A novel multifunction material with both electrorheological performance and luminescence property

A multifunctional material with both electrorheological（ER） performance and luminescence property was synthesized by a simple coprecipitation. The tetrabutyl titanate, as well as the Tb（NO3）3·6H2O and sulphosalicylic acid（C7H6O6S·2H2O, SSA） were chosen as starting materials. The composition, ER performance and luminescence property of the material were studied. The results showed that a novel material（TiTbSSA） with both ER performance and luminescence property was obtained. The relative shear stress τr（τr=τE/τ0, τE and τ0 were the shear stresses of the suspension with and without an applied electric field） of the suspension（30 wt.%） of the material in silicone oil reached 32.7 at a shear rate of 12.5 s–1 and an electric field strength of 4 kV/mm（DC electric field）. The material containing the rare earth（RE=Tb） complex exhibited fine luminescence performance and higher ER activity. Therefore, it is a novel multifunction material which would have wide application prospect.     

Influence of La, Y, Gd, Cu, NH4^＋ Ions and DMSO on Luminescent Property of Terbium Complexes with Sulfosalicylate

Ｔｈｅｌａｎｔｈａｎｉｄｅｃｏｍｐｌｅｘｅｓｏｆｏｒｇａｎｉｃｌｉｇ ａｎｄｓａｓｆｌｕｏｒｅｓｃｅｎｔｍａｔｅｒｉａｌｓｈａｖｅｒｅｃｅｉｖｅｄｅｘ ｔｅｎｓｉｖｅａｔｔｅｎｔｉｏｎ .Ｔｈｅｕｓｅｏｆｆｌｕｏｒｅｓｃｅｎｔｏｒｇａｎｏ ｌａｎｔｈａｎｉｄｅｃｏｍｐｌｅｘｅｓｒｅｑｕｉｒｅｈｉｇｈｆｌｕｏ ｒｅｓｃｅｎｃｅｉｎｔｅｎｓｉｔｙａｎｄｌｏｗｃｏｓｔｃｏｍｐｌｅｘｅｓ .Ｉｎｒｅｃｅｎｔｙｅａｒｓ ,ｔｈｅｆｌｕｏｒｅｓｃｅｎｃｅｅｎｈａｎｃｅｍｅｎｔｏｆＴｂ(Ⅲ )ｏｒＥｕ(Ⅲ )ｃｏｍｐｌｅｘｅ…     

Effect of Y2 （CO3）3 and Surfactants on Electrorheological Performance of SiO2 Particle Materials

The SiO2 particle material has weak electrorheological (ER) activity. The ER performance of the SiO2 particlescan be ameliorated after adsorbing Y2(CO3)3. In this paper, the effect of Y2(CO3)3 and different surfactants on the ER performance of the SiO2 particle materials is investigated. The results show lhat anionic or cationic surfactants maybe enhance the ER activity of SiO2 material, and nonionic surfactants cannot when surfactants are added during the process of the SiO2 particle preparation, only the anionic surfactant, AES, can enhance markedly the ER performance of the material. The surface area, pore volume and pore diameter of the particles were measured. The effect of Y2(CO3)3 and the surfactants on the microstructure of SiO2 materials and the relationship between ER effect and the microstructure are described.     

Nitrilotriacetate Bridged 3d-4f Heteronuclear Complex: Synthesis and Crystal Structure of ｛[GdCu(NTA)(H_2O)_6Cl]ClO_4·H_2O｝_n

Ｔｈｅｓｙｎｔｈｅｓｉｓｏｆ 3ｄ 4ｆｈｅｔｅｒｏｎｕｃｌｅａｒｃｏｍ ｐｌｅｘｅｓｉｓｏｆｉｎｔｅｒｅｓｔｆｏｒｓｅｖｅｒａｌｒｅａｓｏｎｓ[1～ 9] .Ｔｈｅｓｅｃｏｍｐｌｅｘｅｓａｒｅｉｍｐｏｒｔａｎｔｉｎｔｈｅｓｔｕｄｉｅｓｏｆｍａｇｎｅｔｉｃｅｘｃｈａｎｇｅｉｎｔｅｒａｃｔｉｏｎｂｅｔｗｅｅｎｌａｎ ｔｈａｎｉｄｅａｎｄｄ ｔｒａｎｓｉｔｉｏｎｍｅｔａｌｉｏｎｓ,ａｎｄｔｈｅｙｃａｎｐｒｏｂａｂｌｙｂｅｕｓｅｄａｓｍａｇｎｅｔｉｃｍａｔｅｒｉ ａｌｓ[2～ 8] .Ｔｈｅｃｏｏｒｄｉｎａｔｉｏｎａｎｄｓ…     

