AT91SAM7S64芯片I2C(TWI)接口应用开发

较为详细地介绍AT91SAM7S64芯片的I2C接口控制器中外围数据控制器(PDC)的使用方式,并将其与AT24C04之间的通信作为实例给出完整的应用开发流程和软硬件详细描述。该方法的可行性已经为工程实践和实际产品所证实。该操作也可推广到其他AT91SAM7S系列ARM处理器与其他I2C接口器件间的通信。并对其他拥有外围数据控制器的接口开发有一定的借鉴意义。     

From Natural Methylation to Versatile Alkylations Using Halide Methyltransferases

Halide methyltransferases (HMTs) enable the enzymatic synthesis of S-adenosyl-l -methionine (SAM) from S-adenosyl-l -homocysteine (SAH) and methyl iodide. Characterisation of a range of naturally occurring HMTs and subsequent protein engineering led to HMT variants capable of synthesising ethyl, propyl, and allyl analogues of SAM. Notably, HMTs do not depend on chemical synthesis of methionine analogues, as required by methionine adenosyltransferases (MATs). However, at the moment MATs have a much broader substrate scope than the HMTs. Herein we provide an overview of the discovery and engineering of promiscuous HMTs and how these strategies will pave the way towards a toolbox of HMT variants for versatile chemo- and regioselective biocatalytic alkylations.     

基于ARM的便携式电机参数实时监测仪设计

针对三相电机参数监测问题,基于AT91SAM9261微处理器和嵌入式实时操作系统VxWorks,设计了一套便携式电机参数监测仪。监测仪以ATT7022B电能测量芯片和鉴相计数单元为核心,对三相电机的工作电压、电流及电机的转速转向参数进行实时监测与故障报警,并能在联网模式下通过以太网与上层监控主机通信,实现远程参数监测和多电机联网测量,保证系统安全的同时方便了伺服系统调试。     

利用SPR生物传感器检测缺血修饰白蛋白

缺血修饰白蛋白(IMA)的检测对心肌缺血的早期诊断和治疗具有重要意义。利用纳米金颗粒和混合巯基自组装于金膜表面上,研制了一种快速检测IMA的表面等离子体共振(SPR)生物传感器。同时比较了直接法和抑制法的检测下限。结果表明:直接检测法可以检测到393ng/L的IMA,而抑制检测法检测限小于5.0 ng/L。与现有的IMA检测方法相比,SPR生物传感器具有特异性好、检测下限低以及检测耗时短等优点。     

Protoporphyrin-modified gold surfaces for the selective monitoring of catecholamines

Protoporphyrin IX (PPIX) was immobilized on Au surfaces for the electrochemical oxidation of dopamine (DA) and epinephrine (EP). Two procedures for the immobilization were employed. One class of modified electrodes was prepared by immobilizing the PPIX into polypyrrole (PPy) films synthesized by anodic electropolymerization. The other procedure involved the immobilization of PPIX on an electrode modified by a 11-mercaptoundecanoic acid (MUA) self-assembled monolayer (SAM). The modified surfaces were characterized by cyclic voltammetry (CV).The efficiency of these modified surfaces for the electrochemical oxidation of DA and EP was investigated and compared. The peak potential for the oxidation of each analyte at the different electrode surfaces was determined by square-wave voltammetry (SWV).The dependence of the sensitivity of the electrodes for the detection of the catecholamines on the applied potential was also measured. The SAM-based electrodes showed better selectivity for detecting DA in the potential range between 0.2 and 0.4 V versus Pt (QRE). However, higher sensitivity and linearity were observed for the film-based electrodes.     

Adsorption of mercaptopropionic acid onto Au(1 1 1): Part II. Effect on copper electrodeposition

Copper deposition in the presence of an organic additive (3-mercaptopropionic acid, MPA) was studied by cyclic voltammetry and in situ scanning tunneling microscopy (STM) and the results are compared to those for additive-free solutions. It is shown that underpotential deposition (upd) of copper onto a fully MPA-covered electrode produces a defect-rich substrate, but the defects are blocked by the dense organic film for bulk deposition, resulting in a low number of nuclei. A grain-refining effect of MPA, however, was found, when Cu deposition was initiated shortly after addition of MPA to the solution, i.e., for a low-coverage MPA adlayer.     

利用扫描声学显微镜对金属-陶瓷复合涂层亚表层相分布的研究

利用声学显微技术这一无损检测手段对等离子喷涂的金属－陶瓷复合涂层进行了亚表层显微结构的观察，通过分析涂层材料的声波信号，得出了金属相和陶瓷相分布区域的结论，并为涂层表面的背散射电子像和断面的金相观察等手段所证实。     

Au-Ni-Kovar合金系统基底元素表面偏聚的SAM和XPS研究SCIEI

本文采用SAM和XPS对实用Au-Ni-Kovar合金系统热处理样品(250—350℃,0.5—1.5h)进行了基底元素穿透Au层的表面偏聚研究,给出了这一复杂系统中Ni,Co表面偏聚机理的直观证据,即Ni,Co主要是通过晶界扩散穿透Au层而后以表面扩散覆盖镀Au表面的;表面偏聚元素化学态的研究则不仅表明,氧的吸附和氧化反应是Ni,Co表面偏聚的驱动力,而且发现,上述偏聚会引起样品表面吸水的现象。     

基于Hyperion数据的铜矿信息直接和间接提取方法研究

针对不同的地表覆盖条件,研究基于Hyperion星载高光谱数据的砂页岩型铜矿信息提取方法。首先对Hyperion L1级数据进行波段筛选、坏线修复、大气纠正和几何纠正等预处理,然后分别针对不同的植被覆盖情况使用不同的信息提取方法。在岩石裸露区,直接使用光谱角制图法;在植被覆盖区,使用铜金属离子的积累导致的植被生理异常作为间接标志来识别铜矿信息,生理异常使用高光谱植被指数来计算。结果表明,综合使用这两种方法的互补信息能够便于提取复杂地表覆盖情况下的铜矿信息。     

基于蓝牙的公交自动报站系统的设计与实现

将ARM技术与蓝牙技术相结合,设计了一款公交自动报站装置,阐述了ARM微处理器和蓝牙模块的硬件设计思想与软件实现方案.本系统通信稳定,抗干扰能力强.可在公交系统中广泛使用,有效提高乘车安全与舒适性.