerators are the approach flow Froude number, the deflector angle and the chute bottom angle.