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The non-isothermal formation of Sc- and Zr-containing dispersoids in Al–Zr–Sc ternary alloys has been investigated by atom probe tomography (APT). In the early stages of precipitation, a high number density of Sc-rich clusters form. These clusters subsequently transform into Al3Sc particles with a L12 structure. When Zr diffusion becomes significant, Zr atoms are found to segregate to Al3Sc/α-Al matrix interfaces. Further annealing at 748 K gives rise to a duplex core/shell structure.  相似文献   
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The discrepancy between the classical grain growth law in high purity metals (grain size \( D \propto t^{1/2} \) ) and experimental measurements has long been a subject of debate. It is generally believed that a time growth exponent less than 1/2 is due to small amounts of impurity atoms in solid solution even in high purity metals. The present authors have recently developed a new approach to solute drag based on solute pinning of grain boundaries, which turns out to be mathematically simpler than the classic theory for solute drag. This new approach has been combined with a simple parametric law for the growth of the mean grain size to simulate the growth kinetics in dilute solid solution metals. Experimental grain growth curves in the cases of aluminum, iron, and lead containing small amounts of impurities have been well accounted for.  相似文献   
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A probabilistic model for the slowly varying horizontal motion of a moored floating structure, excited by nonlinear, second order wave forces is derived. The model consists of a coupled system of three white-noise excited stochastic differential equations that govern a continuous vector Markov process. Different methods are applied for the investigation of the first passage time probabilities of the displacement of the marine structure. The methods include time history simulation estimation of the first four moments, time history simulation of the first passage problem, and finite element solution of the backward Kolmogorov equation governing the first passage time distribution. The impact of non-Gaussian aspects of the response on extreme value statistics is demonstrated.  相似文献   
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Possible influences of tamoxifen and estradiol on in vitro radiation sensitivity and cellular receptor content after irradiation and/or tamoxifen treatment were studied in breast cancer cell lines; estrogen receptor (ER) and progesterone receptor (PgR) positive cell lines MCF-7 and MCF-7/TAM(R)-1 and the ER and PgR negative cell line MDA-MB-231. The tamoxifen resistant MCF-7/TAM(R)-1 cells were more resistant to ionizing radiation than the MCF-7 and MDA-MB-231 cells. Exposure to tamoxifen made the MCF-7 cells more radiation resistant, while estradiol made the MDA-MB-231 cells more radiation sensitive. A radiation dose of 6 Gy reduced the ER content in cytosol in both MCF-7 and MCF-7/TAM(R)-1 cells, but brought no alterations to the PgR content. In MCF-7/TAM(R)-1 cells tamoxifen exposure significantly increased the ER and reduced the PgR content, an effect not observed in the MCF-7 cells. To conclude, the present study indicates that irradiation and tamoxifen may modify the ER and PgR content in cytosol in breast cancer cells. Hormonal treatment may alter the radiation sensitivity, even in ER negative cells, suggesting that hormonal agents may act both via receptor and non-receptor binding mechanisms.  相似文献   
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A physically based model for the evolution of recrystallization microstructures and textures during hot rolling of aluminum is presented. The approach taken differs from similar models developed for steels. The present model is based on recent experimental investigations directed toward identifying the nature of the nucleation sites for recrystallized grains of different crystallographic orientations. Particle stimulated nucleation (PSN) and nucleation from cube bands and grain boundary regions have been incorporated in the model. The multipass aspect complicates the modeling due to partial recrystallization between the rolling passes. Two different approaches have been suggested to handle this. The model has been applied to predictions of recrystallization kinetics, recrystallized grain sizes, and recrystallization textures during multipass hot rolling of aluminum. The predictions are reasonable compared to experimental results.  相似文献   
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Metallurgical and Materials Transactions A - The effect of 0.03 and 0.08 at. pct Fe additions on the formation of secondary phases in an Al–1.1Mg–0.5Cu–0.3Si at. pct alloy was...  相似文献   
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The effect of solute atoms on grain boundary migration has been modeled on the basis of the idea that solute atoms will locally perturb the collective rearrangements of solvent atoms associated with boundary migration. The consequence of such perturbations is cusping of the boundary and corresponding stress concentrations on the solute atoms which will promote thermal activation of these atoms out of the boundary. This thermal activation is considered to be the rate-controlling mechanism in boundary migration. It is demonstrated that the current statistical approach is capable of explaining, in phenomenological terms, the known effects of solute atoms on boundary migration. The experimental results of the effect of copper on boundary migration in aluminum, due to Gordon and Vandermeer, have been well accounted for.  相似文献   
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The habit plane, orientation relationship (OR) and interfacial structure between the plate-shaped Al6(Mn,Fe) dispersoids and Al matrix in an AA 5182 alloy have been systematically studied by transmission electron microscopy, selected-area electron diffraction and crystallographic simulation. The published OR data about the dispersoids precipitated in different Al alloys has been critically assessed. A precise OR has been determined as (0 0 1)p//(3 ?1 5)m and [?1 1 0]p//[2 1 ?1]m, while the habit planes are determined as (0 0 1)p and (3 ?1 5)m. The OR and habit plane have been discussed in terms of the Δg approach. The dislocation arrangements at the interphase boundary of the habit planes are calculated by using O-lattice theory, which has been used to explain the mechanism of the OR selection and morphology development of dispersoids. It is revealed that an atom-to-atom matching exists in the good matching regions between the dislocations in the habit plane.  相似文献   
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