全文获取类型
收费全文 | 33565篇 |
免费 | 5911篇 |
国内免费 | 4943篇 |
学科分类
数理化 | 44419篇 |
出版年
2024年 | 34篇 |
2023年 | 625篇 |
2022年 | 803篇 |
2021年 | 1124篇 |
2020年 | 1420篇 |
2019年 | 1513篇 |
2018年 | 1255篇 |
2017年 | 1263篇 |
2016年 | 1690篇 |
2015年 | 1713篇 |
2014年 | 2138篇 |
2013年 | 2658篇 |
2012年 | 3206篇 |
2011年 | 3301篇 |
2010年 | 2509篇 |
2009年 | 2313篇 |
2008年 | 2490篇 |
2007年 | 2305篇 |
2006年 | 2094篇 |
2005年 | 1658篇 |
2004年 | 1205篇 |
2003年 | 994篇 |
2002年 | 948篇 |
2001年 | 850篇 |
2000年 | 673篇 |
1999年 | 630篇 |
1998年 | 451篇 |
1997年 | 368篇 |
1996年 | 315篇 |
1995年 | 303篇 |
1994年 | 285篇 |
1993年 | 222篇 |
1992年 | 187篇 |
1991年 | 182篇 |
1990年 | 161篇 |
1989年 | 121篇 |
1988年 | 93篇 |
1987年 | 69篇 |
1986年 | 72篇 |
1985年 | 56篇 |
1984年 | 24篇 |
1983年 | 25篇 |
1982年 | 21篇 |
1981年 | 8篇 |
1980年 | 8篇 |
1979年 | 9篇 |
1971年 | 4篇 |
1959年 | 3篇 |
1957年 | 4篇 |
1936年 | 5篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
2.
Science China Mathematics - This paper studies exact synchronization and asymptotic synchronization problems for a controlled linear system of ordinary differential equations. In this paper, we... 相似文献
3.
Hu Duo-Duo Gao Qian Dai Jing-Cheng Cui Ru Li Yuan-Bo Li Yuan-Ming Zhou Xiao-Guo Bian Kang-Jie Wu Bing-Bing Zhang Kai-Fan Wang Xi-Sheng Li Yan 《中国科学:化学(英文版)》2022,65(4):753-761
Science China Chemistry - A light-induced, nickel-catalyzed three-component arylsulfonation of 1,3-enynes in the absence of photocatalyst is reported. This methodology exhibited mild conditions,... 相似文献
5.
Zhi Sun Mengfan Zhao Lihua Zuo Shengnan Zhou Feng Fan Qingquan Jia Lianping Xue Hanbing Li Jian Kang Xiaojian Zhang 《Journal of separation science》2022,45(2):518-528
Juglandis Mandshuricae Cortex is the bark of Juglans mandshurica Maxim., which has been used as a folk medicine plant in China and India. In this study, an ultra-high performance liquid chromatography–quadrupole/orbitrap high-resolution mass spectrometry method was developed to clarify and quantify the chemical profiling of Juglandis Mandshuricae Cortex rapidly. A total of 113 compounds were characterized. Among them, seven flavonoids were simultaneously quantified in 15 min, including myricetin, myricetrin, taxifolin, kaempferol, quercetin, quercitrin, and naringenin. The method was validated for accuracy, precision, and the limits of detection and quantification. All calibration curves showed a good linear relationship (r > 0.9990) within test ranges. The intra- and inter-day relative standard deviations were less than 2.16%. Accuracy validation showed that the recovery was between 95.6 and 101.3% with relative standard deviation values below 2.85%. The validated method was successfully applied to determine the contents of seven flavones in Juglandis Mandshuricae Cortex from seven sources and the contents of these places were calculated respectively. This method provides a theoretical basis for further developing the medicinal value of Juglandis Mandshuricae Cortex. 相似文献
6.
Given a graph sequence denote by T3(Gn) the number of monochromatic triangles in a uniformly random coloring of the vertices of Gn with colors. In this paper we prove a central limit theorem (CLT) for T3(Gn) with explicit error rates, using a quantitative version of the martingale CLT. We then relate this error term to the well-known fourth-moment phenomenon, which, interestingly, holds only when the number of colors satisfies . We also show that the convergence of the fourth moment is necessary to obtain a Gaussian limit for any , which, together with the above result, implies that the fourth-moment condition characterizes the limiting normal distribution of T3(Gn), whenever . Finally, to illustrate the promise of our approach, we include an alternative proof of the CLT for the number of monochromatic edges, which provides quantitative rates for the results obtained in [7]. 相似文献
7.
Thermoelectric(TE)energy harvesting can effectively convert waste heat into electricity,which is a crucial technology to solve energy concerns.As a promising candidate for energy conversion,poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate)(PEDOT:PSS)has gained significant attention owing to its easy doping,high transparency,and solution processability.However,the TE performance of PEDOT:PSS still needs to be further enhanced.Herein,different approaches have been applied for tuning the TE properties:(i)direct dipping PEDOT:PSS thin films in ionic liquid;(ii)post-treatment of the films with concentrated sulfuric acid(H2SO4),and then dipping in ionic liquid.Besides,the same bis(trifluoromethanesulfonyl)amide(TFSI)anion and different cation salts,including 1-ethyl-3-methylimidazolium(EMIM+)and lithium(Li+),are selected to study the influence of varying cation types on the TE properties of PEDOT:PSS.The Seebeck coefficient and electrical conductivity of the PEDOT:PSS film treated with H2SO4EMIM:TFSI increase simultaneously,and the resulting maximum power factor is 46.7μW·m-1·K-2,which may be attributed to the ionic liquid facilitating the rearrangement of the molecular chain of PEDOT.The work provides a reference for the development of organic films with high TE properties. 相似文献
8.
In this paper,we investigate the non-autonomous Hamilton-Jacobi equation ■ where H is 1-periodic with respect to t and M is a compact Riemannian manifold without boundary.We obtain the viscosity solution denoted by T_(t_0)~tφ(x) and show T_(t_0)~tφ(x) converges uniformly to a time-periodic viscosity solution u~*(x,t) of ?_tu+H(t,x,?_xu,u)=0. 相似文献
9.
Applied Mathematics and Mechanics - A consequence of nonlinearities is a multi-harmonic response via a mono-harmonic excitation. A similar phenomenon also exists in random vibration. The power... 相似文献
10.
First-principles study of the co-effect of carbon doping and oxygen vacancies in ZnO photocatalyst 下载免费PDF全文
Although tuning band structure of optoelectronic semiconductor-based materials by means of doping single defect is an important approach for potential photocatalysis application,C-doping or oxygen vacancy(Vo)as a single defect in ZnO still has limitations for photocatalytic activity.Meanwhile,the influence of co-existence of various defects in ZnO still lacks sufficient studies.Therefore,we investigate the photocatalytic properties of ZnOx C0.0625(x=0.9375,0.875,0.8125),confirming that the co-effect of various defects has a greater enhancement for photocatalytic activity driven by visible-light than the single defect in ZnO.To clarify the underlying mechanism of co-existence of various defects in ZnO,we perform systematically the electronic properties calculations using density functional theory.It is found that the coeffect of C-doping and Vo in ZnO can achieve a more controllable band gap than doping solely in ZnO.Moreover,the impact of the effective masses of ZnOxC0.0625(x=0.9375,0.875,0.8125)is also taken into account.In comparison with heavy Vo concentrations,the light Vo concentration(x=0.875)as the optimal component together with C-doping in ZnO,can significantly improve the visible-light absorption and benefit photocatalytic activity. 相似文献