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1.
With a sharp increase in the information volume, analyzing and retrieving this vast data volume is much more essential than ever. One of the main techniques that would be beneficial in this regard is called the Clustering method. Clustering aims to classify objects so that all objects within a cluster have similar features while other objects in different clusters are as distinct as possible. One of the most widely used clustering algorithms with the well and approved performance in different applications is the k-means algorithm. The main problem of the k-means algorithm is its performance which can be directly affected by the selection in the primary clusters. Lack of attention to this crucial issue has consequences such as creating empty clusters and decreasing the convergence time. Besides, the selection of appropriate initial seeds can reduce the cluster’s inconsistency. In this paper, we present a new method to determine the initial seeds of the k-mean algorithm to improve the accuracy and decrease the number of iterations of the algorithm. For this purpose, a new method is proposed considering the average distance between objects to determine the initial seeds. Our method attempts to provide a proper tradeoff between the accuracy and speed of the clustering algorithm. The experimental results showed that our proposed approach outperforms the Chithra with 1.7% and 2.1% in terms of clustering accuracy for Wine and Abalone detection data, respectively. Furthermore, achieved results indicate that comparing with the Reverse Nearest Neighbor (RNN) search approach, the proposed method has a higher convergence speed.  相似文献   
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The mechanical property is a crucial factor in the design of bone tissue engineering scaffolds. In the current study, novel PLLA (Poly-L-lactic acid)–Hydroxyapatite (HA)–yttria-stabilized zirconia (YSZ) nanocomposite scaffold with various compositions was prepared and characterized. The effect of HA and YSZ contents on the mechanical behavior of the resultant composites was investigated. TEM micrograph revealed that HA particles are needle-like in shape and nano in size. Scanning electron microscopy (SEM) micrograph also showed that YSZ powder is in granule form and submicron size. SEM disclosed that all scaffolds had a highly interconnected porous structure and X-ray diffractometry revealed that there were some molecular interactions between PLA (Polylactic acid), HA, and YSZ in the composites. The results depicted that introducing YSZ to the nanocomposite leads to a significant increase in compressive strength, modulus, and densification strain. In addition, flexural strength and modulus showed an upward trend by adding YSZ particles to scaffolds. It should be noted that PLA–20%HA–20%YSZ indicates the highest strength and modulus in both compression and bending tests, though, it did not demonstrate the proper strain compared to other scaffolds. Thus, PLA–15%HA–15%YSZ has been reported as the best candidate due to appropriate strength and strain. Also, energy absorption in nanocomposites showed an upward trend by increasing the amount of YSZ particles. It was found that the strength of samples was declined after being soaked in simulated body fluid. However, scaffolds with HA underwent more decrease in strength compared to samples containing YSZ.  相似文献   
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High-efficiency sound absorbing flexible polyurethane foams (FPUFs) are manufactured using nonpolar polyester resin, methylene diphenyl diisocyanate, and other reagents by one-shot bulk polymerization. In this study, the impact of the isocyanate index (90, 100, and 110) and water content (2.5 and 5%) on the microphase separation and soundproofing behavior of FPUFs are examined using atomic force microscopy, Fourier transform infrared spectroscopy, optical microscope, and an impedance tube device. The results reveal that the increase of the isocyanate index and water content leads to the increase of the cell size, cell size distribution, open-cell content, cell wall roughness, and microphase separation. Also, maximum sound absorption coefficient (α) reaches to 0.98 and the average of α in the frequency range of 1500–4000 Hz increases from 0.7 to 0.87 by increasing the water content from 2.5 to 5% and isocyanate index from 90 to 110; therefore, acoustic damping performance enhances up to 26.24% due to the synergic effects of microphase separation on the viscose media formation, open-cell content, cell wall roughness, cell size, and cell size distribution. In conclusion, FPUFs with an optimal amount of microphase separation and drainage flow can be a promising candidate for sound insulating materials. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47363.  相似文献   
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H2S removal from an off‐gas stream was performed in a spray column by H2S reactive absorption into a NaOH solution. The individual and interactive effects of three independent operating variables on the percentage of absorbed H2S were investigated: the initial pH of the scrubbing solution, the initial scrubbing solution temperature, and the volumetric liquid‐to‐gas ratio. The optimum operating variables were determined by response surface methodology (RSM) attaining a percentage of absorbed H2S of 98.7 ± 0.2 %. Additionally, the process performance was modeled by an artificial neural network (ANN) to predict the percentage of absorbed H2S. The results showed that the experimental data agreed better with the ANN model than with the RSM results.  相似文献   
7.
