Fabrication and upconversion luminescence properties of Er:SrF2 transparent ceramics compared with Er:CaF2

SrF₂ transparent ceramic is a promising upconversion material due to the low phonon energy. The effect of different sintering temperatures on Er:SrF₂ transparent ceramics was investigated. The suitable sintering temperature for Er:SrF₂ transparent ceramics was 900 °C by hot-pressed sintering in this study. High quality of Er:SrF₂ transparent ceramics with different doping concentrations were obtained. The upconversion luminescence spectra and decay behavior were compared between Er:SrF₂ and Er:CaF₂ transparent ceramics with different Er³⁺ doping concentration. The green emission of 5 at.% Er:SrF₂ ceramic was much stronger than that of 5 at.% Er:CaF₂ ceramic, while the red emission of Er:SrF₂ ceramic was almost the same as that of Er:CaF₂ ceramic. The upconversion luminescence lifetime of Er:SrF₂ transparent ceramics was longer than that of Er:CaF₂.All the results indicated Er:SrF₂ transparent ceramics was a candidate for green fluorescent upconversion materials.     

四川某黏土矿中钪和钛的焙烧浸出试验研究

以四川某地含钪、钛、稀土黏土矿为研究对象,进行钠盐焙烧-酸浸、直接酸浸、硫酸化焙烧-水浸、空白焙烧-酸浸探索试验。结果表明,直接酸浸、空白焙烧-酸浸对钪和钛的回收效果均不好。硫酸化焙烧-水浸对钛的回收效果很好,但钪的浸出率较低。钠盐焙烧-酸浸试验结果表明,适宜的焙烧条件为:碳酸钠用量80%,焙烧温度800℃,焙烧时间1h；适宜的浸出条件为:10v.%硫酸,液固比20:1,浸出温度60℃,搅拌浸出时间2h；钪的浸出率为89.98%,钛的浸出率为80.55%。液固比对钪和钛的浸出率有显著影响,增大液固比可以暂时解决硅酸造成的过滤困难的问题。      

Preparation of epoxidized acrylonitrile butadiene rubber and its compatibilization effect on water-swellable rubber composites

In this research, water-swellable rubbers (WSRs) were prepared by the blending of acrylonitrile butadiene rubber (NBR) with epoxidized acrylonitrile butadiene rubber (ENBR), precipitated silica, vulcanizing agents, and polyacrylic acid sodium (PAAS) as superabsorbent polymers (SAPs). ENBR was prepared with a molybdenum trioxide catalyst and a tert-butyl hydroperoxide oxidant through a free-radical reaction under specific conditions and was used as a compatibilizer to improve the interfacial adhesion of the NBR matrix and hydrophilic components of the WSRs. Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy were used to analyze the structure and properties of ENBR. The dispersion of silica and SAPs in the rubber matrix was investigated by transmission electron microscopy. The presence of ENBR enhanced the water-absorption properties of the WSRs. The NBR–ENBR composites exhibited a higher mechanical performance after water absorption than that without ENBR. Both the swelling ratio and the absorption rate increased with the ENBR content. When the weight ratio of NBR–ENBR was 25/75, an equilibrium swelling ratio of 172% (13% higher than that of the sample without ENBR) was obtained. Scanning electron microscopy analysis revealed that the addition of ENBR improved the compatibility between the SAPs and the NBR matrix. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47694.     

大型原点反共振振动筛的初步设计

针对传统大型振动筛筛箱侧帮易断裂,参振质量大,隔振效果差等问题,提出了将反共振理论用于振动筛的设计理念,建立了反共振振动筛的力学模型,并进行动力学分析,得到筛箱和下质体稳态时的响应振幅,通过绘制双质体系统的幅频特性曲线得到反共振振动筛的激振频率。利用Solidworks软件对反共振振动筛进行三维建模,完成了大型原点反共振振动筛的初步设计。结果表明:可调激振器位置的斜面设计使激振力通过上质体质心,保证了筛箱的正常工作。由圆柱形螺旋弹簧组成的弹簧座连接上、下质体及地面,保证了系统所需弹性系数;通过应用PID控制技术监控上下质体振幅,并改变激振频率来稳定上、下质体振幅,实现原点反共振振动筛振幅的稳定性控制。     

考古遗址公园研究进展与趋势

有关考古遗址公园的研究理论和实践日趋成熟。利用文献统计方法,对中国考古遗址公园相关文献进行梳理,分析其发展脉络与动态,并通过热点主题词分析及相关文献综述,重点从理论发展、保护展示、规划、管理运营及使用评价5个方面阐述其研究趋势:理论发展表明考古遗址公园的名实问题关系到其准确定位及可持续发展;保护与展示应加强新技术、新理念的研究应用;规划应针对环境区位特点提出相应策略;管理要适应遗址旅游发展的需要;使用评价应建构系统的评价体系。最后提出研究展望。     

隔离病房隔离效果的研究(1)

从理论上分析总结了影响隔离效果的因素:压差、门的开关、人的进出、温差及缓冲室的设置。建立了实验用单床隔离病房和双床隔离病房,对三种送排风口方案及缓冲室的隔离效果进行了实验研究。指出压差不能抵消其他因素的影响;提出主流区和定向气流是保护医护人员的首要措施;证明床侧和床尾双送风口效果最好;提出用缓冲室稀释、自净、过滤在动态条件下外泄的污染物是最重要的动态隔离措施。     

寒冷地区蒸压加气混凝土砌块的施工

根据蒸压加气混凝土砌块的特性和新疆石河子地区的气候特征,对蒸压加气混凝土砌块墙体采取有针对性的构造和施工措施,有效解决了加气混凝土砌块应用中出现的裂缝问题。     

隔离病房回风高效过滤器滤菌效率的实验研究

介绍了国外各类高效过滤器的滤菌效率。在安装有高效过滤器的隔离病房回风口进行了发菌实验,计算了B类和C类回风高效过滤器的滤菌效率,证明了当隔离病房回风口安装高效过滤器时,可使用部分循环风。     

地下建筑专用全新风无级调载除湿机研制

分析了普通除湿机用于地下建筑全新风系统存在的问题,指出设计全新风除湿机要解决的关键问题,介绍了样机设计方案及测试结果。