Preparation, patterning and luminescent properties of nanocrystalline Gd2O3:A (A=Eu, Dy, Sm, Er) phosphor films via Pechini sol–gel soft lithography

Nanocrystalline Gd₂O₃:A (A=Eu³⁺, Dy³⁺, Sm³⁺, Er³⁺) phosphor films and their patterning were fabricated by a Pechini sol–gel process combined with a soft lithography. X-ray diffraction (XRD), atomic force microscopy (AFM), scanning electron microscopy (SEM) and optical microscopy, UV/vis transmission and photoluminescence (PL) spectra as well as lifetimes were used to characterize the resulting films. The results of XRD indicated that the films began to crystallize at 500 °C and that the crystallinity increased with the elevation of annealing temperatures. Uniform and crack free non-patterned phosphor films were obtained by optimizing the composition of the coating sol, which mainly consisted of grains with an average size of 70 nm and a thickness of 550 nm. Using micro-molding in capillaries technique, we obtained homogeneous and defects-free patterned gel and crystalline phosphor films with different stripe widths (5, 10, 20 and 50 μm). Significant shrinkage (50%) was observed in the patterned films during the heat treatment process. The doped rare earth ions (A) showed their characteristic emission in crystalline Gd₂O₃ phosphor films due to an efficient energy transfer from Gd₂O₃ host to them. Both the lifetimes and PL intensity of the rare earth ions increased with increasing the annealing temperature from 500 to 900 °C, and the optimum concentrations for Eu³⁺, Dy³⁺, Sm³⁺, Er³⁺ were determined to be 5, 0.25, 1 and 1.5 mol% of Gd³⁺ in Gd₂O₃ films, respectively.     

无钴黑色陶瓷颜料中铬含量测定的新方法

本文以盐酸羟胺作还原剂,研究了三价铬与二甲酚橙的显色反应,结果发现Cr3 在0～80滋g/50ml范围内,其吸光度与Cr3 含量成正比相关,用于无钴黑色陶瓷颜料中铬含量的测定,作出了回归方程,且进行了显著性检验,获得了理想的结果。     

Physico-chemical properties of ceramic pigments for high-temperature application

Heat resistant coatings are required primarily for stacks, exhaust pipes, reactors, space crafts and similar equipments that are permanently or occasionally exposed to elevated temperatures. High-temperature coatings are generally based on silicone resin with ceramic and metallic pigments. In this study, iron oxide, cobalt oxide (thermo chromic compound) and aluminum oxide are used for the preparation of four new types of coloured pigments. The thermal resistant characteristics of these ceramic pigments were studied by differential thermal analysis, thermo gravimetric analysis and differential scanning calorimetric analysis. These ceramic pigments are found to be thermally stable up to 400 °C.     

Effective factors on synthesis of the hematite–silica red inclusion pigment

The work focuses on the synthesis of a red ceramic pigment by inclusion of hematite in a fumed silica matrix with different specific surface areas. Iron(II) sulfate was used as hematite precursor. Mixtures of iron(II) sulfate and fumed silica with different mole ratios were heated at different temperatures from 1000 to 1300 °C for 4 h.     

稀土棕红色陶瓷颜料的制备

在低温下,采用溶胶均匀共沉淀法合成了含少量稀土氧化物CeO2的棕色陶瓷颜料,并应用颜色测定、SEM及XRD分析等手段对颜料的颜色、粒度及结晶构造进行了表征。同时,将合成的颜料应用于陶瓷釉料中,表明该颜料可以应用于1320℃的高温环境下。     

退火损伤对Er注入GaAs和Yb注入InP发光的影响

本文报道了CaAs∶Er、InP∶Yb发光样品的二次离子质谱、X-射线双晶衍射测量结果及其与Er离子的表面成份的关系.分析讨论了退火损伤对GaAs∶Er和InP∶Yb发光的影响以及Er~(3+)复合体发光中心模型.     

GaAlInP发光材料计算的经验公式

根据已经发表的实验数据，针对镓铝铟磷发光材料的提出了一组经验公式及相应的曲线，作为ＧａＡｌＩｎＰ可见光材料设计的依据或参考。     

紫草色素的研究

紫草色素原植物系紫草科Broaginaceae几种植物的根，又称紫根色素。该研究首次用人工栽培的硬紫草(Lithospermum erythrohizon Sieb.)的根，作了加工工艺和特性的研究。产品得率近1％，色价E 1^1Q5nm达150以，卫生指标符合有关规定，是种理想的脂溶性红色素。     

着色型珠光颜料涂布纸的研制

本文论述了着色型珠光颜料涂布纸的研制工作，并对影响珠光涂料制备的几个因素进行探讨．优化结果表明，瓷土０～３０％，珠光颜料７０％～１００％，胶粘剂２５％～３０％，固含量２３％～２５％，涂布量１０～１５ｇ／ｍ２时，其纸面呈现强烈的珠光光泽，适用于胶印．     

苯乙烯-马来酸酐(SMA)共聚物对颜料的分散及其在喷墨印花中的应用

介绍了苯乙烯-马来酸酐（SMA）共聚物的合成方法和分散性能。探讨了它对颜料分散的机理、影响分散性能的主要因素，以及在喷墨印花中的应用前景作了展望。