Optimization of hydrogen enrichment via palladium membrane in vacuum environments using Taguchi method and normalized regression analysis

In this study, the separation of hydrogen from gas mixtures using a palladium membrane coupled with a vacuum environment on the permeate side was studied experimentally. The gas mixtures composed of H₂, N₂, and CO₂ were used as the feed. Hydrogen permeation fluxes were measured with membrane operating temperature in the range of 320–380 °C, pressures on the retentate side in the range of 2–5 atm, and vacuum pressures on the permeate side in the range of 15–51 kPa. The Taguchi method was used to design the operating conditions for the experiments based on an orthogonal array. Using the measured H₂ permeation fluxes from the Taguchi approach, the stepwise regression analysis was also employed for establishing the prediction models of H₂ permeation flux, followed by the analysis of variance (ANOVA) to identify the significance and suitability of operating conditions. Based on both the Taguchi approach and ANOVA, the H₂ permeation flux was mostly affected by the gas mixture composition, followed by the retentate side pressure, the vacuum degree, and the membrane temperature. The predicted optimal operating conditions were the gas mixture with 75% H₂ and 25% N₂, the membrane temperature of 320 °C, the retentate side pressure of 5 atm, and the vacuum degree of 51 kPa. Under these conditions, the H₂ permeation flux was 0.185 mol s^?1 m^?2. A second-order normalized regression model with a relative error of less than 7% was obtained based on the measured H₂ permeation flux.     

Total Site Hydrogen Integration with fresh hydrogen of multiple quality and waste hydrogen recovery in refineries

This paper proposes a novel method combining Pinch Methodology and waste hydrogen recovery, aiming to minimise fresh hydrogen consumption and waste hydrogen discharge. The method of multiple-level resource Pinch Analysis is extended to the level of Total Site Hydrogen Integration by considering fresh hydrogen sources with various quality. Waste hydrogen after Total Site Integration is further regenerated. The technical feasibility and economy of the various purification approaches are considered, demonstrated with a case study of a refinery hydrogen network in a petrochemical industrial park. The results showed that fresh hydrogen usage and waste hydrogen discharge could be reduced by 21.3% and 67.6%. The hydrogen recovery ratio is 95.2%. It has significant economic benefits and a short payback period for Total Site Hydrogen Integration with waste hydrogen purification. The proposed method facilitates the reuse of waste hydrogen before the purification process that incurs an additional environmental footprint. In line with the Circular Economy principles, hydrogen resource is retained in the system as long as possible before discharge.     

结合优化支持向量机与K-means++的工控系统入侵检测方法

针对工业控制系统传统单一检测算法模型对不同攻击类型检测率和检测速度不佳的问题，提出一种优化支持向量机和K-means++算法结合的入侵检测模型。首先利用主成分分析法（PCA）对原始数据集进行预处理，消除其相关性；其次在粒子群优化（PSO）算法的基础上加入自适应变异过程避免在训练的过程中陷入局部最优解；然后利用自适应变异粒子群优化（AMPSO）算法优化支持向量机的核函数和惩罚参数；最后利用密度中心法改进K-means算法与优化后的支持向量机组合成入侵检测模型，从而实现工业控制系统的异常检测。实验结果表明，所提方法在检测速度和对各类攻击的检测率上得到明显提升。     

基于模式间混淆关系自适应构建层次化分类器

为了解决层次化分类器的设计难点——子分类器的层属关系及其内部组成的确定,本文首先定义了模式间混淆关系,用于描述不同模式在判决域中的相互作用;进而提出了基于混淆矩阵度量模式间混淆关系的方法。设计并实现了多模式混淆关系分析机MPCRAM,将有师指派和无师自组两种常用的模式重组方法有机结合,遵循Fisher准则,自适应地产生层次化分类器结构。大量综合测试证实了该方法有效、实用,可显著提高分类器的识别性能和稳健性。     

多带抗噪声语音识别算法研究

根据Flether等人的研究,基于感知独立性假设的子带识别方法被用于抗噪声鲁棒语音识别。本文拓展子带方法,采用基于噪声污染假定的多带框架来减少噪声影响。论文不仅从理论上分析了噪声污染假定多带框架在识别性能上的潜在优势,而且提出了多带环境下的鲁棒语音识别算法。研究表明：多带框架不仅回避了独立感知假设要求,而且与子带方法相比,多带方法能更好的减少噪声影响,提高系统识别性能。     

用人工神经网络作地质数据分析

本文提出了利用人工神经网络进行地质数据多变量分析的方法，研究表明，此方法具有精度高、运算速度快、算法简单易于编程等显著特点，是地质数据分析中一有效方法。     

双极关键工艺的在线统计分析

采用了双极晶体管作为双极工艺的测试结构,将在线工艺的统计分析理论应用于双极工艺,研制了双极工艺的统计分析软件。最后给出了双极工艺的某些分析结果。     

一起罕见的粗氩充装爆炸事故

对一起粗氩 充装设备发生爆炸事故进行了现场介绍、原因分析，找出了导致事故的主因，并提出了防范措施．     

低渗透率地层渗透率的确定方法

结合大庆油田外围低渗透率地层的地质特点,根椐渗流理论和岩心分析资料,分析了地层渗透率与孔隙度、组成地层的各种矿物含量以及泥质含量之间的关系,建立了不同矿物组合地层的渗透率计算方程。用本方法计算的和岩心分析的渗透率进行了对比,二者之间具有较好的一致性。