全文获取类型
收费全文 | 8417篇 |
免费 | 573篇 |
国内免费 | 135篇 |
学科分类
工业技术 | 9125篇 |
出版年
2024年 | 2篇 |
2023年 | 76篇 |
2022年 | 181篇 |
2021年 | 242篇 |
2020年 | 324篇 |
2019年 | 268篇 |
2018年 | 231篇 |
2017年 | 193篇 |
2016年 | 242篇 |
2015年 | 229篇 |
2014年 | 469篇 |
2013年 | 500篇 |
2012年 | 524篇 |
2011年 | 708篇 |
2010年 | 538篇 |
2009年 | 477篇 |
2008年 | 382篇 |
2007年 | 513篇 |
2006年 | 419篇 |
2005年 | 388篇 |
2004年 | 349篇 |
2003年 | 330篇 |
2002年 | 210篇 |
2001年 | 169篇 |
2000年 | 175篇 |
1999年 | 150篇 |
1998年 | 148篇 |
1997年 | 116篇 |
1996年 | 91篇 |
1995年 | 74篇 |
1994年 | 82篇 |
1993年 | 40篇 |
1992年 | 35篇 |
1991年 | 24篇 |
1990年 | 20篇 |
1989年 | 12篇 |
1988年 | 16篇 |
1987年 | 23篇 |
1986年 | 16篇 |
1985年 | 34篇 |
1984年 | 30篇 |
1983年 | 42篇 |
1982年 | 11篇 |
1981年 | 2篇 |
1980年 | 8篇 |
1979年 | 2篇 |
1978年 | 1篇 |
1977年 | 2篇 |
1976年 | 1篇 |
1951年 | 6篇 |
排序方式: 共有9125条查询结果,搜索用时 15 毫秒
1.
Shilin Du Yichen Dong Feiqiang Guo Beile Tian Songbo Mao Lin Qian Chengyun Xin 《International Journal of Hydrogen Energy》2021,46(27):14138-14147
The potential of using high metals containing coal gangue and lignite to prepare high-activity coal char-based catalysts is investigated for effective biomass tar decomposition. Loose structure and rough surface are formed for these char-based catalysts with heterogeneous distribution of a large number of inorganic particles. In the biomass tar decomposition, the performance of the coal char-based catalysts is significantly influenced by the content of the metals in the raw materials and coal gangue char (GC) with the ash content as high as 50.80% exhibits the highest activity in this work. A high biomass tar conversion efficiency of 93.5% is achieved at 800 °C along with a significant increase in the fuel gas product. During the five-time consecutive tests, the catalytic performance of GC increases a little at the second or third times reuse and remains relatively stable, showing the remarkable stability of the catalyst in biomass tar decomposition applications. 相似文献
2.
《International Journal of Hydrogen Energy》2022,47(14):8716-8728
In this study, lignin was gasified in supercritical water with catalysis of CuO–ZnO synthesized by deposition precipitation, co-precipitation and sol-gel methods. Sol-gel synthesized CuO–ZnO showed the highest catalytic performance, and the gasification efficiency was increased by 37.92% with it. The XRD, SEM-EDS and N2 adsorption/desorption analysis showed that the priority of the sol-gel catalyst was the smallest crystallite size, largest specific surface area and high dispersion. For sol-gel synthesized CuO–ZnO, the increase of CuO/ZnO ratio improved the gasification efficiency but reduced H2 selectivity. And the catalytic activity was reduced with the calcination temperature above 600 °C due to enlarged crystallites and reduced pores. During sol-gel preparation, both the addition of ethanol and PEG in the solvent reduced the agglomeration and improved the catalytic activity. With CuO–ZnO prepared with 1 g PEG + water as the solvent, the highest H2 yield of 6.86 mol/kg was obtained, which was over 1.5 times of that without catalyst. 相似文献
3.
《International Journal of Hydrogen Energy》2022,47(74):31833-31842
Biomass gasification technology under microwave irradiation is a new and novel method, and the energy conversion performances during the process play a guiding role in improving the energy conversion efficiencies and developing the gasification simulation models. In order to improve the energy utilization efficiency of microwave biomass gasification system, this study investigated and presented the energy conversion performances during biomass gasification process under microwave irradiation, and these were materialized through detailing (a) the energy conversion performance in the microwave heating stage, and (b) the energy conversion performance in the microwave assisted biomass gasification stage. Different forms of energies in the biomass microwave gasification process were calculated by the method given in this study based on the experimental data. The results showed that the useful energy (energy in silicon carbide (SiC), 18.73 kJ) accounted for 31.22% of the total energy input (electrical energy, 60.00 kJ) in the heating stage, and the useful energy (energy in the products, 758.55 kJ) accounted for 63.41% of the total energy input (electrical and biomass energy, 1196.28 kJ) in the gasification stage. During the whole biomass gasification process under microwave irradiation, the useful energy output (energy in the products, 758.55 kJ) accounted for 60.38% of the total energy input (electrical and biomass energy, 1256.28 kJ), and the energy in the gas (523.40 kJ) product played a dominate role in product energy (758.55 kJ). The energy loss mainly included the heat loss in the gas flow (89.20 kJ), magnetron loss (191.80 kJ) and microwave dissipation loss (198.00 kJ), which accounted for 7.10%, 15.27% and 15.76% of the total energy, respectively. The contents detailed in this study not only presented the energy conversion performances during microwave assisted gasification process but also supplied important data for developing gasification simulation models. 相似文献
4.