PLC在井式炉炉温控制中的应用

PLC具有功能完备、可靠性高、使用灵活方便的显著优点,可编程控制器技术已成为现代控制技术的重要支柱之一。本文通过对PLC的应用使读者对整个设计能够有一个深入的了解,从而将该技术运用在实际生产当中。     

ALS型PLC在磨矿流程中的应用

对比了使用ALS型PLC前后对选矿车间生产效益的影响,简单介绍了与之配套的计算机检测控制系统、软硬件配置情况。     

高纯氧化镧的制备

本文以HEH(EH)P为萃取剂,在研究了分离系数受纯度影响的基础上,应用串级萃取理论设计了制各高纯氧化镧的串级萃取工艺参数,进行了小型串级实验。结果为,氧化镧产品中稀土杂质总量小于3ppm,其中氧化铈含量由原来的0.5％下降到≤0.15×10~(-4)％;非稀土杂质如铜、锌、铅、钴、镍等元素含量均不大于1ppm;实验还验证了串级萃取的动态平衡的计算结果。     

弱电网下考虑锁相环影响的并网逆变器自适应改进前馈策略

LCL型并网逆变器采用网压比例前馈策略可以有效地抑制电网背景谐波,但在弱电网下,随着电网阻抗的增大,系统逐渐失稳,同时再考虑锁相环影响,系统鲁棒性大幅降低。为此,本文首先建立包含锁相环以及网压比例前馈的LCL型并网逆变器阻抗模型,并采用阻抗分析法进行稳定性分析;提出了在锁相环以及网压前馈通道前串联陷波器对逆变器等效输出阻抗相位进行补偿的改进策略,在提升系统鲁棒性的同时保留网压比例前馈策略谐波抑制能力。然而,改进策略无法满足电网阻抗宽范围变化时系统稳定的要求,因此在改进策略的基础上加入了自适应环节,通过电网阻抗测量技术结合粒子群优化算法对陷波器参数进行自适应优化,从而提升系统在电网阻抗宽范围变化时的鲁棒性。最终通过仿真与实验验证了自适应改进策略的正确性和有效性。     

碳纤维掺杂β-环糊精包合物材料的制备和电流变性能

利用无毒、易得的β-环糊精(β-CD)作为主体,对甲基苯磺酸(PTA)作为客体,碳纤维作为掺杂材料,用研磨法,制得包合物(β-CD-PPTA)和碳纤维掺杂包合物(β-CD-PTA-C)电流变(ER)材料.FT-IR及XRD分析证实了包合物的形成.不同材料的电流变性质表明,包合PTA改善了β-CD材料的电流变性能,在包合物中掺杂碳纤维可以更有效地提高材料的电流变活性.另外,β-CD-PTA-C材料在硅油中的悬浮液具有良好的抗沉淀稳定性.     

Preparation and Electrorheological Property of Y4O（OH）9（NO3）-NH4NO3 Materials

The new electrorheological (ER) material, a particle material composed of Y4O(OH)9(NO3) and NH4NO3, was obtained.They display better ER performance.The shear stress of the suspension of Y4O(OH)9(NO3)(NH4NO3)2.8 material in dimethyl silicone oil reaches 1469 Pa at an electric field strength (E) of 4.2 kV·mm-1 and the shear rate (γ) of 150 s-1.The relative shear stress, τE/τ0 (τE and τ0 are the shear stresses at E=4.2 and 0 kV·mm-1, respectively), is up to 29, which is 19 times that of pure Y2O3 material.The dielectric and conductive property of the materials play important roles in the modification of the ER effect of the particle materials.The researches on these new ER materials are very useful for obtaining a better understanding on the mechanism of the ER effect and finding an ideal ER material.