This research was conducted to evaluate the effects of cold atmospheric plasma treatment on the color of Hyssop (Hyssopus officinalis L.) and also to compare the usage of the spectrophotometer vs the color imaging instrumentation for the evaluation of the treatment on the color parameters. The experiments were investigated at different treatment times of 1, 5, and 10 minutes and the voltage values of 17, 20, and 23 kV. Possible changes of color were evaluated by using CIE L*a*b* values obtained with HunterLab colorimeter and CIE L*a*b* values obtained with a digital still camera (DSC) using digital image processing (MATLAB software). The values of L*, a*, and b* of the samples were obtained using both the methods. The results revealed that the L*, a*, and b* values of the treated Hyssop samples changed with increasing the treatment time and the voltage applied. Evaluating the interaction effects revealed that there was a significant difference in the (−a*/b* ) ratio. In addition, the results showed that the effects of all variables on the color parameters were significantly different in the case of the DSC using digital image processing. However, these effects were not significantly different using HunterLab colorimeter except for time variable and interaction effects of a* and (−a*/b* ) ratio. The lightest green color and the maximum chlorophyll content loss were observed for 23 kV applied over 10 minutes. Based on the results, the digital image processing can be used as a practical tool to study the variations at the color of dried Hyssop leaves after cold plasma treatment.  相似文献   
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A series of poly(carbazole‐quinoxaline‐amide)s (PCQAs) containing phenyl and long alkyl chain as pendants was synthesized from polycondensation between a new diamine with a synthesized and several commercial dicarboxylic acids using Yamazaki's method. PCQAs had inherent viscosities and weight average molecular weights ( ) in the range of 0.48–0.62 dL g?1 and 51,600–58,500 g mol?1, respectively. These luminescent polymers are readily soluble in a variety of organic solvents and formed low‐colored and tough thin films. In this study, silane modified SiO2 (mSiO2) nanoparticles were prepared, characterized and used with PCQAs in preparation of nanocomposites via solution blending method. The interfacial interaction strength between mSiO2 and the polymer–matrix enhanced thermal stability (T10%, from 463°C to 500°C) and mechanical strength (from 100 MPa to 150 MPa) for composite containing 30 wt % mSiO2 in comparison with the pure polyamide. These materials showed good ability for extraction–elimination of metal ions such as Cr6+, Cr3+, Co2+, Zn2+, Pb2+, Cd2+, and Hg2+ from aqueous solutions either individually or in the mixture at various pH. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 40219.  相似文献   
10.
Biomimetic [Fe(pyridoxinato)2OH·(H2O)3] non-hem complex designated as [Fe(L)2OH·(H2O)3] was synthesized with basic solution of pyridoxine (Vitamin B6) and FeCl3 in methanol under reflux condition. It was then immobilized within the Al-MCM-41. Characterizations were carried out by powder X-ray diffraction, nitrogen adsorption desorption, FTIR and UV–Vis spectroscopy. It was found that pore volume, surface area, and pore diameter of Al-MCM-41 decreases after immobilization of iron complex. Density functional theory studies confirmed the experimental results of [Fe(L)2OH·(H2O)3] complex. Fe-complex/Al-MCM-41 was found to successfully catalyze the oxidation of cyclohexane, cyclooctane and adamantane using H2O2 as oxidant with 45–90 % conversion toward the corresponding alcohols and ketones is considerable.  相似文献   
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