Chaoxin Li Yi Zhou Yuming Tian Yuanyuan Zhao Kaiyue Wang Guomin Li Yuesheng Chai 《Ceramics International》2019,45(5):5613-5616
Ceramics with mullite whiskers were prepared from coal fly ash and Al2O3 raw materials, with AlF3 used as an additive. The phase structures and microstructures of the ceramics were identified via X-ray diffraction and scanning electron microscopy, respectively. The results show that pickling of coal fly ash is an effective method for enhancing the flexural strength of ceramics. Sintering temperature and AlF3 addition were also key factors influencing the creation of ideal ceramics. The ceramic made from pickled coal fly ash, 6?wt% AlF3, and sintered at 1200?°C, exhibited the highest flexural strength of 59.1?MPa, and had a bulk density of 1.32?g/cm3 and porosity of 26.8%. The results show that ceramic materials made under these conditions are ideal candidates for manufacturing ceramic proppants for the exploitation of unconventional oil and gas resources. 相似文献
5.
6.
《International Journal of Hydrogen Energy》2020,45(7):4793-4803
As an industrial pollutant, tar derived from biomass gasification is used as the precursor for fabricating a novel carbon-metal hydroxides composite electrode. A slurry (the mixture of tar, KOH and melamine) is daubed uniformly onto the nickel foam, which is directly carbonized to form NPC@LDH electrode material. This electrode is further coated with NiCo-LDH nanosheets using an electrodeposition method to form NF@NPC@LDH. The newly made NF@NPC@LDH electrode exhibits a high specific capacity of 9.6 F cm−2 at a current density of 2 mA cm−2 and good rate performance (55.3% retention). Furthermore, a hybrid NF@NPC@LDH//NF@PC all-solid-state supercapacitor is fabricated, and the device exhibits high energy density of 1.28 mWh cm−3 at a power density of 8.04 mW cm−3, low resistance and good cycling stability. 相似文献
7.
һ����ӱ����˹����ȼ����ȼ�Զ���Ͽ���װ�� 总被引:1,自引:0,他引:1
我国是煤资源大国,长期来在采煤的同时,抽放排空大量煤层瓦斯,不仅浪费大量资源,还严重污染大气。利用煤层瓦斯发电是解决煤层瓦斯放空的重要途径 。文章介绍一种全新的有别于传统 发动机的瓦斯内燃机空燃自动混合控制装置,其中包括:煤层瓦斯的理化特性、装置的结构、工作原理及工作过程,阐述了结构参数对发动机性能的影响。经过在中心瓦斯工区内燃发动机组群上安装试运行,结果表明:该装置可以适用于高、中、低不同浓度的煤层瓦斯,性能稳定、可靠,达到了设计性能指标,完全满足燃气,内燃机组的使用要求,并取得了很好的经济效益、生态效益和环保效益。 相似文献
8.
壳牌煤气化工艺在荷兰德姆科列克IGCC工厂的应用 总被引:3,自引:0,他引:3
介绍采用壳牌煤气化工艺的荷兰德姆科列克250MW整体煤气化烧气--蒸汽联合循环发电厂的建厂过程及运行经验。阐述了IGCC能量平衡原理、SCGP系统流程和运行操作指标,对壳牌煤气化装置的优良性能和发展前景进行了总结和展望。 相似文献
9.
10.
Using the SiO2 and Al2O3 components of the amorphous phase in coal fly ash (Fa), Fa was converted to Na-X zeolites in NaOH-NaAlO2 solutions by stirring at 35°C for 72 hr and then aging at 85°C for a given period. The molar ratio SiO2/Al2O3 of the starting materials was controlled from 2.0 to 13.2. The resulting materials were characterized by various means. Increasing the SiO2/Al2O3 ratio of the starting material increased the degree of crystallinity of faujasite, exhibiting a maximum at SiO2/Al2O3 = 8.0. The faujasite formed was identified as Na-X zeolite with Si/Al = 1.20. The amorphous phase in Fa was dissolved during the stirring to form a precursor of zeolite, such as amorphous aluminosilicate. The Na-X zeolite was formed by aging for 24 hr, and the degree of crystallinity of this material was increased with the increasing aging period. The cation exchange capacity and specific surface area were increased with the increasing degree of crystallinity of the Na-X zeolites. 相似文献