Self Assembly of Polymer Structures Induced by Electric Field

A method has been developed for fabricating polymer microstructures based on electric field induced self assembly and pattern formation. A dielectric fluid placed in between two conductive plates experience a force in an applied electric field gradient across the plates, which can induce a diffusive surface instability and self construction of the fluid surface. This process is exploited for the fabrication of self assembled polymer microstructures as well as replicated patterns through the use of pre-patterned plates or electrodes. FEM simulation is used to decide the minimum wavelength and electric gradient distribution of polymer structures. A variety of structures in the micron and nanometer scales including bio-fluidic MEMS, polymer optoelectronic devices can be fabricated using this method.     

High‐pressure processing effects on the mechanical,barrier and mass transfer properties of food packaging flexible structures: a critical review

Food products can be high‐pressure processed (HPP) either in bulk or prepackaged in flexible or semi‐rigid packaging materials. In the latter case the packaging material is subjected, together with the food, to high‐pressure treatment. A number of studies have been performed to quantify the effects of high‐pressure processing on the physical and barrier properties of the packaging material, since the integrity of the package during and after processing is of paramount importance to the safety and quality of the food product. This article reviews the results of published research concerning the effect of HPP on packaging materials. Copyright © 2004 John Wiley & Sons, Ltd.     

Heat evolution of high-volume fly ash concrete

In this paper, the results of a laboratory investigation conducted with heat evolution of high-volume fly ash (HVFA) concrete are presented. Heat evolution of concrete was studied by measuring the temperature increase in concrete under adiabatic curing condition. Characteristic of heat evolution of fly ash concrete was found to be strongly dependent on the replacement level of fly ash and dosage of superplasticizer used to maintain workability. It was also found that using fly ash as cement replacement resulted in a reduction on the maximum temperature rise. Increasing the replacement level of fly ash caused lower temperature rise in concrete. Superplasticizer caused a delay in peak temperature rise time; this is taken as an indicator that high-dosage superplasticizer used in concrete caused retardation in hydration of cement. Concretes having similar ingredients showed similar peak temperature rise whether they are superplasticized or not.     

Transplantectomy today: indications and complications

Analysis of the indications for transplantectomy and its complications over a 12-year period. Over a total of 159 failure grafts, we performed 53 transplantectomies (33.3%). The percentage of complications was 16.9%. Three patients died (5.6%) during the more or less immediate post-operative period. In our experience, consistent and prolonged maintenance of immunosuppression should avoid the need for transplantectomy in a high percentage of grafts. Only 15 transplantectomies were made on 104 failure grafts after 6 months (14.4%). Our short but successful experience with embolization of 2 rejected grafts confirms the validity of this conservative alternative versus conventional surgical transplantectomy in selected cases.     

Synthesis Routes and Characterization of High-Purity, Single-Phase Gallium Nitride Powders

Synthesis of high-purity, single-phase gallium nitride powder has been achieved in a hot-wall tube furnace via (i) the reaction of gallium with ammonia (NH₃) and (ii) the conversion of gallium oxide (Ga₂O₃). For complete reaction, the optimum temperatures, NH₃ flow rates, and boat positions relative to the NH₃ inlet were 975°C, 400 standard cubic centimeters per minute (sccm), and 50 cm, respectively, for the gallium-NH₃ reaction, and 1050°C, 500 sccm, and 50 cm, respectively, for the Ga₂O₃ conversion. Polyhedra of various shapes were obtained from both processes; some rod-shaped crystals also were observed in the material derived from Ga₂O₃.     

Spatio‐temporal geometry fusion for multiple hybrid cameras using moving least squares surfaces

Multi‐view reconstruction aims at computing the geometry of a scene observed by a set of cameras. Accurate 3D reconstruction of dynamic scenes is a key component for a large variety of applications, ranging from special effects to telepresence and medical imaging. In this paper we propose a method based on Moving Least Squares surfaces which robustly and efficiently reconstructs dynamic scenes captured by a calibrated set of hybrid color+depth cameras. Our reconstruction provides spatio‐temporal consistency and seamlessly fuses color and geometric information. We illustrate our approach on a variety of real sequences and demonstrate that it favorably compares to state‐of‐the‐art methods.     

Preparation and characterization of PVA/OMMT composites

In this study, polyvinyl alcohol/organically modified montmorillonite (HDA/MMT; organoclay) composite was prepared for the intercalation processes. Firstly, the rheological behavior of aqueous montmorillonite dispersions was investigated as a function of solid content. Hexadecylamine (HDA) was added to the montmorillonite dispersion (2%, w/w) in different concentrations in the range of 5 × 10^?4 – 9 × 10^?3 mmol/L. The basal spacing of the organoclay (OMMT) was studied by X‐ray diffraction. The FTIR spectra are obtained from the modified montmorillonite products, which revealed the characteristic absorbencies after treatment with HDA. HDA/MMT/PVA composite, which was produced by the reaction of 1 wt % PVA solution with organoclay complex, is characterized by the rheology, electrokinetic, XRD, FTIR, and SEM techniques. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102:2315–2323, 2006     

Fuzzy multiattribute evaluation of R&D projects using a real options valuation model

R&D project selection decision is very important in two ways. First, in many organizations, R&D budget represents huge investment. Project selection decisions could be thought with the strategic objectives and plans of the firm. Second, R&D projects' organizational returns are multidimensional in nature and risky in terms of projected outcome. Real options approach helps to calculate this risky side of the selection process. This paper considers that multidimensional side of the R&D project selection process. Another consideration is the vagueness in the evaluation process. The fuzzy analytic hierarchy process, which takes monetary (fuzzy real option value) and nonmonetary (capability, success probability, trends, etc.) criteria into account, is used to make this selection among alternative R&D projects. A real case study is given to illustrate the application of the proposed approach. © 2008 Wiley Periodicals, Inc.     

Prediction of deflection of reinforced concrete shear walls

Reinforced concrete shear walls are used in tall buildings for efficiently resisting lateral loads. Due to the low tensile strength of concrete, reinforced concrete shear walls tend to behave in a nonlinear manner with a significant reduction in stiffness, even under service loads. To accurately assess the lateral deflection of shear walls, the prediction of flexural and shear stiffness of these members after cracking becomes important. In the present study, an iterative analytical procedure which considers the cracking in the reinforced concrete shear walls has been presented. The effect of concrete cracking on the stiffness and deflection of shear walls have also been investigated by the developed computer program based on the iterative procedure. In the program, the variation of the flexural stiffness of a cracked member has been evaluated by ACI and probability-based effective stiffness model. In the analysis, shear deformation which can be large and significant after development of cracks is also taken into account and the variation of shear stiffness in the cracked regions of members has been considered by using effective shear stiffness model available in the literature. Verification of the proposed procedure has been confirmed from series of reinforced concrete shear wall tests available in the literature. Comparison between the analytical and experimental results shows that the proposed analytical procedure can provide an accurate and efficient prediction of both the deflection and flexural stiffness reduction of shear walls with different height to width ratio and vertical load. The results of the analytical procedure also indicate that the percentage of shear deflection in the total deflection increases with decreasing height to width ratio of the shear wall.