Preparation of high-activity coal char-based catalysts from high metals containing coal gangue and lignite for catalytic decomposition of biomass tar

The potential of using high metals containing coal gangue and lignite to prepare high-activity coal char-based catalysts is investigated for effective biomass tar decomposition. Loose structure and rough surface are formed for these char-based catalysts with heterogeneous distribution of a large number of inorganic particles. In the biomass tar decomposition, the performance of the coal char-based catalysts is significantly influenced by the content of the metals in the raw materials and coal gangue char (GC) with the ash content as high as 50.80% exhibits the highest activity in this work. A high biomass tar conversion efficiency of 93.5% is achieved at 800 °C along with a significant increase in the fuel gas product. During the five-time consecutive tests, the catalytic performance of GC increases a little at the second or third times reuse and remains relatively stable, showing the remarkable stability of the catalyst in biomass tar decomposition applications.     

Preparation and characterization of mullite whisker reinforced ceramics made from coal fly ash

Ceramics with mullite whiskers were prepared from coal fly ash and Al₂O₃ raw materials, with AlF₃ used as an additive. The phase structures and microstructures of the ceramics were identified via X-ray diffraction and scanning electron microscopy, respectively. The results show that pickling of coal fly ash is an effective method for enhancing the flexural strength of ceramics. Sintering temperature and AlF₃ addition were also key factors influencing the creation of ideal ceramics. The ceramic made from pickled coal fly ash, 6?wt% AlF₃, and sintered at 1200?°C, exhibited the highest flexural strength of 59.1?MPa, and had a bulk density of 1.32?g/cm³ and porosity of 26.8%. The results show that ceramic materials made under these conditions are ideal candidates for manufacturing ceramic proppants for the exploitation of unconventional oil and gas resources.     

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我国是煤资源大国，长期来在采煤的同时，抽放排空大量煤层瓦斯，不仅浪费大量资源，还严重污染大气。利用煤层瓦斯发电是解决煤层瓦斯放空的重要途径 。文章介绍一种全新的有别于传统 发动机的瓦斯内燃机空燃自动混合控制装置，其中包括：煤层瓦斯的理化特性、装置的结构、工作原理及工作过程，阐述了结构参数对发动机性能的影响。经过在中心瓦斯工区内燃发动机组群上安装试运行，结果表明：该装置可以适用于高、中、低不同浓度的煤层瓦斯，性能稳定、可靠，达到了设计性能指标，完全满足燃气,内燃机组的使用要求，并取得了很好的经济效益、生态效益和环保效益。     

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2002年AAPG年会于3月10－13日在美国休斯顿隆重召开。根据会议论文，介绍了国外天然气勘探与研究最新进展及发展趋势，其中包括：生物气、海域及深水区有利含气区带、际上新老气区带等常规天然气，以及煤层气、深盆气、天然气水合物等非常规天然气的最新勘探与研究进展。     

Synthesis, Characterization, and Formation Process of Na-X Zeolite from Coal Fly Ash

Using the SiO₂ and Al₂O₃ components of the amorphous phase in coal fly ash (Fa), Fa was converted to Na-X zeolites in NaOH-NaAlO₂ solutions by stirring at 35°C for 72 hr and then aging at 85°C for a given period. The molar ratio SiO₂/Al₂O₃ of the starting materials was controlled from 2.0 to 13.2. The resulting materials were characterized by various means. Increasing the SiO₂/Al₂O₃ ratio of the starting material increased the degree of crystallinity of faujasite, exhibiting a maximum at SiO₂/Al₂O₃ = 8.0. The faujasite formed was identified as Na-X zeolite with Si/Al = 1.20. The amorphous phase in Fa was dissolved during the stirring to form a precursor of zeolite, such as amorphous aluminosilicate. The Na-X zeolite was formed by aging for 24 hr, and the degree of crystallinity of this material was increased with the increasing aging period. The cation exchange capacity and specific surface area were increased with the increasing degree of crystallinity of the Na-X zeolites.     

Investigations of water inrushes from aquifers under coal seams

In many coal mines, limestone-confined aquifers underlie coal seams. During coal extraction from these mines, water inrushes occur frequently with disastrous consequences. This paper introduces the hydrogeological conditions of the coal mines and the potential water inrush disasters from aquifers under coal seams. It then presents the water inrush mechanism. The main factors which control water inrushes include strata pressure, mining size, geologic structures and the water pressure in the underlying aquifer. Analysis shows that reduction of confinement due to mining is the major cause of the water-conducting failure in the floor strata. The depth of the failure zone is strongly dependent on the mining width. This paper also presents field observation results of the water-conducting failure in the floor strata, and applies the finite element method coupled with stress-dependent permeability to analyze hydraulic conductivity enhancement due to coal extraction. Finally, theoretical and empirical methods to predict water inrushes are given, and technical measures for improving mine design and safety for coal extraction over aquifers are presented. These measures include fault and fracture grouting and mining method modification such as changing long-wall to short-wall mining.     

煤系高岭土制备裂化催化剂的探索性研究

从石嘴山煤系高岭土的分析测实,经过改性处理,实验后得出具有碱改性条件,且制备裂化催化剂后重油转化能力有明显提高,开拓了煤系高岭土在石化领域的应用。     

Apparent versus true density for the volume-to-weight transformation in coal blends

This work reviews the procedures involved in the conversion of the petrographic characterization data of blended coals into weight percentages of the single coals in the blends, the selection of the most suitable parameter for describing the density of the coals being critical. First, the fundamentals of the volume-to-weight transformation of the petrographic data were developed by means of mathematical formulae. This part of the procedure highlighted the need to use a density value adapted to the resolving power of the optical microscope. It was found that mercury penetration at 5 MPa, as determined by mercury porosimetry, was best suited for this purpose. A literature survey of published coal density data revealed that the use of correlations between coal density and rank was not an accurate enough procedure to deal with the relatively low corrections involved in the transformation of petrographic data. In the end, three binary blends were prepared from six carefully selected coals and polished particulate blocks of these blends were petrographically analysed to determine their compositions on a volume per cent basis. The best fit of these volume percentages with the weight percentages used in the formulation of the blends was found for a density correction based on mercury penetration at 5 MPa, in agreement with the empirical analysis.     

6m焦炉投产初期的热工管理

简要介绍焦化厂6m焦炉投产一年多以来的生产现状，整改措施和焦炉热工管理。